Synthesis and application of a new, facile, and efficient sorbitol-based finishing agent for durable and flame retardant lyocell fibers
In this paper, a simple and facile polyol sorbitol was employed to design and synthesize a novel flame retardant containing phosphorus and nitrogen by the reaction of sorbitol with phosphoric acid and urea. The obtained sorbitol-based flame retardant was then used to treat lyocell fibers by a pad-dr...
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| Veröffentlicht in: | Cellulose (London) 2020-04, Vol.27 (6), p.3427-3442 |
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| creator | Liu, Xiao-hui Ding, Chen Peng, Bo Ren, Yuan-lin Cheng, Bo-wen Lin, Sheng-gen He, Ju Su, Xiao-wei |
| description | In this paper, a simple and facile polyol sorbitol was employed to design and synthesize a novel flame retardant containing phosphorus and nitrogen by the reaction of sorbitol with phosphoric acid and urea. The obtained sorbitol-based flame retardant was then used to treat lyocell fibers by a pad-dry-cure procedure. Formaldehyde and other harmful substances were not used during the preparation of flame retardant and modified fibers. For this strategy, only water is used as solvent, and the conditions are mild, safe and environmentally friendly. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy analyses show that the sorbitol-based flame retardant was successfully grafted onto lyocell fibers. Scanning electron microscopy analyses show that the surface morphology of the treated fibers remained unchanged. Thermogravimetric analyses imply that the residue of the treated fibers increases considerably. Vertical combustion and limit oxygen index results indicate that the treated fibers possess excellent flame retardant and durable properties. Based on the results of pyrolysis gas chromatography–mass spectrometry, thermogravimetric-infrared and Raman spectroscopy, the flame retardant operates in condensed phase and gas phase during burning of treated fibers. |
| doi_str_mv | 10.1007/s10570-019-02894-z |
| format | Article |
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The obtained sorbitol-based flame retardant was then used to treat lyocell fibers by a pad-dry-cure procedure. Formaldehyde and other harmful substances were not used during the preparation of flame retardant and modified fibers. For this strategy, only water is used as solvent, and the conditions are mild, safe and environmentally friendly. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy analyses show that the sorbitol-based flame retardant was successfully grafted onto lyocell fibers. Scanning electron microscopy analyses show that the surface morphology of the treated fibers remained unchanged. Thermogravimetric analyses imply that the residue of the treated fibers increases considerably. Vertical combustion and limit oxygen index results indicate that the treated fibers possess excellent flame retardant and durable properties. Based on the results of pyrolysis gas chromatography–mass spectrometry, thermogravimetric-infrared and Raman spectroscopy, the flame retardant operates in condensed phase and gas phase during burning of treated fibers.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-019-02894-z</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Bioorganic Chemistry ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Combustion ; Composites ; Fibers ; Flame retardants ; Fourier transforms ; Gas chromatography ; Glass ; Infrared analysis ; Infrared spectroscopy ; Mass spectrometry ; Morphology ; Natural Materials ; Organic Chemistry ; Original Research ; Phosphoric acid ; Photoelectrons ; Physical Chemistry ; Polymer Sciences ; Pyrolysis ; Raman spectroscopy ; Sorbitol ; Sustainable Development ; Vapor phases</subject><ispartof>Cellulose (London), 2020-04, Vol.27 (6), p.3427-3442</ispartof><rights>Springer Nature B.V. 2020</rights><rights>Cellulose is a copyright of Springer, (2020). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-cac2697729d28e5ec7c4775c2214289370078f27f186e5c35e883678caceef853</citedby><cites>FETCH-LOGICAL-c356t-cac2697729d28e5ec7c4775c2214289370078f27f186e5c35e883678caceef853</cites><orcidid>0000-0003-1175-4521</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-019-02894-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-019-02894-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Liu, Xiao-hui</creatorcontrib><creatorcontrib>Ding, Chen</creatorcontrib><creatorcontrib>Peng, Bo</creatorcontrib><creatorcontrib>Ren, Yuan-lin</creatorcontrib><creatorcontrib>Cheng, Bo-wen</creatorcontrib><creatorcontrib>Lin, Sheng-gen</creatorcontrib><creatorcontrib>He, Ju</creatorcontrib><creatorcontrib>Su, Xiao-wei</creatorcontrib><title>Synthesis and application of a new, facile, and efficient sorbitol-based finishing agent for durable and flame retardant lyocell fibers</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>In this paper, a simple and facile polyol sorbitol was employed to design and synthesize a novel flame retardant containing phosphorus and nitrogen by the reaction of sorbitol with phosphoric acid and urea. 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Based on the results of pyrolysis gas chromatography–mass spectrometry, thermogravimetric-infrared and Raman spectroscopy, the flame retardant operates in condensed phase and gas phase during burning of treated fibers.