Transparent ZnO-coated polydimethylsiloxane-based material for photocatalytic purification applications
We describe production and photocatalytic properties of a material based on polydimethylsiloxane (PDMS) as a carrier substrate coated with microparticles of zinc oxide (ZnO). The ZnO microparticles are fabricated by our original hydrothermal method and intentionally have a defect structure. Accordin...
Gespeichert in:
Veröffentlicht in: | JCT research 2020-03, Vol.17 (2), p.573-579 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 579 |
---|---|
container_issue | 2 |
container_start_page | 573 |
container_title | JCT research |
container_volume | 17 |
creator | Sosnin, I. M. Vlassov, S. Akimov, E. G. Agenkov, V. I. Dorogin, L. M. |
description | We describe production and photocatalytic properties of a material based on polydimethylsiloxane (PDMS) as a carrier substrate coated with microparticles of zinc oxide (ZnO). The ZnO microparticles are fabricated by our original hydrothermal method and intentionally have a defect structure. According to our understanding, this peculiar defect structure contributes to the greatly enhanced photocatalytic properties of the ZnO material. The resulting photocatalyst demonstrates high activity under visible light (410 nm) in the process of phenol degradation in water solution, while generally ZnO is inactive below the UV range. In addition, we compare the photocatalytic activity of our ZnO/PDMS composite to that of the same ZnO powder suspension in a similar setup. We find that the same activity is achieved by three orders of magnitude smaller amount of ZnO in our composite compared to the powder suspension. The ZnO/PDMS interface exhibits sufficiently strong bonding for stable operation that is ensured during material production. The obtained photocatalytic material preserves the transparency of PDMS due to the low amount of attached ZnO (about 0.1% by mass). The transparency of the photocatalytic ZnO/PDMS material enables easy performance upgrades by constructing multilayer or manifold fluid treatment devices. |
doi_str_mv | 10.1007/s11998-019-00314-2 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2371171191</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2371171191</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-8f4e7c17f996688bfb8e26ab5d0171f0a2bacf7ffa8f80accae4e86843f384473</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhoMoWKt_wNOC52iyyW6SoxS_oNBLvXgJs2nSpmw3a7IF998b3YI3TzPD-zHwIHRLyT0lRDwkSpWSmFCFCWGU4_IMzahiFWaS8PO8V1xkSdFLdJXSnpBSSMlmaLuO0KUeou2G4qNbYRNgsJuiD-248Qc77MY2-TZ8QWdxAylLh2yIHtrChVj0uzAEAwO04-BN0R-jdz7fPnQF9H172tM1unDQJntzmnP0_vy0Xrzi5erlbfG4xIZV9YCl41YYKpxSdS1l4xppyxqaakOooI5A2YBxwjmQThIwBiy3spacOSY5F2yO7qbePobPo02D3odj7PJLXTJBcwlVNLvKyWViSClap_voDxBHTYn-AaonoDoD1b9Ac3qO2BRK2dxtbfyr_if1DYCtfFY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2371171191</pqid></control><display><type>article</type><title>Transparent ZnO-coated polydimethylsiloxane-based material for photocatalytic purification applications</title><source>SpringerNature Journals</source><creator>Sosnin, I. M. ; Vlassov, S. ; Akimov, E. G. ; Agenkov, V. I. ; Dorogin, L. M.</creator><creatorcontrib>Sosnin, I. M. ; Vlassov, S. ; Akimov, E. G. ; Agenkov, V. I. ; Dorogin, L. M.</creatorcontrib><description>We describe production and photocatalytic properties of a material based on polydimethylsiloxane (PDMS) as a carrier substrate coated with microparticles of zinc oxide (ZnO). The ZnO microparticles are fabricated by our original hydrothermal method and intentionally have a defect structure. According to our understanding, this peculiar defect structure contributes to the greatly enhanced photocatalytic properties of the ZnO material. The resulting photocatalyst demonstrates high activity under visible light (410 nm) in the process of phenol degradation in water solution, while generally ZnO is inactive below the UV range. In addition, we compare the photocatalytic activity of our ZnO/PDMS composite to that of the same ZnO powder suspension in a similar setup. We find that the same activity is achieved by three orders of magnitude smaller amount of ZnO in our composite compared to the powder suspension. The ZnO/PDMS interface exhibits sufficiently strong bonding for stable operation that is ensured during material production. The obtained photocatalytic material preserves the transparency of PDMS due to the low amount of attached ZnO (about 0.1% by mass). The transparency of the photocatalytic ZnO/PDMS material enables easy performance upgrades by constructing multilayer or manifold fluid treatment devices.