Improving melt strength of polypropylene by minimal branching and blending
ABSTRACT Branched polypropylenes (PPb) with markedly improved melt strength were produced without significantly affecting the processability of the original PP. A two‐step process of functionalization with MA and crosslinking with m‐XDA was used, both by batch mixing and by extrusion. Branching degr...
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| Veröffentlicht in: | Journal of applied polymer science 2020-07, Vol.137 (26), p.n/a |
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| container_title | Journal of applied polymer science |
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| creator | Guapacha, Jorge Barbosa, Jonathan Vallés, Enrique M. Quinzani, Lidia M. Failla, Marcelo D. |
| description | ABSTRACT
Branched polypropylenes (PPb) with markedly improved melt strength were produced without significantly affecting the processability of the original PP. A two‐step process of functionalization with MA and crosslinking with m‐XDA was used, both by batch mixing and by extrusion. Branching degrees of ~0.06 LCB/1000 monomer units or smaller were obtained. All PPbs display clear and significant strain hardening, being the PPb obtained by extrusion the one that shows the largest melt strength. This polymer has a zero‐shear‐rate viscosity slightly smaller than that of PP while its strain‐hardening index is about 10 times higher. Moreover, the nonlinear behavior of PP at elongation begins at a time similar to its terminal relaxation time or larger, while the ratio of these times reduces significantly with branching. PP/PPb blends were prepared to extend the range of obtainable melt strength in PP. They display rheological behavior between those of the mixed polymers with slight positive deviation. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48845. |
| doi_str_mv | 10.1002/app.48845 |
| format | Article |
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Branched polypropylenes (PPb) with markedly improved melt strength were produced without significantly affecting the processability of the original PP. A two‐step process of functionalization with MA and crosslinking with m‐XDA was used, both by batch mixing and by extrusion. Branching degrees of ~0.06 LCB/1000 monomer units or smaller were obtained. All PPbs display clear and significant strain hardening, being the PPb obtained by extrusion the one that shows the largest melt strength. This polymer has a zero‐shear‐rate viscosity slightly smaller than that of PP while its strain‐hardening index is about 10 times higher. Moreover, the nonlinear behavior of PP at elongation begins at a time similar to its terminal relaxation time or larger, while the ratio of these times reduces significantly with branching. PP/PPb blends were prepared to extend the range of obtainable melt strength in PP. They display rheological behavior between those of the mixed polymers with slight positive deviation. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48845.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.48845</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Crosslinking ; Elongation ; Extrusion ; Materials science ; Polymers ; polyolefins ; Polypropylene ; Relaxation time ; Rheological properties ; rheology ; Strain hardening ; Strength ; structure–property relationships</subject><ispartof>Journal of applied polymer science, 2020-07, Vol.137 (26), p.n/a</ispartof><rights>2019 Wiley Periodicals, Inc.</rights><rights>2020 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3345-2ebd36697da4d682f0d2ed7e69fd7df20f1d08adaa7c6be32de3046940ffd1613</citedby><cites>FETCH-LOGICAL-c3345-2ebd36697da4d682f0d2ed7e69fd7df20f1d08adaa7c6be32de3046940ffd1613</cites><orcidid>0000-0002-7350-212X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.48845$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.48845$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Guapacha, Jorge</creatorcontrib><creatorcontrib>Barbosa, Jonathan</creatorcontrib><creatorcontrib>Vallés, Enrique M.</creatorcontrib><creatorcontrib>Quinzani, Lidia M.</creatorcontrib><creatorcontrib>Failla, Marcelo D.</creatorcontrib><title>Improving melt strength of polypropylene by minimal branching and blending</title><title>Journal of applied polymer science</title><description>ABSTRACT
