Cyclohexylammonium Cinnamate Single Crystal for Nonlinear Optical Applications

Slow evaporation technique has been employed to grow single crystals of cyclohexylammonium cinnamate (CYHC). The presence of functional groups was analyzed via Fourier transform infrared spectroscopy, and the single-crystal x-ray diffraction analysis confirmed P21/n symmetry in the crystal. Thermal...

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Veröffentlicht in:Journal of electronic materials 2020-05, Vol.49 (5), p.3350-3356
Hauptverfasser: Gomathi, R., Ganesamoorthy, Ramasamy, Vinitha, G., Settu, Ramki, Chen, Shen Ming
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container_issue 5
container_start_page 3350
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creator Gomathi, R.
Ganesamoorthy, Ramasamy
Vinitha, G.
Settu, Ramki
Chen, Shen Ming
description Slow evaporation technique has been employed to grow single crystals of cyclohexylammonium cinnamate (CYHC). The presence of functional groups was analyzed via Fourier transform infrared spectroscopy, and the single-crystal x-ray diffraction analysis confirmed P21/n symmetry in the crystal. Thermal analysis confirmed the melting point of the single crystal at 175.12°C and decomposition mechanism. The dielectric studies of CYHC were analyzed, and the activation energy of the sample was also estimated. The photoluminescence (PL) spectrum of CYHC shows the emission wavelength at 500 nm (green emission region), and chemical etching studies were carried out to investigate the surface quality of CYHC crystal. Third-order nonlinear and optical limiting studies were performed, and the values of threshold output and clamping output were found to be 18.62 mW and 1.72 mW, respectively.
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subjects Characterization and Evaluation of Materials
Chemical etching
Chemistry and Materials Science
Crystal growth
Electronics and Microelectronics
Emission analysis
Fourier transforms
Functional groups
Infrared analysis
Instrumentation
Materials Science
Melting points
Nonlinear optics
Optical and Electronic Materials
Photoluminescence
Single crystals
Solid State Physics
Surface properties
Thermal analysis
title Cyclohexylammonium Cinnamate Single Crystal for Nonlinear Optical Applications
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