Flexible and rechargeable electrochromic aluminium-ion battery based on tungsten oxide film electrode
Electrochromic (EC) energy storage devices that possess characteristics of energy storage and electrochromism are highly desirable and have increasingly attracted research interests, whilst devices that can be stretched or are flexible have received very little attention. Herein, we report a flexibl...
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| Veröffentlicht in: | Solar energy materials and solar cells 2020-04, Vol.207, p.110332, Article 110332 |
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| container_title | Solar energy materials and solar cells |
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| creator | Sun, Shibin Tang, Chengji Jiang, Yingchang Wang, Dongsheng Chang, Xueting Lei, Yanhua Wang, Nannan Zhu, Yanqiu |
| description | Electrochromic (EC) energy storage devices that possess characteristics of energy storage and electrochromism are highly desirable and have increasingly attracted research interests, whilst devices that can be stretched or are flexible have received very little attention. Herein, we report a flexible and rechargeable aluminium (Al) ion EC battery (ECB), which consists of a WO3 film as positive electrode, PET/ITO as substrate, Al sheet as negative electrode, aluminum trichloride (AlCl3) aqueous solution as electrolyte, and absorptive glass mat (AGM) as electrolyte carrier and separator. The ECB exhibits a high specific capacity of 142 mAhg−1, while demonstrating reversible color transitions between white (bleached state) and dark blue (colored state) during the cyclic charge/discharge processes. Furthermore, the ECB can work at bending angles of 0-80° with a capacity retention of 92.3% after 40 bending cycles. The flexibility of the ECB is ascribed to the flexible, porous, and highly stable features of the AGM as well as the deformability of the PET/ITO substrate. The potential widow of the ECB can be largely enhanced by connecting small-sized ECBs internally in series while maintaining the energy density unchanged. The present study demonstrates that the ECB using the AGM as the electrolyte carrier and separator may have great potentials for the construction of both flexible, portable electronics and smart windows.
A flexible and rechargeable electrochromic battery that possesses characteristics of energy storage, electrochromism, and deformability is assembled by using absorptive glass mat (AGM) as the electrolyte carrier and separator. [Display omitted]
•The WO3 films were deposited on the PET/ITO substrate using a magnetron sputtering method.•A flexible and rechargeable ECB was assembled with AGM as electrolyte carrier and separator.•The ECB exhibited high specific capacity (142 mAhg−1) and can work at bending angles of 0-80°. |
| doi_str_mv | 10.1016/j.solmat.2019.110332 |
| format | Article |
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A flexible and rechargeable electrochromic battery that possesses characteristics of energy storage, electrochromism, and deformability is assembled by using absorptive glass mat (AGM) as the electrolyte carrier and separator. [Display omitted]
•The WO3 films were deposited on the PET/ITO substrate using a magnetron sputtering method.•A flexible and rechargeable ECB was assembled with AGM as electrolyte carrier and separator.•The ECB exhibited high specific capacity (142 mAhg−1) and can work at bending angles of 0-80°.</description><identifier>ISSN: 0927-0248</identifier><identifier>EISSN: 1879-3398</identifier><identifier>DOI: 10.1016/j.solmat.2019.110332</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Absorptive glass mat (AGM) ; Absorptivity ; Aluminum ; Aluminum chloride ; Aluminum-ion batteries ; Aqueous solutions ; Battery ; Bending ; Bleaching ; Chlorides ; Deformability ; Electrochromic ; Electrochromism ; Electrodes ; Electrolytes ; Energy storage ; Flexible ; Flux density ; Formability ; Lithium ; Oxide coatings ; Polyethylene terephthalate ; Rechargeable batteries ; Separators ; Smart materials ; Specific capacity ; Substrates ; Tungsten ; Tungsten oxide ; Windows (apertures) ; WO3</subject><ispartof>Solar energy materials and solar cells, 2020-04, Vol.207, p.110332, Article 110332</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright Elsevier BV Apr 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c334t-e78a8c8b5c586777381076533a6772623403f24c03fed5be1f2a9fdfea4c3df73</citedby><cites>FETCH-LOGICAL-c334t-e78a8c8b5c586777381076533a6772623403f24c03fed5be1f2a9fdfea4c3df73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0927024819306609$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Sun, Shibin</creatorcontrib><creatorcontrib>Tang, Chengji</creatorcontrib><creatorcontrib>Jiang, Yingchang</creatorcontrib><creatorcontrib>Wang, Dongsheng</creatorcontrib><creatorcontrib>Chang, Xueting</creatorcontrib><creatorcontrib>Lei, Yanhua</creatorcontrib><creatorcontrib>Wang, Nannan</creatorcontrib><creatorcontrib>Zhu, Yanqiu</creatorcontrib><title>Flexible