</description><subject>Bioorganic Chemistry</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Combustion</subject><subject>Composites</subject><subject>Fibers</subject><subject>Flame retardants</subject><subject>Fourier transforms</subject><subject>Gas chromatography</subject><subject>Glass</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Mass spectrometry</subject><subject>Morphology</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Phosphoric acid</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Pyrolysis</subject><subject>Raman spectroscopy</subject><subject>Sorbitol</subject><subject>Sustainable Development</subject><subject>Vapor phases</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kM1KAzEURoMoWKsv4CrgtqNJpjPJLEX8g4ILFdyFTOamTUmTMZki7Qv42qat4M7VXXzfuZd7ELqk5JoSwm8SJRUnBaFNQZhopsX2CI1oxVkhBPs4RiPS1LuobE7RWUpLQkjDGR2h79eNHxaQbMLKd1j1vbNaDTZ4HAxW2MPXBBulrYPJvgHGWG3BDziF2NohuKJVCTpsrLdpYf0cq_kuNiHibh1V62APGqdWgCMMKnYq524TNDiXuRZiOkcnRrkEF79zjN4f7t_unorZy-Pz3e2s0GVVD4VWmtUN56zpmIAKNNdTzivNGJ3mv0ueZQjDuKGihiozIERZc5E5ACOqcoyuDnv7GD7XkAa5DOvo80nJSi5qVom6zC12aOkYUopgZB_tSsWNpETuhMuDcJmFy71wuc1QeYBSLvs5xL_V_1A_QmeFlg</recordid><startdate>20200401</startdate><enddate>20200401</enddate><creator>Liu, Xiao-hui</creator><creator>Ding, Chen</creator><creator>Peng, Bo</creator><creator>Ren, Yuan-lin</creator><creator>Cheng, Bo-wen</creator><creator>Lin, Sheng-gen</creator><creator>He, Ju</creator><creator>Su, Xiao-wei</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0003-1175-4521</orcidid></search><sort><creationdate>20200401</creationdate><title>Synthesis and application of a new, facile, and efficient sorbitol-based finishing agent for durable and flame retardant lyocell fibers</title><author>Liu, Xiao-hui ; Ding, Chen ; Peng, Bo ; Ren, Yuan-lin ; Cheng, Bo-wen ; Lin, Sheng-gen ; He, Ju ; Su, Xiao-wei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-cac2697729d28e5ec7c4775c2214289370078f27f186e5c35e883678caceef853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Bioorganic Chemistry</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Combustion</topic><topic>Composites</topic><topic>Fibers</topic><topic>Flame retardants</topic><topic>Fourier transforms</topic><topic>Gas chromatography</topic><topic>Glass</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Mass spectrometry</topic><topic>Morphology</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Phosphoric acid</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Pyrolysis</topic><topic>Raman spectroscopy</topic><topic>Sorbitol</topic><topic>Sustainable Development</topic><topic>Vapor phases</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Xiao-hui</creatorcontrib><creatorcontrib>Ding, Chen</creatorcontrib><creatorcontrib>Peng, Bo</creatorcontrib><creatorcontrib>Ren, Yuan-lin</creatorcontrib><creatorcontrib>Cheng, Bo-wen</creatorcontrib><creatorcontrib>Lin, Sheng-gen</creatorcontrib><creatorcontrib>He, Ju</creatorcontrib><creatorcontrib>Su, Xiao-wei</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Xiao-hui</au><au>Ding, Chen</au><au>Peng, Bo</au><au>Ren, Yuan-lin</au><au>Cheng, Bo-wen</au><au>Lin, Sheng-gen</au><au>He, Ju</au><au>Su, Xiao-wei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and application of a new, facile, and efficient sorbitol-based finishing agent for durable and flame retardant lyocell fibers</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2020-04-01</date><risdate>2020</risdate><volume>27</volume><issue>6</issue><spage>3427</spage><epage>3442</epage><pages>3427-3442</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>In this paper, a simple and facile polyol sorbitol was employed to design and synthesize a novel flame retardant containing phosphorus and nitrogen by the reaction of sorbitol with phosphoric acid and urea. The obtained sorbitol-based flame retardant was then used to treat lyocell fibers by a pad-dry-cure procedure. Formaldehyde and other harmful substances were not used during the preparation of flame retardant and modified fibers. For this strategy, only water is used as solvent, and the conditions are mild, safe and environmentally friendly. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy analyses show that the sorbitol-based flame retardant was successfully grafted onto lyocell fibers. Scanning electron microscopy analyses show that the surface morphology of the treated fibers remained unchanged. Thermogravimetric analyses imply that the residue of the treated fibers increases considerably. Vertical combustion and limit oxygen index results indicate that the treated fibers possess excellent flame retardant and durable properties. Based on the results of pyrolysis gas chromatography–mass spectrometry, thermogravimetric-infrared and Raman spectroscopy, the flame retardant operates in condensed phase and gas phase during burning of treated fibers.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-019-02894-z</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0003-1175-4521</orcidid></addata></record> |
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| subjects | Bioorganic Chemistry Ceramics Chemistry Chemistry and Materials Science Combustion Composites Fibers Flame retardants Fourier transforms Gas chromatography Glass Infrared analysis Infrared spectroscopy Mass spectrometry Morphology Natural Materials Organic Chemistry Original Research Phosphoric acid Photoelectrons Physical Chemistry Polymer Sciences Pyrolysis Raman spectroscopy Sorbitol Sustainable Development Vapor phases |
| title | Synthesis and application of a new, facile, and efficient sorbitol-based finishing agent for durable and flame retardant lyocell fibers |
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