An exploratory research of calorimetric and structural shape memory effect characteristics of Cu–Al–Sn alloy
The ternary CuAlSn alloy was fabricated as cast ingot by arc melting method and the traditional homogenization and fast cooling (quenched in iced-brine water) SMA processes were carried out on small-cut samples of the ingot alloy. Then, the differential thermal and structural EDX, XRD measurements a...
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Veröffentlicht in: | Physica. B, Condensed matter Condensed matter, 2020-03, Vol.580, p.411932, Article 411932 |
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creator | Canbay, Canan Aksu Karaduman, Oktay Ünlü, Nihan Özkul, İskender |
description | The ternary CuAlSn alloy was fabricated as cast ingot by arc melting method and the traditional homogenization and fast cooling (quenched in iced-brine water) SMA processes were carried out on small-cut samples of the ingot alloy. Then, the differential thermal and structural EDX, XRD measurements and analyses were made for this monotype alloy samples. The DSC thermograms graphed at different heating/cooling rates revealed the deep endo/exo peaks indicating martensitic phase transitions occurred in the alloy. The alloy's behavior in high temperature region was elicited by DTA results. The thermodynamical parameters such as characteristic phase transformation temperatures, hysteresis, enthalpy and entropy changes, equilibrium temperature were determined either by taking directly from DSC data or by calculations made on them. XRD measurement made in room conditions showed the diffraction patterns belong to the existing martensite phase in the alloy, plus the crystallite size of the alloy was computed by using XRD data. |
doi_str_mv | 10.1016/j.physb.2019.411932 |
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Then, the differential thermal and structural EDX, XRD measurements and analyses were made for this monotype alloy samples. The DSC thermograms graphed at different heating/cooling rates revealed the deep endo/exo peaks indicating martensitic phase transitions occurred in the alloy. The alloy's behavior in high temperature region was elicited by DTA results. The thermodynamical parameters such as characteristic phase transformation temperatures, hysteresis, enthalpy and entropy changes, equilibrium temperature were determined either by taking directly from DSC data or by calculations made on them. XRD measurement made in room conditions showed the diffraction patterns belong to the existing martensite phase in the alloy, plus the crystallite size of the alloy was computed by using XRD data.</description><identifier>ISSN: 0921-4526</identifier><identifier>EISSN: 1873-2135</identifier><identifier>DOI: 10.1016/j.physb.2019.411932</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Alloys ; Aluminum base alloys ; Austenite ; Cooling rate ; Copper ; Crystal structure ; Crystallites ; Cu-Al-Sn shape memory alloy ; Differential thermal analysis ; Diffraction patterns ; DSC ; DTA ; Electric arc melting ; Enthalpy ; High temperature ; Ingot casting ; Ingots ; Martensite ; Martensitic transformations ; Phase transitions ; Saline water ; Shape effects ; Shape memory alloys ; Shape memory effect ; Thermodynamics ; Tin ; Transformation temperature ; X-ray diffraction</subject><ispartof>Physica. B, Condensed matter, 2020-03, Vol.580, p.411932, Article 411932</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright Elsevier BV Mar 1, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c246t-c632896149da475d1d530c6374658c15b461996bd7896fa5e9a4606b662c99c13</citedby><cites>FETCH-LOGICAL-c246t-c632896149da475d1d530c6374658c15b461996bd7896fa5e9a4606b662c99c13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0921452619308129$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids></links><search><creatorcontrib>Canbay, Canan Aksu</creatorcontrib><creatorcontrib>Karaduman, Oktay</creatorcontrib><creatorcontrib>Ünlü, Nihan</creatorcontrib><creatorcontrib>Özkul, İskender</creatorcontrib><title>An exploratory research of calorimetric and structural shape memory effect characteristics of Cu–Al–Sn alloy</title><title>Physica. B, Condensed matter</title><description>The ternary CuAlSn alloy was fabricated as cast ingot by arc melting method and the traditional homogenization and fast cooling (quenched in iced-brine water) SMA processes were carried out on small-cut samples of the ingot alloy. Then, the differential thermal and structural EDX, XRD measurements and analyses were made for this monotype alloy samples. The DSC thermograms graphed at different heating/cooling rates revealed the deep endo/exo peaks indicating martensitic phase transitions occurred in the alloy. The alloy's behavior in high temperature region was elicited by DTA results. The thermodynamical parameters such as characteristic phase transformation temperatures, hysteresis, enthalpy and entropy changes, equilibrium temperature were determined either by taking directly from DSC data or by calculations made on them. XRD measurement made in room conditions showed the diffraction patterns belong to the existing martensite phase in the alloy, plus the crystallite size of the alloy was computed by using XRD data.