and rechargeable electrochromic aluminium-ion battery based on tungsten oxide film electrode</title><title>Solar energy materials and solar cells</title><description>Electrochromic (EC) energy storage devices that possess characteristics of energy storage and electrochromism are highly desirable and have increasingly attracted research interests, whilst devices that can be stretched or are flexible have received very little attention. Herein, we report a flexible and rechargeable aluminium (Al) ion EC battery (ECB), which consists of a WO3 film as positive electrode, PET/ITO as substrate, Al sheet as negative electrode, aluminum trichloride (AlCl3) aqueous solution as electrolyte, and absorptive glass mat (AGM) as electrolyte carrier and separator. The ECB exhibits a high specific capacity of 142 mAhg−1, while demonstrating reversible color transitions between white (bleached state) and dark blue (colored state) during the cyclic charge/discharge processes. Furthermore, the ECB can work at bending angles of 0-80° with a capacity retention of 92.3% after 40 bending cycles. The flexibility of the ECB is ascribed to the flexible, porous, and highly stable features of the AGM as well as the deformability of the PET/ITO substrate. The potential widow of the ECB can be largely enhanced by connecting small-sized ECBs internally in series while maintaining the energy density unchanged. The present study demonstrates that the ECB using the AGM as the electrolyte carrier and separator may have great potentials for the construction of both flexible, portable electronics and smart windows.
A flexible and rechargeable electrochromic battery that possesses characteristics of energy storage, electrochromism, and deformability is assembled by using absorptive glass mat (AGM) as the electrolyte carrier and separator. [Display omitted]
•The WO3 films were deposited on the PET/ITO substrate using a magnetron sputtering method.•A flexible and rechargeable ECB was assembled with AGM as electrolyte carrier and separator.•The ECB exhibited high specific capacity (142 mAhg−1) and can work at bending angles of 0-80°.</description><subject>Absorptive glass mat (AGM)</subject><subject>Absorptivity</subject><subject>Aluminum</subject><subject>Aluminum chloride</subject><subject>Aluminum-ion batteries</subject><subject>Aqueous solutions</subject><subject>Battery</subject><subject>Bending</subject><subject>Bleaching</subject><subject>Chlorides</subject><subject>Deformability</subject><subject>Electrochromic</subject><subject>Electrochromism</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Energy storage</subject><subject>Flexible</subject><subject>Flux density</subject><subject>Formability</subject><subject>Lithium</subject><subject>Oxide coatings</subject><subject>Polyethylene terephthalate</subject><subject>Rechargeable batteries</subject><subject>Separators</subject><subject>Smart materials</subject><subject>Specific capacity</subject><subject>Substrates</subject><subject>Tungsten</subject><subject>Tungsten oxide</subject><subject>Windows (apertures)</subject><subject>WO3</subject><issn>0927-0248</issn><issn>1879-3398</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWD_-gYcFz1uTzHaTvQgifkHBi55Dmsy2KbubmmSl_femrF69zMsM877DPITcMDpnlNV323n0Xa_TnFPWzBmjAPyEzJgUTQnQyFMyow0XJeWVPCcXMW4ppbyGakbwucO9W3VY6MEWAc1GhzXq4wA7NCl4swm-d6bQ3di7wY196fxQrHRKGA5ZI9oiD9I4rGPCofB7Z7FoXdf_JVi8Imet7iJe_-ol-Xx--nh8LZfvL2-PD8vSAFSpRCG1NHK1MAtZCyFAMirqBYDOHa85VBRaXplc0S5WyFqum9a2qCsDthVwSW6n3F3wXyPGpLZ-DEM-qTiIWgCFSuatatoywccYsFW74HodDopRdQSqtmoCqo5A1QQ02-4nG-YPvh0GFY3DwaB1mVtS1rv_A34A4reB_A</recordid><startdate>202004</startdate><enddate>202004</enddate><creator>Sun, Shibin</creator><creator>Tang, Chengji</creator><creator>Jiang, Yingchang</creator><creator>Wang, Dongsheng</creator><creator>Chang, Xueting</creator><creator>Lei, Yanhua</creator><creator>Wang, Nannan</creator><creator>Zhu, Yanqiu</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7ST</scope><scope>7TB</scope><scope>7U5</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>L7M</scope><scope>SOI</scope></search><sort><creationdate>202004</creationdate><title>Flexible and rechargeable electrochromic aluminium-ion battery based on tungsten oxide film electrode</title><author>Sun, Shibin ; Tang, Chengji ; Jiang, Yingchang ; Wang, Dongsheng ; Chang, Xueting ; Lei, Yanhua ; Wang, Nannan ; Zhu, Yanqiu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-e78a8c8b5c586777381076533a6772623403f24c03fed5be1f2a9fdfea4c3df73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Absorptive