</description><identifier>ISSN: 1547-0091</identifier><identifier>EISSN: 1935-3804</identifier><identifier>EISSN: 2168-8028</identifier><identifier>DOI: 10.1007/s11998-019-00314-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Bonding strength ; Brief Communication ; Catalytic activity ; Chemistry and Materials Science ; Corrosion and Coatings ; Industrial Chemistry/Chemical Engineering ; Materials Science ; Microparticles ; Multilayers ; Photocatalysis ; Polydimethylsiloxane ; Polymer Sciences ; Silicone resins ; Substrates ; Surfaces and Interfaces ; Thin Films ; Tribology ; Zinc oxide ; Zinc oxides</subject><ispartof>JCT research, 2020-03, Vol.17 (2), p.573-579</ispartof><rights>American Coatings Association 2020</rights><rights>2020© American Coatings Association 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-8f4e7c17f996688bfb8e26ab5d0171f0a2bacf7ffa8f80accae4e86843f384473</citedby><cites>FETCH-LOGICAL-c356t-8f4e7c17f996688bfb8e26ab5d0171f0a2bacf7ffa8f80accae4e86843f384473</cites><orcidid>0000-0002-4457-1820</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11998-019-00314-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11998-019-00314-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Sosnin, I. M.</creatorcontrib><creatorcontrib>Vlassov, S.</creatorcontrib><creatorcontrib>Akimov, E. G.</creatorcontrib><creatorcontrib>Agenkov, V. I.</creatorcontrib><creatorcontrib>Dorogin, L. M.</creatorcontrib><title>Transparent ZnO-coated polydimethylsiloxane-based material for photocatalytic purification applications</title><title>JCT research</title><addtitle>J Coat Technol Res</addtitle><description>We describe production and photocatalytic properties of a material based on polydimethylsiloxane (PDMS) as a carrier substrate coated with microparticles of zinc oxide (ZnO). The ZnO microparticles are fabricated by our original hydrothermal method and intentionally have a defect structure. According to our understanding, this peculiar defect structure contributes to the greatly enhanced photocatalytic properties of the ZnO material. The resulting photocatalyst demonstrates high activity under visible light (410 nm) in the process of phenol degradation in water solution, while generally ZnO is inactive below the UV range. In addition, we compare the photocatalytic activity of our ZnO/PDMS composite to that of the same ZnO powder suspension in a similar setup. We find that the same activity is achieved by three orders of magnitude smaller amount of ZnO in our composite compared to the powder suspension. The ZnO/PDMS interface exhibits sufficiently strong bonding for stable operation that is ensured during material production. The obtained photocatalytic material preserves the transparency of PDMS due to the low amount of attached ZnO (about 0.1% by mass). The transparency of the photocatalytic ZnO/PDMS material enables easy performance upgrades by constructing multilayer or manifold fluid treatment devices.</description><subject>Bonding strength</subject><subject>Brief Communication</subject><subject>Catalytic activity</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion and Coatings</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Materials Science</subject><subject>Microparticles</subject><subject>Multilayers</subject><subject>Photocatalysis</subject><subject>Polydimethylsiloxane</subject><subject>Polymer Sciences</subject><subject>Silicone resins</subject><subject>Substrates</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Tribology</subject><subject>Zinc oxide</subject><subject>Zinc oxides</subject><issn>1547-0091</issn><issn>1935-3804</issn><issn>2168-8028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wNOC52iyyW6SoxS_oNBLvXgJs2nSpmw3a7IF998b3YI3TzPD-zHwIHRLyT0lRDwkSpWSmFCFCWGU4_IMzahiFWaS8PO8V1xkSdFLdJXSnpBSSMlmaLuO0KUeou2G4qNbYRNgsJuiD-248Qc77MY2-TZ8QWdxAylLh2yIHtrChVj0uzAEAwO04-BN0R-jdz7fPnQF9H172tM1unDQJntzmnP0_vy0Xrzi5erlbfG4xIZV9YCl41YYKpxSdS1l4xppyxqaakOooI5A2YBxwjmQThIwBiy3spacOSY5F2yO7qbePobPo02D3odj7PJLXTJBcwlVNLvKyWViSClap_voDxBHTYn-AaonoDoD1b9Ac3qO2BRK2dxtbfyr_if1DYCtfFY</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Sosnin, I. M.</creator><creator>Vlassov, S.</creator><creator>Akimov, E. G.</creator><creator>Agenkov, V. I.</creator><creator>Dorogin, L. M.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-4457-1820</orcidid></search><sort><creationdate>20200301</creationdate><title>Transparent ZnO-coated polydimethylsiloxane-based material for photocatalytic purification applications</title><author>Sosnin, I. M. ; Vlassov, S. ; Akimov, E. G. ; Agenkov, V. I. ; Dorogin, L. