Soybean hulls as a low‐cost biosorbent for removal of methylene blue contaminant
Methylene blue is a cationic dye used for dyeing cotton, wool, and silk. This dye can cause impacts when reaching water resources due to the reduction of sunlight infiltration, besides the health problems if ingested. Therefore, the complete removal of this contaminant in industrial effluents is ind...
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| Veröffentlicht in: | Environmental progress 2020-03, Vol.39 (2), p.n/a |
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| creator | Cusioli, Luís Fernando Quesada, Heloise B. Baptista, Aline T. A. Gomes, Raquel G. Bergamasco, Rosângela |
| description | Methylene blue is a cationic dye used for dyeing cotton, wool, and silk. This dye can cause impacts when reaching water resources due to the reduction of sunlight infiltration, besides the health problems if ingested. Therefore, the complete removal of this contaminant in industrial effluents is indispensable. Currently, soybean hulls residues are used in animal feed supplementation; however, since soybean oil production is large, expressive quantities is discarded in landfills. Thus, the present study aim is to evaluate the adsorption capacity of methylene blue onto soybean hulls as an alternative use of this agroindustrial residue. The material was characterized through morphological and chemical analysis which showed porosity, heterogeneity, and functional groups that favor the adsorption. Due to the mainly negative charge of the surface, the pH did not affect the cationic dye uptake, enabling a wide pH range. After the adsorption studies, the best experimental conditions were at temperatures of 298 K, mass of 0.025 g, and contact time of 180 min, resulting in the maximum adsorption capacity of 169.90 mg g−1. When compared with other low‐cost biosorbent and activated carbons, it can be perceived a potential applicability of soybean hulls in wastewater treatment as an alternative use. |
| doi_str_mv | 10.1002/ep.13328 |
| format | Article |
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A. ; Gomes, Raquel G. ; Bergamasco, Rosângela</creator><creatorcontrib>Cusioli, Luís Fernando ; Quesada, Heloise B. ; Baptista, Aline T. A. ; Gomes, Raquel G. ; Bergamasco, Rosângela</creatorcontrib><description>Methylene blue is a cationic dye used for dyeing cotton, wool, and silk. This dye can cause impacts when reaching water resources due to the reduction of sunlight infiltration, besides the health problems if ingested. Therefore, the complete removal of this contaminant in industrial effluents is indispensable. Currently, soybean hulls residues are used in animal feed supplementation; however, since soybean oil production is large, expressive quantities is discarded in landfills. Thus, the present study aim is to evaluate the adsorption capacity of methylene blue onto soybean hulls as an alternative use of this agroindustrial residue. The material was characterized through morphological and chemical analysis which showed porosity, heterogeneity, and functional groups that favor the adsorption. Due to the mainly negative charge of the surface, the pH did not affect the cationic dye uptake, enabling a wide pH range. After the adsorption studies, the best experimental conditions were at temperatures of 298 K, mass of 0.025 g, and contact time of 180 min, resulting in the maximum adsorption capacity of 169.90 mg g−1. When compared with other low‐cost biosorbent and activated carbons, it can be perceived a potential applicability of soybean hulls in wastewater treatment as an alternative use.</description><identifier>ISSN: 1944-7442</identifier><identifier>EISSN: 1944-7450</identifier><identifier>DOI: 10.1002/ep.13328</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Activated carbon ; Adsorption ; Agricultural economics ; Agricultural production ; Agricultural wastes ; Animal feed ; biosorption ; Cationic dyes ; Chemical analysis ; Contaminants ; Cotton ; Dyeing ; Dyes ; Feeds ; Functional groups ; Health problems ; Heterogeneity ; Hulls ; Industrial effluents ; Industrial pollution ; Industrial wastewater ; Landfills ; Methylene blue ; Oils & fats ; pH effects ; Pollutant removal ; Porosity ; Silk ; soybean hulls ; Soybean oil ; Soybeans ; Supplements ; Surface charge ; Waste disposal sites ; Wastewater treatment ; Water resources ; Wool</subject><ispartof>Environmental progress, 2020-03, Vol.39 (2), p.n/a</ispartof><rights>2019 American Institute of Chemical Engineers</rights><rights>2020 American Institute of Chemical Engineers</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3308-9749f3430af526064f45de477ec5f321414ac3f6979ae38726609760e977435f3</citedby><cites>FETCH-LOGICAL-c3308-9749f3430af526064f45de477ec5f321414ac3f6979ae38726609760e977435f3</cites><orcidid>0000-0003-3906-336X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fep.13328$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fep.13328$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Cusioli, Luís Fernando</creatorcontrib><creatorcontrib>Quesada, Heloise B.