glass mat (AGM)</topic><topic>Absorptivity</topic><topic>Aluminum</topic><topic>Aluminum chloride</topic><topic>Aluminum-ion batteries</topic><topic>Aqueous solutions</topic><topic>Battery</topic><topic>Bending</topic><topic>Bleaching</topic><topic>Chlorides</topic><topic>Deformability</topic><topic>Electrochromic</topic><topic>Electrochromism</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Energy storage</topic><topic>Flexible</topic><topic>Flux density</topic><topic>Formability</topic><topic>Lithium</topic><topic>Oxide coatings</topic><topic>Polyethylene terephthalate</topic><topic>Rechargeable batteries</topic><topic>Separators</topic><topic>Smart materials</topic><topic>Specific capacity</topic><topic>Substrates</topic><topic>Tungsten</topic><topic>Tungsten oxide</topic><topic>Windows (apertures)</topic><topic>WO3</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Shibin</creatorcontrib><creatorcontrib>Tang, Chengji</creatorcontrib><creatorcontrib>Jiang, Yingchang</creatorcontrib><creatorcontrib>Wang, Dongsheng</creatorcontrib><creatorcontrib>Chang, Xueting</creatorcontrib><creatorcontrib>Lei, Yanhua</creatorcontrib><creatorcontrib>Wang, Nannan</creatorcontrib><creatorcontrib>Zhu, Yanqiu</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Solar energy materials and solar cells</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Shibin</au><au>Tang, Chengji</au><au>Jiang, Yingchang</au><au>Wang, Dongsheng</au><au>Chang, Xueting</au><au>Lei, Yanhua</au><au>Wang, Nannan</au><au>Zhu, Yanqiu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Flexible and rechargeable electrochromic aluminium-ion battery based on tungsten oxide film electrode</atitle><jtitle>Solar energy materials and solar cells</jtitle><date>2020-04</date><risdate>2020</risdate><volume>207</volume><spage>110332</spage><pages>110332-</pages><artnum>110332</artnum><issn>0927-0248</issn><eissn>1879-3398</eissn><abstract>Electrochromic (EC) energy storage devices that possess characteristics of energy storage and electrochromism are highly desirable and have increasingly attracted research interests, whilst devices that can be stretched or are flexible have received very little attention. Herein, we report a flexible and rechargeable aluminium (Al) ion EC battery (ECB), which consists of a WO3 film as positive electrode, PET/ITO as substrate, Al sheet as negative electrode, aluminum trichloride (AlCl3) aqueous solution as electrolyte, and absorptive glass mat (AGM) as electrolyte carrier and separator. The ECB exhibits a high specific capacity of 142 mAhg−1, while demonstrating reversible color transitions between white (bleached state) and dark blue (colored state) during the cyclic charge/discharge processes. Furthermore, the ECB can work at bending angles of 0-80° with a capacity retention of 92.3% after 40 bending cycles. The flexibility of the ECB is ascribed to the flexible, porous, and highly stable features of the AGM as well as the deformability of the PET/ITO substrate. The potential widow of the ECB can be largely enhanced by connecting small-sized ECBs internally in series while maintaining the energy density unchanged. The present study demonstrates that the ECB using the AGM as the electrolyte carrier and separator may have great potentials for the construction of both flexible, portable electronics and smart windows.
A flexible and rechargeable electrochromic battery that possesses characteristics of energy storage, electrochromism, and deformability is assembled by using absorptive glass mat (AGM) as the electrolyte carrier and separator. [Display omitted]
•The WO3 films were deposited on the PET/ITO substrate using a magnetron sputtering method.•A flexible and rechargeable ECB was assembled with AGM as electrolyte carrier and separator.•The ECB exhibited high specific capacity (142 mAhg−1) and can work at bending angles of 0-80°.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.solmat.2019.110332</doi></addata></record> |
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| ispartof | Solar energy materials and solar cells, 2020-04, Vol.207, p.110332, Article 110332 |
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| subjects | Absorptive glass mat (AGM) Absorptivity Aluminum Aluminum chloride Aluminum-ion batteries Aqueous solutions Battery Bending Bleaching Chlorides Deformability Electrochromic Electrochromism Electrodes Electrolytes Energy storage Flexible Flux density Formability Lithium Oxide coatings Polyethylene terephthalate Rechargeable batteries Separators Smart materials Specific capacity Substrates Tungsten Tungsten oxide Windows (apertures) WO3 |
| title | Flexible and rechargeable electrochromic aluminium-ion battery based on tungsten oxide film electrode |
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