Accelerated Polymerization of Ammonium Lignosulfonate from Loblolly Pine
Lignin bioproducts derived from pulping of woody biomass find utility in multiple industrial applications. Ammonium lignosulfonates have historically displayed unique polymerization characteristics relative to other lignin materials and show promise as sustainable adhesives for the panel industry. T...
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| Veröffentlicht in: | Forest products journal 2020-03, Vol.70 (1), p.134-142 |
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| creator | Narron, Robert Wolken, Gregory Gargulak, Jerry |
| description | Lignin bioproducts derived from pulping of woody biomass find utility in multiple industrial applications. Ammonium lignosulfonates have historically displayed unique polymerization characteristics relative to other lignin materials and show promise as sustainable adhesives for the panel industry. To further understand the system's chemistry, polymerization reactions were observed through the lens of viscosity build-up using high temperature rheological measurements. It was found that highly controllable lignosulfonate properties like cooking temperature, pH, and percentage dissolved solids each significantly contribute to gelation behavior. The concept of thermal priming to shorten gelation time was also introduced and demonstrated. Finally, possible applications for this technology are postulated. |
| doi_str_mv | 10.13073/FPJ-D-19-00044 |
| format | Article |
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Ammonium lignosulfonates have historically displayed unique polymerization characteristics relative to other lignin materials and show promise as sustainable adhesives for the panel industry. To further understand the system's chemistry, polymerization reactions were observed through the lens of viscosity build-up using high temperature rheological measurements. It was found that highly controllable lignosulfonate properties like cooking temperature, pH, and percentage dissolved solids each significantly contribute to gelation behavior. The concept of thermal priming to shorten gelation time was also introduced and demonstrated. Finally, possible applications for this technology are postulated.</description><identifier>ISSN: 0015-7473</identifier><identifier>EISSN: 2376-9637</identifier><identifier>DOI: 10.13073/FPJ-D-19-00044</identifier><language>eng</language><publisher>Madison: Forest Products Society</publisher><subject>Ammonium ; Analysis ; Biomass ; By-products ; Chemical properties ; Cooking ; Dissolved solids ; Forest products industry ; Gelation ; High temperature ; Industrial applications ; Lignin ; Lignosulfonates ; Loblolly pine ; Materials ; Mechanical properties ; Molecular weight ; Organic chemistry ; Pine trees ; Polymerization ; Priming ; Production capacity ; Pulping ; Rheological properties ; Rheology ; Software ; Sulfonation ; Temperature ; Thermal properties ; Viscosity ; Wood adhesives ; Wood pulping</subject><ispartof>Forest products journal, 2020-03, Vol.70 (1), p.134-142</ispartof><rights>COPYRIGHT 2020 Forest Products Society</rights><rights>Copyright Forest Products Society 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Narron, Robert</creatorcontrib><creatorcontrib>Wolken, Gregory</creatorcontrib><creatorcontrib>Gargulak, Jerry</creatorcontrib><title>Accelerated Polymerization of Ammonium Lignosulfonate from Loblolly Pine</title><title>Forest products journal</title><description>Lignin bioproducts derived from pulping of woody biomass find utility in multiple industrial applications. Ammonium lignosulfonates have historically displayed unique polymerization characteristics relative to other lignin materials and show promise as sustainable adhesives for the panel industry. To further understand the system's chemistry, polymerization reactions were observed through the lens of viscosity build-up using high temperature rheological measurements. It was found that highly controllable lignosulfonate properties like cooking temperature, pH, and percentage dissolved solids each significantly contribute to gelation behavior. The concept of thermal priming to shorten gelation time was also introduced and demonstrated. Finally, possible applications for this technology are postulated.</description><subject>Ammonium</subject><subject>Analysis</subject><subject>Biomass</subject><subject>By-products</subject><subject>Chemical properties</subject><subject>Cooking</subject><subject>Dissolved solids</subject><subject>Forest products industry</subject><subject>Gelation</subject><subject>High temperature</subject><subject>Industrial applications</subject><subject>Lignin</subject><subject>Lignosulfonates</subject><subject>Loblolly pine</subject><subject>Materials</subject><subject>Mechanical properties</subject><subject>Molecular weight</subject><subject>Organic chemistry</subject><subject>Pine trees</subject><subject>Polymerization</subject><subject>Priming</subject><subject>Production capacity</subject><subject>Pulping</subject><subject>Rheological properties</subject><subject>Rheology</subject><subject>Software</subject><subject>Sulfonation</subject><subject>Temperature</subject><subject>Thermal properties</subject><subject>Viscosity</subject><subject>Wood adhesives</subject><subject>Wood 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Polymerization of Ammonium Lignosulfonate from Loblolly Pine</title><author>Narron, Robert ; Wolken, Gregory ; Gargulak, Jerry</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c365t-516f1ff474417872ff46fad3c6da72680461fb192171d6e30be3187db7b190893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Ammonium</topic><topic>Analysis</topic><topic>Biomass</topic><topic>By-products</topic><topic>Chemical properties</topic><topic>Cooking</topic><topic>Dissolved solids</topic><topic>Forest products industry</topic><topic>Gelation</topic><topic>High temperature</topic><topic>Industrial applications</topic><topic>Lignin</topic><topic>Lignosulfonates</topic><topic>Loblolly pine</topic><topic>Materials</topic><topic>Mechanical properties</topic><topic>Molecular weight</topic><topic>Organic chemistry</topic><topic>Pine 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Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Narron, Robert</au><au>Wolken, Gregory</au><au>Gargulak, Jerry</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Accelerated Polymerization of Ammonium Lignosulfonate from Loblolly Pine</atitle><jtitle>Forest products journal</jtitle><date>2020-03-22</date><risdate>2020</risdate><volume>70</volume><issue>1</issue><spage>134</spage><epage>142</epage><pages>134-142</pages><issn>0015-7473</issn><eissn>2376-9637</eissn><abstract>Lignin bioproducts derived from pulping of woody biomass find utility in multiple industrial applications. Ammonium lignosulfonates have historically displayed unique polymerization characteristics relative to other lignin materials and show promise as sustainable adhesives for the panel industry. To further understand the system's chemistry, polymerization reactions were observed through the lens of viscosity build-up using high temperature rheological measurements. It was found that highly controllable lignosulfonate properties like cooking temperature, pH, and percentage dissolved solids each significantly contribute to gelation behavior. The concept of thermal priming to shorten gelation time was also introduced and demonstrated. Finally, possible applications for this technology are postulated.</abstract><cop>Madison</cop><pub>Forest Products Society</pub><doi>10.13073/FPJ-D-19-00044</doi><tpages>9</tpages></addata></record> |
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| source | Allen Press Journals; EBSCOhost Business Source Complete; Alma/SFX Local Collection |
| subjects | Ammonium Analysis Biomass By-products Chemical properties Cooking Dissolved solids Forest products industry Gelation High temperature Industrial applications Lignin Lignosulfonates Loblolly pine Materials Mechanical properties Molecular weight Organic chemistry Pine trees Polymerization Priming Production capacity Pulping Rheological properties Rheology Software Sulfonation Temperature Thermal properties Viscosity Wood adhesives Wood pulping |
| title | Accelerated Polymerization of Ammonium Lignosulfonate from Loblolly Pine |
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