</creatorcontrib><creatorcontrib>Baptista, Aline T. A.</creatorcontrib><creatorcontrib>Gomes, Raquel G.</creatorcontrib><creatorcontrib>Bergamasco, Rosângela</creatorcontrib><title>Soybean hulls as a low‐cost biosorbent for removal of methylene blue contaminant</title><title>Environmental progress</title><description>Methylene blue is a cationic dye used for dyeing cotton, wool, and silk. This dye can cause impacts when reaching water resources due to the reduction of sunlight infiltration, besides the health problems if ingested. Therefore, the complete removal of this contaminant in industrial effluents is indispensable. Currently, soybean hulls residues are used in animal feed supplementation; however, since soybean oil production is large, expressive quantities is discarded in landfills. Thus, the present study aim is to evaluate the adsorption capacity of methylene blue onto soybean hulls as an alternative use of this agroindustrial residue. The material was characterized through morphological and chemical analysis which showed porosity, heterogeneity, and functional groups that favor the adsorption. Due to the mainly negative charge of the surface, the pH did not affect the cationic dye uptake, enabling a wide pH range. After the adsorption studies, the best experimental conditions were at temperatures of 298 K, mass of 0.025 g, and contact time of 180 min, resulting in the maximum adsorption capacity of 169.90 mg g−1. When compared with other low‐cost biosorbent and activated carbons, it can be perceived a potential applicability of soybean hulls in wastewater treatment as an alternative use.</description><subject>Activated carbon</subject><subject>Adsorption</subject><subject>Agricultural economics</subject><subject>Agricultural production</subject><subject>Agricultural wastes</subject><subject>Animal feed</subject><subject>biosorption</subject><subject>Cationic dyes</subject><subject>Chemical analysis</subject><subject>Contaminants</subject><subject>Cotton</subject><subject>Dyeing</subject><subject>Dyes</subject><subject>Feeds</subject><subject>Functional groups</subject><subject>Health problems</subject><subject>Heterogeneity</subject><subject>Hulls</subject><subject>Industrial effluents</subject><subject>Industrial pollution</subject><subject>Industrial wastewater</subject><subject>Landfills</subject><subject>Methylene blue</subject><subject>Oils & fats</subject><subject>pH effects</subject><subject>Pollutant removal</subject><subject>Porosity</subject><subject>Silk</subject><subject>soybean hulls</subject><subject>Soybean oil</subject><subject>Soybeans</subject><subject>Supplements</subject><subject>Surface charge</subject><subject>Waste disposal sites</subject><subject>Wastewater treatment</subject><subject>Water resources</subject><subject>Wool</subject><issn>1944-7442</issn><issn>1944-7450</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp10MtKxDAUBuAgCo6j4CME3LjpmFuTZinDeIEBxcs6pPWE6dA2NWkduvMRfEafxGrFnXDgnMXHf-BH6JSSBSWEXUC7oJyzbA_NqBYiUSIl-3-3YIfoKMYtIZILrWfo4dEPOdgGb_qqitiOgyu_-3z_KHzscF766EMOTYedDzhA7d9shb3DNXSboYIGcF71gAvfdLYuG9t0x-jA2SrCye-eo-er1dPyJlnfXd8uL9dJwTnJEq2EdlxwYl3KJJHCifQFhFJQpI4zKqiwBXdSK22BZ4pJSbSSBLRSgo9kjs6m3Db41x5iZ7a-D8340jCuFGOZ5HRU55Mqgo8xgDNtKGsbBkOJ-W7MQGt-GhtpMtFdWcHwrzOr-8l_AdQ3a1k</recordid><startdate>202003</startdate><enddate>202003</enddate><creator>Cusioli, Luís Fernando</creator><creator>Quesada, Heloise B.</creator><creator>Baptista, Aline T. A.</creator><creator>Gomes, Raquel G.