Cyclohexylammonium Cinnamate Single Crystal for Nonlinear Optical Applications
Slow evaporation technique has been employed to grow single crystals of cyclohexylammonium cinnamate (CYHC). The presence of functional groups was analyzed via Fourier transform infrared spectroscopy, and the single-crystal x-ray diffraction analysis confirmed P21/n symmetry in the crystal. Thermal...
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Veröffentlicht in: | Journal of electronic materials 2020-05, Vol.49 (5), p.3350-3356 |
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creator | Gomathi, R. Ganesamoorthy, Ramasamy Vinitha, G. Settu, Ramki Chen, Shen Ming |
description | Slow evaporation technique has been employed to grow single crystals of cyclohexylammonium cinnamate (CYHC). The presence of functional groups was analyzed via Fourier transform infrared spectroscopy, and the single-crystal x-ray diffraction analysis confirmed P21/n symmetry in the crystal. Thermal analysis confirmed the melting point of the single crystal at 175.12°C and decomposition mechanism. The dielectric studies of CYHC were analyzed, and the activation energy of the sample was also estimated. The photoluminescence (PL) spectrum of CYHC shows the emission wavelength at 500 nm (green emission region), and chemical etching studies were carried out to investigate the surface quality of CYHC crystal. Third-order nonlinear and optical limiting studies were performed, and the values of threshold output and clamping output were found to be 18.62 mW and 1.72 mW, respectively. |
doi_str_mv | 10.1007/s11664-020-08042-9 |
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The presence of functional groups was analyzed via Fourier transform infrared spectroscopy, and the single-crystal x-ray diffraction analysis confirmed P21/n symmetry in the crystal. Thermal analysis confirmed the melting point of the single crystal at 175.12°C and decomposition mechanism. The dielectric studies of CYHC were analyzed, and the activation energy of the sample was also estimated. The photoluminescence (PL) spectrum of CYHC shows the emission wavelength at 500 nm (green emission region), and chemical etching studies were carried out to investigate the surface quality of CYHC crystal. Third-order nonlinear and optical limiting studies were performed, and the values of threshold output and clamping output were found to be 18.62 mW and 1.72 mW, respectively.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-020-08042-9</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemical etching ; Chemistry and Materials Science ; Crystal growth ; Electronics and Microelectronics ; Emission analysis ; Fourier transforms ; Functional groups ; Infrared analysis ; Instrumentation ; Materials Science ; Melting points ; Nonlinear optics ; Optical and Electronic Materials ; Photoluminescence ; Single crystals ; Solid State Physics ; Surface properties ; Thermal analysis</subject><ispartof>Journal of electronic materials, 2020-05, Vol.49 (5), p.3350-3356</ispartof><rights>The Minerals, Metals & Materials Society 2020</rights><rights>The Minerals, Metals & Materials Society 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-bdd28fd12961df0ea18ed663dba31d71c0b67c961666db19292dfba1afa986343</citedby><cites>FETCH-LOGICAL-c319t-bdd28fd12961df0ea18ed663dba31d71c0b67c961666db19292dfba1afa986343</cites><orcidid>0000-0001-9307-5383</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11664-020-08042-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11664-020-08042-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Gomathi, R.</creatorcontrib><creatorcontrib>Ganesamoorthy, Ramasamy</creatorcontrib><creatorcontrib>Vinitha, G.</creatorcontrib><creatorcontrib>Settu, Ramki</creatorcontrib><creatorcontrib>Chen, Shen Ming</creatorcontrib><title>Cyclohexylammonium Cinnamate Single Crystal for Nonlinear Optical Applications</title><title>Journal of electronic materials</title><addtitle>Journal of Elec Materi</addtitle><description>Slow evaporation technique has been employed to grow single crystals of cyclohexylammonium cinnamate (CYHC). The presence of functional groups was analyzed via Fourier transform infrared spectroscopy, and the single-crystal x-ray diffraction analysis confirmed P21/n symmetry in the crystal. Thermal analysis confirmed the melting point of the single crystal at 175.12°C and decomposition mechanism. The dielectric studies of CYHC were analyzed, and the activation energy of the sample was also estimated. The photoluminescence (PL) spectrum of CYHC shows the emission wavelength at 500 nm (green emission region), and chemical etching studies were carried out to investigate the surface quality of CYHC crystal. 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The presence of functional groups was analyzed via Fourier transform infrared spectroscopy, and the single-crystal x-ray diffraction analysis confirmed P21/n symmetry in the crystal. Thermal analysis confirmed the melting point of the single crystal at 175.12°C and decomposition mechanism. The dielectric studies of CYHC were analyzed, and the activation energy of the sample was also estimated. The photoluminescence (PL) spectrum of CYHC shows the emission wavelength at 500 nm (green emission region), and chemical etching studies were carried out to investigate the surface quality of CYHC crystal. Third-order nonlinear and optical limiting studies were performed, and the values of threshold output and clamping output were found to be 18.62 mW and 1.72 mW, respectively.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11664-020-08042-9</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-9307-5383</orcidid></addata></record> |
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subjects | Characterization and Evaluation of Materials Chemical etching Chemistry and Materials Science Crystal growth Electronics and Microelectronics Emission analysis Fourier transforms Functional groups Infrared analysis Instrumentation Materials Science Melting points Nonlinear optics Optical and Electronic Materials Photoluminescence Single crystals Solid State Physics Surface properties Thermal analysis |
title | Cyclohexylammonium Cinnamate Single Crystal for Nonlinear Optical Applications |
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