</description><subject>Alloys</subject><subject>Aluminum base alloys</subject><subject>Austenite</subject><subject>Cooling rate</subject><subject>Copper</subject><subject>Crystal structure</subject><subject>Crystallites</subject><subject>Cu-Al-Sn shape memory alloy</subject><subject>Differential thermal analysis</subject><subject>Diffraction patterns</subject><subject>DSC</subject><subject>DTA</subject><subject>Electric arc melting</subject><subject>Enthalpy</subject><subject>High temperature</subject><subject>Ingot casting</subject><subject>Ingots</subject><subject>Martensite</subject><subject>Martensitic transformations</subject><subject>Phase transitions</subject><subject>Saline water</subject><subject>Shape effects</subject><subject>Shape memory alloys</subject><subject>Shape memory effect</subject><subject>Thermodynamics</subject><subject>Tin</subject><subject>Transformation temperature</subject><subject>X-ray diffraction</subject><issn>0921-4526</issn><issn>1873-2135</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kL9OwzAQhy0EEqXwBCyWmBN8TuzUA0NV8U-qxADMlutc1FRpEmwH0Y134A15EhzCzA0-6fT7zrqPkEtgKTCQ17u03x78JuUMVJoDqIwfkRksiizhkIljMmOKQ5ILLk_Jmfc7FgsKmJF-2VL86JvOmdC5A3Xo0Ti7pV1FrYnjeo_B1ZaatqQ-uMGGwZmG-q3pke5xP0JYVWgDtVvjjA3oah9q68cVq-H782vZxOe5paZpusM5OalM4_Hir8_J693ty-ohWT_dP66W68TyXIbEyowvlIRclSYvRAmlyFgcFrkUCwtik0tQSm7KIqYqI1CZXDK5kZJbpSxkc3I17e1d9zagD3rXDa6NX2qeRUgJLlRMZVPKus57h5Xu48XGHTQwParVO_2rVo9q9aQ2UjcThfGA9xqd9rbG1mJZuyhCl139L_8DqdSFeA</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Canbay, Canan Aksu</creator><creator>Karaduman, Oktay</creator><creator>Ünlü, Nihan</creator><creator>Özkul, İskender</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20200301</creationdate><title>An exploratory research of calorimetric and structural shape memory effect characteristics of Cu–Al–Sn alloy</title><author>Canbay, Canan Aksu ; Karaduman, Oktay ; Ünlü, Nihan ; Özkul, İskender</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c246t-c632896149da475d1d530c6374658c15b461996bd7896fa5e9a4606b662c99c13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alloys</topic><topic>Aluminum base alloys</topic><topic>Austenite</topic><topic>Cooling rate</topic><topic>Copper</topic><topic>Crystal structure</topic><topic>Crystallites</topic><topic>Cu-Al-Sn shape memory alloy</topic><topic>Differential thermal analysis</topic><topic>Diffraction patterns</topic><topic>DSC</topic><topic>DTA</topic><topic>Electric arc melting</topic><topic>Enthalpy</topic><topic>High temperature</topic><topic>Ingot casting</topic><topic>Ingots</topic><topic>Martensite</topic><topic>Martensitic transformations</topic><topic>Phase transitions</topic><topic>Saline water</topic><topic>Shape effects</topic><topic>Shape memory alloys</topic><topic>Shape memory effect</topic><topic>Thermodynamics</topic><topic>Tin</topic><topic>Transformation temperature</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Canbay, Canan Aksu</creatorcontrib><creatorcontrib>Karaduman, Oktay</creatorcontrib><creatorcontrib>Ünlü, Nihan</creatorcontrib><creatorcontrib>Özkul, İskender</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Physica. B, Condensed matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Canbay, Canan Aksu</au><au>Karaduman, Oktay</au><au>Ünlü, Nihan</au><au>Özkul, İskender</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An exploratory research of calorimetric and structural shape memory effect characteristics of Cu–Al–Sn alloy</atitle><jtitle>Physica. B, Condensed matter</jtitle><date>2020-03-01</date><risdate>2020</risdate><volume>580</volume><spage>411932</spage><pages>411932-</pages><artnum>411932</artnum><issn>0921-4526</issn><eissn>1873-2135</eissn><abstract>The ternary CuAlSn alloy was fabricated as cast ingot by arc melting method and the traditional homogenization and fast cooling (quenched in iced-brine water) SMA processes were carried out on small-cut samples of the ingot alloy. Then, the differential thermal and structural EDX, XRD measurements and analyses were made for this monotype alloy samples. The DSC thermograms graphed at different heating/cooling rates revealed the deep endo/exo peaks indicating martensitic phase transitions occurred in the alloy. The alloy's behavior in high temperature region was elicited by DTA results. The thermodynamical parameters such as characteristic phase transformation temperatures, hysteresis, enthalpy and entropy changes, equilibrium temperature were determined either by taking directly from DSC data or by calculations made on them. XRD measurement made in room conditions showed the diffraction patterns belong to the existing martensite phase in the alloy, plus the crystallite size of the alloy was computed by using XRD data.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.physb.2019.411932</doi></addata></record> |
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subjects | Alloys Aluminum base alloys Austenite Cooling rate Copper Crystal structure Crystallites Cu-Al-Sn shape memory alloy Differential thermal analysis Diffraction patterns DSC DTA Electric arc melting Enthalpy High temperature Ingot casting Ingots Martensite Martensitic transformations Phase transitions Saline water Shape effects Shape memory alloys Shape memory effect Thermodynamics Tin Transformation temperature X-ray diffraction |
title | An exploratory research of calorimetric and structural shape memory effect characteristics of Cu–Al–Sn alloy |
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