Infrared Multiple Photon Dissociation of Chloromethyltrifluorosilane
Infrared multiphoton absorption and dissociation of chloromethyltrifluorosilane molecules under the action of pulsed transversely excited atmospheric pressure CO2 laser were experimentally studied. Dissociation products were analyzed. The dissociation proceeds via chlorine atom transfer from carbon...
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| Veröffentlicht in: | Photochemistry and photobiology 2009-07, Vol.85 (4), p.901-908 |
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| container_end_page | 908 |
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| container_issue | 4 |
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| container_title | Photochemistry and photobiology |
| container_volume | 85 |
| creator | Koshlyakov, Pavel V. Gorelik, Sergey R. Chesnokov, Evgeniy N. Aseev, Oleg S. Rakhymzhan, Asylkhan A. Petrov, Alexander K. |
| description | Infrared multiphoton absorption and dissociation of chloromethyltrifluorosilane molecules under the action of pulsed transversely excited atmospheric pressure CO2 laser were experimentally studied. Dissociation products were analyzed. The dissociation proceeds via chlorine atom transfer from carbon to silicone. High degrees of silicon isotope separation were achieved. The presence of α‐chlorine atom in a silicon organic compound brings about a significant improvement in multiple photon dissociation characteristics and an essential increase in isotopic selectivity. |
| doi_str_mv | 10.1111/j.1751-1097.2009.00541.x |
| format | Article |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | Infrared Multiple Photon Dissociation of Chloromethyltrifluorosilane |
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