Clay content and mineralogy, organic carbon and cation exchange capacity affect water vapour sorption hysteresis of soil
The hysteretic behaviour of the dry region (
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| Veröffentlicht in: | European journal of soil science 2020-03, Vol.71 (2), p.204-214 |
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| container_title | European journal of soil science |
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| creator | Arthur, Emmanuel Tuller, Markus Moldrup, Per Jonge, Lis W. |
| description | The hysteretic behaviour of the dry region ( |
| doi_str_mv | 10.1111/ejss.12853 |
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Highlights
A new index for quantification of soil vapour sorption hysteresis was proposed
Large SOC and clay content increased sorption hysteresis
For soil samples, dominant clay mineralogy controlled the magnitude of hysteresis
Cation exchange capacity was the best predictor of hysteresis for all soil types</description><identifier>ISSN: 1351-0754</identifier><identifier>EISSN: 1365-2389</identifier><identifier>DOI: 10.1111/ejss.12853</identifier><language>eng</language><publisher>Oxford, UK: Blackwell Publishing Ltd</publisher><subject>Carbon ; Carbon content ; Cation exchange ; Cation exchanging ; Cations ; CEC ; Clay ; Clay minerals ; Clay soils ; dry region soil water characteristic ; Exchange capacity ; Hysteresis ; Illite ; Illites ; Kaolinite ; Mineralogy ; Minerals ; Moisture content ; Organic carbon ; Organic soils ; Smectites ; Soil conditions ; soil organic carbon ; soil particle size distribution ; Soil properties ; Soil texture ; Soil types ; Soil water ; Sorption ; Texture ; Water vapor ; Water vapour</subject><ispartof>European journal of soil science, 2020-03, Vol.71 (2), p.204-214</ispartof><rights>2019 British Society of Soil Science</rights><rights>2020 British Society of Soil Science</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3373-e362db26c92a190cc34965eb13ab601d464a9b57b9f2c89eaab316bed8eec7333</citedby><cites>FETCH-LOGICAL-c3373-e362db26c92a190cc34965eb13ab601d464a9b57b9f2c89eaab316bed8eec7333</cites><orcidid>0000-0002-0788-0712</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fejss.12853$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fejss.12853$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Arthur, Emmanuel</creatorcontrib><creatorcontrib>Tuller, Markus</creatorcontrib><creatorcontrib>Moldrup, Per</creatorcontrib><creatorcontrib>Jonge, Lis W.</creatorcontrib><title>Clay content and mineralogy, organic carbon and cation exchange capacity affect water vapour sorption hysteresis of soil</title><title>European journal of soil science</title><description>The hysteretic behaviour of the dry region (<−1.5 MPa) of the soil water characteristic, which is of the essence for accurate characterization and modelling of bio‐physicochemical soil processes under dry conditions, is well documented. However, knowledge about how to best quantify water vapour sorption hysteresis and about the effects of soil properties on dry‐region hysteretic behaviour is limited. To overcome this knowledge gap, we proposed a new method for quantifying sorption hysteresis and evaluated its applicability based on measured sorption isotherms of four source clay minerals and 147 soil samples. Furthermore, the effects of clay mineralogy, clay content, soil organic carbon (SOC) and cation exchange capacity (CEC) on the magnitude of sorption hysteresis were investigated. For the clay minerals, kaolinite did not exhibit hysteretic behaviour, illite showed some hysteresis, whereas Na‐ and Ca‐smectite exhibited strong hysteretic behaviour. The average hysteresis, corrected for clay and SOC contents, was strongly reflective of the dominant clay mineralogy of the soil samples. For the soil samples with low SOC content, the average hysteresis significantly increased with increasing clay content (R2 = 0.92), except for the kaolinite‐rich samples (R2 = 0.35). The SOC‐rich samples that exhibited illitic clay mineralogy and similar soil texture showed a significant increase in average hysteresis with increasing organic carbon content (R2 = 0.93). For all soil samples combined, the CEC was the strongest indicator for the magnitude of water vapour sorption hysteresis.