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-8f4e7c17f996688bfb8e26ab5d0171f0a2bacf7ffa8f80accae4e86843f384473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Bonding strength</topic><topic>Brief Communication</topic><topic>Catalytic activity</topic><topic>Chemistry and Materials Science</topic><topic>Corrosion and Coatings</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Materials Science</topic><topic>Microparticles</topic><topic>Multilayers</topic><topic>Photocatalysis</topic><topic>Polydimethylsiloxane</topic><topic>Polymer Sciences</topic><topic>Silicone resins</topic><topic>Substrates</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>Tribology</topic><topic>Zinc oxide</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sosnin, I. M.</creatorcontrib><creatorcontrib>Vlassov, S.</creatorcontrib><creatorcontrib>Akimov, E. G.</creatorcontrib><creatorcontrib>Agenkov, V. I.</creatorcontrib><creatorcontrib>Dorogin, L. M.</creatorcontrib><collection>CrossRef</collection><jtitle>JCT research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sosnin, I. M.</au><au>Vlassov, S.</au><au>Akimov, E. G.</au><au>Agenkov, V. I.</au><au>Dorogin, L. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transparent ZnO-coated polydimethylsiloxane-based material for photocatalytic purification applications</atitle><jtitle>JCT research</jtitle><stitle>J Coat Technol Res</stitle><date>2020-03-01</date><risdate>2020</risdate><volume>17</volume><issue>2</issue><spage>573</spage><epage>579</epage><pages>573-579</pages><issn>1547-0091</issn><eissn>1935-3804</eissn><eissn>2168-8028</eissn><abstract>We describe production and photocatalytic properties of a material based on polydimethylsiloxane (PDMS) as a carrier substrate coated with microparticles of zinc oxide (ZnO). The ZnO microparticles are fabricated by our original hydrothermal method and intentionally have a defect structure. According to our understanding, this peculiar defect structure contributes to the greatly enhanced photocatalytic properties of the ZnO material. The resulting photocatalyst demonstrates high activity under visible light (410 nm) in the process of phenol degradation in water solution, while generally ZnO is inactive below the UV range. In addition, we compare the photocatalytic activity of our ZnO/PDMS composite to that of the same ZnO powder suspension in a similar setup. We find that the same activity is achieved by three orders of magnitude smaller amount of ZnO in our composite compared to the powder suspension. The ZnO/PDMS interface exhibits sufficiently strong bonding for stable operation that is ensured during material production. The obtained photocatalytic material preserves the transparency of PDMS due to the low amount of attached ZnO (about 0.1% by mass). The transparency of the photocatalytic ZnO/PDMS material enables easy performance upgrades by constructing multilayer or manifold fluid treatment devices.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11998-019-00314-2</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-4457-1820</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1547-0091 |
ispartof | JCT research, 2020-03, Vol.17 (2), p.573-579 |
issn | 1547-0091 1935-3804 2168-8028 |
language | eng |
recordid | cdi_proquest_journals_2371171191 |
source | SpringerNature Journals |
subjects | Bonding strength Brief Communication Catalytic activity Chemistry and Materials Science Corrosion and Coatings Industrial Chemistry/Chemical Engineering Materials Science Microparticles Multilayers Photocatalysis Polydimethylsiloxane Polymer Sciences Silicone resins Substrates Surfaces and Interfaces Thin Films Tribology Zinc oxide Zinc oxides |
title | Transparent ZnO-coated polydimethylsiloxane-based material for photocatalytic purification applications |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-19T03%3A09%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Transparent%20ZnO-coated%20polydimethylsiloxane-based%20material%20for%20photocatalytic%20purification%20applications&rft.jtitle=JCT%20research&rft.au=Sosnin,%20I.%20M.&rft.date=2020-03-01&rft.volume=17&rft.issue=2&rft.spage=573&rft.epage=579&rft.pages=573-579&rft.issn=1547-0091&rft.eissn=1935-3804&rft_id=info:doi/10.1007/s11998-019-00314-2&rft_dat=%3Cproquest_cross%3E2371171191%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2371171191&rft_id=info:pmid/&rfr_iscdi=true |