Metal-Free Hybrid Capacitor Using Intercalation of 1-Butyl-3-Methylimidazolium Cations
The hybrid capacitor with an activated carbon positive electrode, a carbon negative electrode, and 1-Butyl-3-methylimidazolium tetrafluoroborate (BMIBF4) electrolyte was constructed and investigated as a high-performance hybrid capacitor. Three different carbon materials, Ketjen Black (KB), acetylen...
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Veröffentlicht in: | Denki kagaku oyobi kōgyō butsuri kagaku 2020/03/05, Vol.88(2), pp.60-62 |
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creator | CHIKU, Masanobu TANIMOTO, Yuuya HIGUCHI, Eiji INOUE, Hiroshi |
description | The hybrid capacitor with an activated carbon positive electrode, a carbon negative electrode, and 1-Butyl-3-methylimidazolium tetrafluoroborate (BMIBF4) electrolyte was constructed and investigated as a high-performance hybrid capacitor. Three different carbon materials, Ketjen Black (KB), acetylene black, and graphite, were employed as negative electrode material. The insertion/extraction reaction of BMI+ cations into the carbon negative electrodes was suggested from the strength change of X-ray diffraction peaks. The KB negative electrode showed the highest charge-discharge cycle performance due to the multiple effect of the large surface area and small graphitic crystals, which is flexible to stand for the large volumetric expansion with BMI+ cation insertion reaction. |
doi_str_mv | 10.5796/electrochemistry.20-63003 |
format | Article |
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Three different carbon materials, Ketjen Black (KB), acetylene black, and graphite, were employed as negative electrode material. The insertion/extraction reaction of BMI+ cations into the carbon negative electrodes was suggested from the strength change of X-ray diffraction peaks. The KB negative electrode showed the highest charge-discharge cycle performance due to the multiple effect of the large surface area and small graphitic crystals, which is flexible to stand for the large volumetric expansion with BMI+ cation insertion reaction.</description><identifier>ISSN: 1344-3542</identifier><identifier>EISSN: 2186-2451</identifier><identifier>DOI: 10.5796/electrochemistry.20-63003</identifier><language>eng</language><publisher>Tokyo: The Electrochemical Society of Japan</publisher><subject>1-Butyl-3-methylimidazolium tetrafluoroborate ; Acetylene ; Activated carbon ; Capacitors ; Carbon ; Cations ; Crystals ; Electrode materials ; Electrodes ; Hybrid capacitor ; Insertion ; Ketjen Black ; Lithium ; X-ray diffraction</subject><ispartof>Electrochemistry, 2020/03/05, Vol.88(2), pp.60-62</ispartof><rights>2020 The Electrochemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c479t-f65046c3632cd48b01a53adb7eb304c9da47195cb04a91561d7237017a0a9e3c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,1883,27924,27925</link.rule.ids></links><search><creatorcontrib>CHIKU, Masanobu</creatorcontrib><creatorcontrib>TANIMOTO, Yuuya</creatorcontrib><creatorcontrib>HIGUCHI, Eiji</creatorcontrib><creatorcontrib>INOUE, Hiroshi</creatorcontrib><title>Metal-Free Hybrid Capacitor Using Intercalation of 1-Butyl-3-Methylimidazolium Cations</title><title>Denki kagaku oyobi kōgyō butsuri kagaku</title><addtitle>Electrochemistry</addtitle><description>The hybrid capacitor with an activated carbon positive electrode, a carbon negative electrode, and 1-Butyl-3-methylimidazolium tetrafluoroborate (BMIBF4) electrolyte was constructed and investigated as a high-performance hybrid capacitor. Three different carbon materials, Ketjen Black (KB), acetylene black, and graphite, were employed as negative electrode material. The insertion/extraction reaction of BMI+ cations into the carbon negative electrodes was suggested from the strength change of X-ray diffraction peaks. The KB negative electrode showed the highest charge-discharge cycle performance due to the multiple effect of the large surface area and small graphitic crystals, which is flexible to stand for the large volumetric expansion with BMI+ cation insertion reaction.