Highlights
A new index for quantification of soil vapour sorption hysteresis was proposed
Large SOC and clay content increased sorption hysteresis
For soil samples, dominant clay mineralogy controlled the magnitude of hysteresis
Cation exchange capacity was the best predictor of hysteresis for all soil types</description><subject>Carbon</subject><subject>Carbon content</subject><subject>Cation exchange</subject><subject>Cation exchanging</subject><subject>Cations</subject><subject>CEC</subject><subject>Clay</subject><subject>Clay minerals</subject><subject>Clay soils</subject><subject>dry region soil water characteristic</subject><subject>Exchange capacity</subject><subject>Hysteresis</subject><subject>Illite</subject><subject>Illites</subject><subject>Kaolinite</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Moisture content</subject><subject>Organic carbon</subject><subject>Organic soils</subject><subject>Smectites</subject><subject>Soil conditions</subject><subject>soil organic carbon</subject><subject>soil particle size distribution</subject><subject>Soil properties</subject><subject>Soil texture</subject><subject>Soil types</subject><subject>Soil water</subject><subject>Sorption</subject><subject>Texture</subject><subject>Water vapor</subject><subject>Water vapour</subject><issn>1351-0754</issn><issn>1365-2389</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kMlOwzAQhi0EEqVw4QkscUOkeGkWH1FVNlXiUDhHY2fSpkrjYKe0eXvchjNzme2bRT8ht5xNeLBH3Hg_4SKL5RkZcZnEkZCZOj_GMY9YGk8vyZX3G8a45EqNyGFWQ0-NbTpsOgpNQbdVgw5qu-ofqHUraCpDDThtm1PbQFeFEA9mDc0KQ96CqbqeQlmi6egeOnT0B1q7c9Rb157wde9DGX3lqS1DuaqvyUUJtcebPz8mX8_zz9lrtPh4eZs9LSIjZSojlIkotEiMEsAVM0ZOVRKj5hJ0wngxTaagdJxqVQqTKQTQkicaiwzRpFLKMbkb9rbOfu_Qd_kmfNaEk7mQKROZSEUcqPuBMs5677DMW1dtwfU5Z_lR2fyobH5SNsB8gPdVjf0_ZD5_Xy6HmV-ffH37</recordid><startdate>202003</startdate><enddate>202003</enddate><creator>Arthur, Emmanuel</creator><creator>Tuller, Markus</creator><creator>Moldrup, Per</creator><creator>Jonge, Lis W.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QL</scope><scope>7SN</scope><scope>7ST</scope><scope>7T7</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>FR3</scope><scope>H96</scope><scope>L.G</scope><scope>P64</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-0788-0712</orcidid></search><sort><creationdate>202003</creationdate><title>Clay content and mineralogy, organic carbon and cation exchange capacity affect water vapour sorption hysteresis of soil</title><author>Arthur, Emmanuel ; Tuller, Markus ; Moldrup, Per ; Jonge, Lis W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3373-e362db26c92a190cc34965eb13ab601d464a9b57b9f2c89eaab316bed8eec7333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Carbon</topic><topic>Carbon content</topic><topic>Cation exchange</topic><topic>Cation exchanging</topic><topic>Cations</topic><topic>CEC</topic><topic>Clay</topic><topic>Clay minerals</topic><topic>Clay soils</topic><topic>dry region soil water characteristic</topic><topic>Exchange capacity</topic><topic>Hysteresis</topic><topic>Illite</topic><topic>Illites</topic><topic>Kaolinite</topic><topic>Mineralogy</topic><topic>Minerals</topic><topic>Moisture content</topic><topic>Organic carbon</topic><topic>Organic soils</topic><topic>Smectites</topic><topic>Soil conditions</topic><topic>soil organic carbon</topic><topic>soil particle size distribution</topic><topic>Soil properties</topic><topic>Soil texture</topic><topic>Soil types</topic><topic>Soil water</topic><topic>Sorption</topic><topic>Texture</topic><topic>Water vapor</topic><topic>Water vapour</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arthur, Emmanuel</creatorcontrib><creatorcontrib>Tuller, Markus</creatorcontrib><creatorcontrib>Moldrup, Per</creatorcontrib><creatorcontrib>Jonge, Lis W.</creatorcontrib><collection>CrossRef</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>European journal of soil science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arthur, Emmanuel</au><au>Tuller, Markus</au><au>Moldrup, Per</au><au>Jonge, Lis W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Clay content and mineralogy, organic carbon and cation exchange capacity affect water vapour sorption hysteresis of soil</atitle><jtitle>European journal of soil science</jtitle><date>2020-03</date><risdate>2020</risdate><volume>71</volume><issue>2</issue><spage>204</spage><epage>214</epage><pages>204-214</pages><issn>1351-0754</issn><eissn>1365-2389</eissn><abstract>The hysteretic behaviour of the dry region (<−1.5 MPa) of the soil water characteristic, which is of the essence for accurate characterization and modelling of bio‐physicochemical soil processes under dry conditions, is well documented. However, knowledge about how to best quantify water vapour sorption hysteresis and about the effects of soil properties on dry‐region hysteretic behaviour is limited. To overcome this knowledge gap, we proposed a new method for quantifying sorption hysteresis and evaluated its applicability based on measured sorption isotherms of four source clay minerals and 147 soil samples. Furthermore, the effects of clay mineralogy, clay content, soil organic carbon (SOC) and cation exchange capacity (CEC) on the magnitude of sorption hysteresis were investigated. For the clay minerals, kaolinite did not exhibit hysteretic behaviour, illite showed some hysteresis, whereas Na‐ and Ca‐smectite exhibited strong hysteretic behaviour. The average hysteresis, corrected for clay and SOC contents, was strongly reflective of the dominant clay mineralogy of the soil samples. For the soil samples with low SOC content, the average hysteresis significantly increased with increasing clay content (R2 = 0.92), except for the kaolinite‐rich samples (R2 = 0.35). The SOC‐rich samples that exhibited illitic clay mineralogy and similar soil texture showed a significant increase in average hysteresis with increasing organic carbon content (R2 = 0.93). For all soil samples combined, the CEC was the strongest indicator for the magnitude of water vapour sorption hysteresis.
Highlights
A new index for quantification of soil vapour sorption hysteresis was proposed
Large SOC and clay content increased sorption hysteresis
For soil samples, dominant clay mineralogy controlled the magnitude of hysteresis
Cation exchange capacity was the best predictor of hysteresis for all soil types</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/ejss.12853</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-0788-0712</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Carbon Carbon content Cation exchange Cation exchanging Cations CEC Clay Clay minerals Clay soils dry region soil water characteristic Exchange capacity Hysteresis Illite Illites Kaolinite Mineralogy Minerals Moisture content Organic carbon Organic soils Smectites Soil conditions soil organic carbon soil particle size distribution Soil properties Soil texture Soil types Soil water Sorption Texture Water vapor Water vapour |
| title | Clay content and mineralogy, organic carbon and cation exchange capacity affect water vapour sorption hysteresis of soil |
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