</creator><creator>Bergamasco, Rosângela</creator><general>John Wiley & Sons, Inc</general><general>John Wiley and Sons, Limited</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7U6</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>M7N</scope><scope>P64</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-3906-336X</orcidid></search><sort><creationdate>202003</creationdate><title>Soybean hulls as a low‐cost biosorbent for removal of methylene blue contaminant</title><author>Cusioli, Luís Fernando ; Quesada, Heloise B. ; Baptista, Aline T. A. ; Gomes, Raquel G. ; Bergamasco, Rosângela</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3308-9749f3430af526064f45de477ec5f321414ac3f6979ae38726609760e977435f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Activated carbon</topic><topic>Adsorption</topic><topic>Agricultural economics</topic><topic>Agricultural production</topic><topic>Agricultural wastes</topic><topic>Animal feed</topic><topic>biosorption</topic><topic>Cationic dyes</topic><topic>Chemical analysis</topic><topic>Contaminants</topic><topic>Cotton</topic><topic>Dyeing</topic><topic>Dyes</topic><topic>Feeds</topic><topic>Functional groups</topic><topic>Health problems</topic><topic>Heterogeneity</topic><topic>Hulls</topic><topic>Industrial effluents</topic><topic>Industrial pollution</topic><topic>Industrial wastewater</topic><topic>Landfills</topic><topic>Methylene blue</topic><topic>Oils & fats</topic><topic>pH effects</topic><topic>Pollutant removal</topic><topic>Porosity</topic><topic>Silk</topic><topic>soybean hulls</topic><topic>Soybean oil</topic><topic>Soybeans</topic><topic>Supplements</topic><topic>Surface charge</topic><topic>Waste disposal sites</topic><topic>Wastewater treatment</topic><topic>Water resources</topic><topic>Wool</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cusioli, Luís Fernando</creatorcontrib><creatorcontrib>Quesada, Heloise B.</creatorcontrib><creatorcontrib>Baptista, Aline T. A.</creatorcontrib><creatorcontrib>Gomes, Raquel G.</creatorcontrib><creatorcontrib>Bergamasco, Rosângela</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Environmental progress</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cusioli, Luís Fernando</au><au>Quesada, Heloise B.</au><au>Baptista, Aline T. A.</au><au>Gomes, Raquel G.</au><au>Bergamasco, Rosângela</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Soybean hulls as a low‐cost biosorbent for removal of methylene blue contaminant</atitle><jtitle>Environmental progress</jtitle><date>2020-03</date><risdate>2020</risdate><volume>39</volume><issue>2</issue><epage>n/a</epage><issn>1944-7442</issn><eissn>1944-7450</eissn><abstract>Methylene blue is a cationic dye used for dyeing cotton, wool, and silk. This dye can cause impacts when reaching water resources due to the reduction of sunlight infiltration, besides the health problems if ingested. Therefore, the complete removal of this contaminant in industrial effluents is indispensable. Currently, soybean hulls residues are used in animal feed supplementation; however, since soybean oil production is large, expressive quantities is discarded in landfills. Thus, the present study aim is to evaluate the adsorption capacity of methylene blue onto soybean hulls as an alternative use of this agroindustrial residue. The material was characterized through morphological and chemical analysis which showed porosity, heterogeneity, and functional groups that favor the adsorption. Due to the mainly negative charge of the surface, the pH did not affect the cationic dye uptake, enabling a wide pH range. After the adsorption studies, the best experimental conditions were at temperatures of 298 K, mass of 0.025 g, and contact time of 180 min, resulting in the maximum adsorption capacity of 169.90 mg g−1. When compared with other low‐cost biosorbent and activated carbons, it can be perceived a potential applicability of soybean hulls in wastewater treatment as an alternative use.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/ep.13328</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-3906-336X</orcidid></addata></record> |
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| subjects | Activated carbon Adsorption Agricultural economics Agricultural production Agricultural wastes Animal feed biosorption Cationic dyes Chemical analysis Contaminants Cotton Dyeing Dyes Feeds Functional groups Health problems Heterogeneity Hulls Industrial effluents Industrial pollution Industrial wastewater Landfills Methylene blue Oils & fats pH effects Pollutant removal Porosity Silk soybean hulls Soybean oil Soybeans Supplements Surface charge Waste disposal sites Wastewater treatment Water resources Wool |
| title | Soybean hulls as a low‐cost biosorbent for removal of methylene blue contaminant |
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