</description><subject>1-Butyl-3-methylimidazolium tetrafluoroborate</subject><subject>Acetylene</subject><subject>Activated carbon</subject><subject>Capacitors</subject><subject>Carbon</subject><subject>Cations</subject><subject>Crystals</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Hybrid capacitor</subject><subject>Insertion</subject><subject>Ketjen Black</subject><subject>Lithium</subject><subject>X-ray diffraction</subject><issn>1344-3542</issn><issn>2186-2451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNplkD1PwzAURS0EEhX0PwQxG56_kniECigSqAtltV4ch7pKk2K7Q_j1pC1igOXd5Zz7pEvIFYMbVej81rXOptDbldv4mMJww4HmAkCckAlnZU65VOyUTJiQkgol-TmZxrgGAAY611xPyPurS9jSx-BcNh-q4Otshlu0PvUhW0bffWTPXXLBYovJ913WNxmj97s0tFTQUV4Nrd_4Gr_61u82o7yn4iU5a7CNbvqTF2T5-PA2m9OXxdPz7O6FWlnoRJtcgcytyAW3tSwrYKgE1lXhKgHS6hplwbSyFUjUTOWsLrgogBUIqJ2w4oJcH3u3of_cuZjMut-FbnxpRlApEEXJR0ofKRv6GINrzDb4DYbBMDD7Jc3fJQ0Hc1hydBdHdx0TfrhfE0PytnX_zbI0_HB-Gn5Ju8JgXCe-AVkBiVg</recordid><startdate>20200305</startdate><enddate>20200305</enddate><creator>CHIKU, Masanobu</creator><creator>TANIMOTO, Yuuya</creator><creator>HIGUCHI, Eiji</creator><creator>INOUE, Hiroshi</creator><general>The Electrochemical Society of Japan</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QL</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20200305</creationdate><title>Metal-Free Hybrid Capacitor Using Intercalation of 1-Butyl-3-Methylimidazolium Cations</title><author>CHIKU, Masanobu ; TANIMOTO, Yuuya ; HIGUCHI, Eiji ; INOUE, Hiroshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c479t-f65046c3632cd48b01a53adb7eb304c9da47195cb04a91561d7237017a0a9e3c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>1-Butyl-3-methylimidazolium tetrafluoroborate</topic><topic>Acetylene</topic><topic>Activated carbon</topic><topic>Capacitors</topic><topic>Carbon</topic><topic>Cations</topic><topic>Crystals</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Hybrid capacitor</topic><topic>Insertion</topic><topic>Ketjen Black</topic><topic>Lithium</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>CHIKU, Masanobu</creatorcontrib><creatorcontrib>TANIMOTO, Yuuya</creatorcontrib><creatorcontrib>HIGUCHI, Eiji</creatorcontrib><creatorcontrib>INOUE, Hiroshi</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Denki kagaku oyobi kōgyō butsuri kagaku</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>CHIKU, Masanobu</au><au>TANIMOTO, Yuuya</au><au>HIGUCHI, Eiji</au><au>INOUE, Hiroshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal-Free Hybrid Capacitor Using Intercalation of 1-Butyl-3-Methylimidazolium Cations</atitle><jtitle>Denki kagaku oyobi kōgyō butsuri kagaku</jtitle><addtitle>Electrochemistry</addtitle><date>2020-03-05</date><risdate>2020</risdate><volume>88</volume><issue>2</issue><spage>60</spage><epage>62</epage><pages>60-62</pages><issn>1344-3542</issn><eissn>2186-2451</eissn><abstract>The hybrid capacitor with an activated carbon positive electrode, a carbon negative electrode, and 1-Butyl-3-methylimidazolium tetrafluoroborate (BMIBF4) electrolyte was constructed and investigated as a high-performance hybrid capacitor. Three different carbon materials, Ketjen Black (KB), acetylene black, and graphite, were employed as negative electrode material. The insertion/extraction reaction of BMI+ cations into the carbon negative electrodes was suggested from the strength change of X-ray diffraction peaks. The KB negative electrode showed the highest charge-discharge cycle performance due to the multiple effect of the large surface area and small graphitic crystals, which is flexible to stand for the large volumetric expansion with BMI+ cation insertion reaction.</abstract><cop>Tokyo</cop><pub>The Electrochemical Society of Japan</pub><doi>10.5796/electrochemistry.20-63003</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
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subjects | 1-Butyl-3-methylimidazolium tetrafluoroborate Acetylene Activated carbon Capacitors Carbon Cations Crystals Electrode materials Electrodes Hybrid capacitor Insertion Ketjen Black Lithium X-ray diffraction |
title | Metal-Free Hybrid Capacitor Using Intercalation of 1-Butyl-3-Methylimidazolium Cations |
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