Branched polypropylenes (PPb) with markedly improved melt strength were produced without significantly affecting the processability of the original PP. A two‐step process of functionalization with MA and crosslinking with m‐XDA was used, both by batch mixing and by extrusion. Branching degrees of ~0.06 LCB/1000 monomer units or smaller were obtained. All PPbs display clear and significant strain hardening, being the PPb obtained by extrusion the one that shows the largest melt strength. This polymer has a zero‐shear‐rate viscosity slightly smaller than that of PP while its strain‐hardening index is about 10 times higher. Moreover, the nonlinear behavior of PP at elongation begins at a time similar to its terminal relaxation time or larger, while the ratio of these times reduces significantly with branching. PP/PPb blends were prepared to extend the range of obtainable melt strength in PP. They display rheological behavior between those of the mixed polymers with slight positive deviation. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48845.</description><subject>Crosslinking</subject><subject>Elongation</subject><subject>Extrusion</subject><subject>Materials science</subject><subject>Polymers</subject><subject>polyolefins</subject><subject>Polypropylene</subject><subject>Relaxation time</subject><subject>Rheological properties</subject><subject>rheology</subject><subject>Strain hardening</subject><subject>Strength</subject><subject>structure–property relationships</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kM1OwzAQhC0EEqFw4A0sceKQ1n9xnGNVQSmqRA9wtpzYblMlTrBTUN4el3DltFrNN7ujAeAeozlGiCxU38-ZECy7AAlGRZ4yTsQlSKKGU1EU2TW4CeGIEMYZ4gl43bS9775qt4etaQYYBm_cfjjAzsK-a8Yo9mNjnIHlCNva1a1qYOmVqw5nj3IallHWcbkFV1Y1wdz9zRn4eH56X72k27f1ZrXcphWlLEuJKTXlvMi1YpoLYpEmRueGF1bn2hJksUZCaaXyipeGEm0oYrxgyFqNOaYz8DDdjdk-TyYM8tidvIsvJaGCUkEEJpF6nKjKdyF4Y2XvY3g_SozkuSoZq5K_VUV2MbHfdWPG_0G53O0mxw-fgWvD</recordid><startdate>20200710</startdate><enddate>20200710</enddate><creator>Guapacha, Jorge</creator><creator>Barbosa, Jonathan</creator><creator>Vallés, Enrique M.</creator><creator>Quinzani, Lidia M.</creator><creator>Failla, Marcelo D.</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-7350-212X</orcidid></search><sort><creationdate>20200710</creationdate><title>Improving melt strength of polypropylene by minimal branching and blending</title><author>Guapacha, Jorge ; Barbosa, Jonathan ; Vallés, Enrique M. ; Quinzani, Lidia M. ; Failla, Marcelo D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3345-2ebd36697da4d682f0d2ed7e69fd7df20f1d08adaa7c6be32de3046940ffd1613</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Crosslinking</topic><topic>Elongation</topic><topic>Extrusion</topic><topic>Materials science</topic><topic>Polymers</topic><topic>polyolefins</topic><topic>Polypropylene</topic><topic>Relaxation time</topic><topic>Rheological properties</topic><topic>rheology</topic><topic>Strain hardening</topic><topic>Strength</topic><topic>structure–property relationships</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guapacha, Jorge</creatorcontrib><creatorcontrib>Barbosa, Jonathan</creatorcontrib><creatorcontrib>Vallés, Enrique M.</creatorcontrib><creatorcontrib>Quinzani, Lidia M.</creatorcontrib><creatorcontrib>Failla, Marcelo D.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guapacha, Jorge</au><au>Barbosa, Jonathan</au><au>Vallés, Enrique M.</au><au>Quinzani, Lidia M.</au><au>Failla, Marcelo D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improving melt strength of polypropylene by minimal branching and blending</atitle><jtitle>Journal of applied polymer science</jtitle><date>2020-07-10</date><risdate>2020</risdate><volume>137</volume><issue>26</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>ABSTRACT
Branched polypropylenes (PPb) with markedly improved melt strength were produced without significantly affecting the processability of the original PP. A two‐step process of functionalization with MA and crosslinking with m‐XDA was used, both by batch mixing and by extrusion. Branching degrees of ~0.06 LCB/1000 monomer units or smaller were obtained. All PPbs display clear and significant strain hardening, being the PPb obtained by extrusion the one that shows the largest melt strength. This polymer has a zero‐shear‐rate viscosity slightly smaller than that of PP while its strain‐hardening index is about 10 times higher. Moreover, the nonlinear behavior of PP at elongation begins at a time similar to its terminal relaxation time or larger, while the ratio of these times reduces significantly with branching. PP/PPb blends were prepared to extend the range of obtainable melt strength in PP. They display rheological behavior between those of the mixed polymers with slight positive deviation. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48845.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.48845</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-7350-212X</orcidid></addata></record> |
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| subjects | Crosslinking Elongation Extrusion Materials science Polymers polyolefins Polypropylene Relaxation time Rheological properties rheology Strain hardening Strength structure–property relationships |
| title | Improving melt strength of polypropylene by minimal branching and blending |
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