Translationally cold trapped CCl+ reactions with acetylene (C2H2)
Ion-neutral chemical reactions are important in several areas of chemistry, including in some regions of the interstellar medium, planetary atmospheres, and comets. Reactions of CCl+ with C2H2 are measured and the main products include c-C3H2+ and l-C3H+, both relevant in extraterrestrial environmen...
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| creator | Catani, Katherine J Greenberg, James Saarel, Benjamin V Lewandowski, Heather J |
| description | Ion-neutral chemical reactions are important in several areas of chemistry, including in some regions of the interstellar medium, planetary atmospheres, and comets. Reactions of CCl+ with C2H2 are measured and the main products include c-C3H2+ and l-C3H+, both relevant in extraterrestrial environments. Accurate branching ratios are obtained, which favor formation of c-C3H2+ over l-C3H+ by a factor of four. Measured rate constants are on the order of Langevin and complementary electronic structure calculations are used to aid in the interpretation of experimental results. |
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| subjects | Acetylene Chemical reactions Cold traps Cometary atmospheres Electronic structure Extraterrestrial environments Interstellar chemistry Interstellar matter Planetary atmospheres Rate constants |
| title | Translationally cold trapped CCl+ reactions with acetylene (C2H2) |
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