Optimization of the Operation Parameters of an Inductively Coupled Plasma Atomic Emission Spectrometer in the Determination of Arsenic and Antimony Concentrations
Values of operation parameters of an inductively coupled plasma atomic emission spectrometer (ICP AES) (flow rate of sample carrying argon gas, flow rate of test solution supply to the discharge plasma, high-frequency power) are optimized for the determination of arsenic and antimony impurities in m...
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| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2020-03, Vol.75 (3), p.304-311 |
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| container_title | Journal of analytical chemistry (New York, N.Y.) |
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| creator | Maiorova, A. V. Belozerova, A. A. Okuneva, T. G. Shunyaev, K. Yu |
| description | Values of operation parameters of an inductively coupled plasma atomic emission spectrometer (ICP AES) (flow rate of sample carrying argon gas, flow rate of test solution supply to the discharge plasma, high-frequency power) are optimized for the determination of arsenic and antimony impurities in materials containing macroamounts of Fe, W, Mo, and Cr. It is found that the use of optimum operation parameters in the analysis leads to an increase in the intensity of the spectral lines As I at 189.042 nm and Sb I at 206.836 nm by 20 and 30%, respectively, relative to the values obtained under “standard” conditions. The mean values of the results of the ICP AES determination of the concentrations of arsenic and antimony in standard samples of the composition of ferrotungsten, ferromolybdenum, and alloy steel obtained at the optimized operation parameters of the spectrometer are closer to the certified values of analyte concentrations. The scatter of the results of analysis is reduced twofold in comparison to the values obtained with the spectrometer parameters recommended by the manufacturer. |
| doi_str_mv | 10.1134/S1061934820010116 |
| format | Article |
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V. ; Belozerova, A. A. ; Okuneva, T. G. ; Shunyaev, K. Yu</creator><creatorcontrib>Maiorova, A. V. ; Belozerova, A. A. ; Okuneva, T. G. ; Shunyaev, K. Yu</creatorcontrib><description>Values of operation parameters of an inductively coupled plasma atomic emission spectrometer (ICP AES) (flow rate of sample carrying argon gas, flow rate of test solution supply to the discharge plasma, high-frequency power) are optimized for the determination of arsenic and antimony impurities in materials containing macroamounts of Fe, W, Mo, and Cr. It is found that the use of optimum operation parameters in the analysis leads to an increase in the intensity of the spectral lines As I at 189.042 nm and Sb I at 206.836 nm by 20 and 30%, respectively, relative to the values obtained under “standard” conditions. The mean values of the results of the ICP AES determination of the concentrations of arsenic and antimony in standard samples of the composition of ferrotungsten, ferromolybdenum, and alloy steel obtained at the optimized operation parameters of the spectrometer are closer to the certified values of analyte concentrations. The scatter of the results of analysis is reduced twofold in comparison to the values obtained with the spectrometer parameters recommended by the manufacturer.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934820010116</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Alloy steels ; Analysis ; Analytical Chemistry ; Antimony ; Argon ; Arsenic ; Chemistry ; Chemistry and Materials Science ; Chromium ; Emission ; Ferromolybdenum ; Ferrotungsten ; Flow velocity ; Inductively coupled plasma ; Line spectra ; Molybdenum ; Optimization ; Parameters ; Plasma physics ; Tungsten</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2020-03, Vol.75 (3), p.304-311</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>COPYRIGHT 2020 Springer</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c455t-3e0271a16a6b3e4c62011cb0fc3be558c9cd652ebb3012d9b06351c58ca4e8753</citedby><cites>FETCH-LOGICAL-c455t-3e0271a16a6b3e4c62011cb0fc3be558c9cd652ebb3012d9b06351c58ca4e8753</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934820010116$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934820010116$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Maiorova, A. V.</creatorcontrib><creatorcontrib>Belozerova, A. A.</creatorcontrib><creatorcontrib>Okuneva, T. G.</creatorcontrib><creatorcontrib>Shunyaev, K. Yu</creatorcontrib><title>Optimization of the Operation Parameters of an Inductively Coupled Plasma Atomic Emission Spectrometer in the Determination of Arsenic and Antimony Concentrations</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>Values of operation parameters of an inductively coupled plasma atomic emission spectrometer (ICP AES) (flow rate of sample carrying argon gas, flow rate of test solution supply to the discharge plasma, high-frequency power) are optimized for the determination of arsenic and antimony impurities in materials containing macroamounts of Fe, W, Mo, and Cr. It is found that the use of optimum operation parameters in the analysis leads to an increase in the intensity of the spectral lines As I at 189.042 nm and Sb I at 206.836 nm by 20 and 30%, respectively, relative to the values obtained under “standard” conditions. The mean values of the results of the ICP AES determination of the concentrations of arsenic and antimony in standard samples of the composition of ferrotungsten, ferromolybdenum, and alloy steel obtained at the optimized operation parameters of the spectrometer are closer to the certified values of analyte concentrations. The scatter of the results of analysis is reduced twofold in comparison to the values obtained with the spectrometer parameters recommended by the manufacturer.</description><subject>Alloy steels</subject><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Antimony</subject><subject>Argon</subject><subject>Arsenic</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromium</subject><subject>Emission</subject><subject>Ferromolybdenum</subject><subject>Ferrotungsten</subject><subject>Flow velocity</subject><subject>Inductively coupled plasma</subject><subject>Line spectra</subject><subject>Molybdenum</subject><subject>Optimization</subject><subject>Parameters</subject><subject>Plasma physics</subject><subject>Tungsten</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1ks9u1DAQxiNEpZbCA_RmiROHFDtOvMkxWgqsVGkrFs6W40wWV4kdbKeiPE6ftJMGASu28sF_5vfNjD87SS4YvWSM5-93jApW8bzMKGWUMfEiOWOClilnVfUS1xhO5_hp8iqEW0ppVTJxljxsx2gG80tF4yxxHYnfgWxH8MvBjfJqgAg-zDFlyca2k47mDvp7snbT2ENLbnoVBkXq6AajydVgQpi1uxF09O5JTox9yvxh3gzG_ilX-wAWVcq2pLbYirNzYqvBxqWH8Do56VQf4M3v-Tz59vHq6_pzer39tFnX16nOiyKmHGi2YooJJRoOuRYZ2qAb2mneQFGUutKtKDJoGk5Z1lYNFbxgGgMqh3JV8PPk7ZJ39O7HBCHKWzd5iyVlxsu8FGj0P9Re9SCN7Rz2qfHOWtb4AiwTZblCKj1C7cGisb2z0Bk8PuAvj_A4WkBPjwreHQiQifAz7tUUgtzsvhyybGG1dyF46OTozaD8vWRUzr9H_vd7UJMtmoCs3YP_a8bzokeddcZ0</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Maiorova, A. V.</creator><creator>Belozerova, A. A.</creator><creator>Okuneva, T. G.</creator><creator>Shunyaev, K. Yu</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20200301</creationdate><title>Optimization of the Operation Parameters of an Inductively Coupled Plasma Atomic Emission Spectrometer in the Determination of Arsenic and Antimony Concentrations</title><author>Maiorova, A. V. ; Belozerova, A. A. ; Okuneva, T. G. ; Shunyaev, K. Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c455t-3e0271a16a6b3e4c62011cb0fc3be558c9cd652ebb3012d9b06351c58ca4e8753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alloy steels</topic><topic>Analysis</topic><topic>Analytical Chemistry</topic><topic>Antimony</topic><topic>Argon</topic><topic>Arsenic</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromium</topic><topic>Emission</topic><topic>Ferromolybdenum</topic><topic>Ferrotungsten</topic><topic>Flow velocity</topic><topic>Inductively coupled plasma</topic><topic>Line spectra</topic><topic>Molybdenum</topic><topic>Optimization</topic><topic>Parameters</topic><topic>Plasma physics</topic><topic>Tungsten</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maiorova, A. V.</creatorcontrib><creatorcontrib>Belozerova, A. A.</creatorcontrib><creatorcontrib>Okuneva, T. G.</creatorcontrib><creatorcontrib>Shunyaev, K. Yu</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maiorova, A. V.</au><au>Belozerova, A. A.</au><au>Okuneva, T. G.</au><au>Shunyaev, K. Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optimization of the Operation Parameters of an Inductively Coupled Plasma Atomic Emission Spectrometer in the Determination of Arsenic and Antimony Concentrations</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2020-03-01</date><risdate>2020</risdate><volume>75</volume><issue>3</issue><spage>304</spage><epage>311</epage><pages>304-311</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>Values of operation parameters of an inductively coupled plasma atomic emission spectrometer (ICP AES) (flow rate of sample carrying argon gas, flow rate of test solution supply to the discharge plasma, high-frequency power) are optimized for the determination of arsenic and antimony impurities in materials containing macroamounts of Fe, W, Mo, and Cr. It is found that the use of optimum operation parameters in the analysis leads to an increase in the intensity of the spectral lines As I at 189.042 nm and Sb I at 206.836 nm by 20 and 30%, respectively, relative to the values obtained under “standard” conditions. The mean values of the results of the ICP AES determination of the concentrations of arsenic and antimony in standard samples of the composition of ferrotungsten, ferromolybdenum, and alloy steel obtained at the optimized operation parameters of the spectrometer are closer to the certified values of analyte concentrations. The scatter of the results of analysis is reduced twofold in comparison to the values obtained with the spectrometer parameters recommended by the manufacturer.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061934820010116</doi><tpages>8</tpages></addata></record> |
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| subjects | Alloy steels Analysis Analytical Chemistry Antimony Argon Arsenic Chemistry Chemistry and Materials Science Chromium Emission Ferromolybdenum Ferrotungsten Flow velocity Inductively coupled plasma Line spectra Molybdenum Optimization Parameters Plasma physics Tungsten |
| title | Optimization of the Operation Parameters of an Inductively Coupled Plasma Atomic Emission Spectrometer in the Determination of Arsenic and Antimony Concentrations |
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