Green synthesis of silver nanoparticles (SNPs)-modified electrode for electrochemical detection of nitrobenzene
Nitrobenzene (NB) is a highly toxic and hazardous compound that needs to be detected at the low level. The current work describes an eco-friendly synthesis of silver nanoparticles (SNPs) using a Eucalyptus extract as reducing and stabilizing agent and its use for electrochemical detection of NB. The...
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| Veröffentlicht in: | Journal of the Iranian Chemical Society 2020-04, Vol.17 (4), p.893-900 |
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| creator | Shivakumar, M. Dharmaprakash, M. S. Manjappa, S. Nagashree, K. L. |
| description | Nitrobenzene (NB) is a highly toxic and hazardous compound that needs to be detected at the low level. The current work describes an eco-friendly synthesis of silver nanoparticles (SNPs) using a
Eucalyptus
extract as reducing and stabilizing agent and its use for electrochemical detection of NB. The synthesized SNPs were characterized by following techniques UV–visible spectroscopy, powder X-ray diffraction, FESEM, HRTEM and TEM, FTIR spectroscopy. Further electrochemical investigation of SNPs-modified glassy carbon electrode (SNPs/GCE) is carried out by cyclic voltammetric and differential pulse voltammetric techniques. The prepared NPs exhibit excellent electrochemical behaviour towards reduction of NB and show a linear response in the range 5–40 µM, sensitivity of 2.262 µA µM
−1
cm
−2
and limit of detection of 0.027 µM. SNPs/GCE shows good selectivity towards NB detection. Also, the system exhibits a considerable recovery towards NB detection in of water and waste samples. |
| doi_str_mv | 10.1007/s13738-019-01822-z |
| format | Article |
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Eucalyptus
extract as reducing and stabilizing agent and its use for electrochemical detection of NB. The synthesized SNPs were characterized by following techniques UV–visible spectroscopy, powder X-ray diffraction, FESEM, HRTEM and TEM, FTIR spectroscopy. Further electrochemical investigation of SNPs-modified glassy carbon electrode (SNPs/GCE) is carried out by cyclic voltammetric and differential pulse voltammetric techniques. The prepared NPs exhibit excellent electrochemical behaviour towards reduction of NB and show a linear response in the range 5–40 µM, sensitivity of 2.262 µA µM
−1
cm
−2
and limit of detection of 0.027 µM. SNPs/GCE shows good selectivity towards NB detection. Also, the system exhibits a considerable recovery towards NB detection in of water and waste samples.</description><identifier>ISSN: 1735-207X</identifier><identifier>EISSN: 1735-2428</identifier><identifier>DOI: 10.1007/s13738-019-01822-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Biochemistry ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Electrochemical analysis ; Electrodes ; Eucalyptus ; Glassy carbon ; Inorganic Chemistry ; Low level ; Nanoparticles ; Nitrobenzene ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Selectivity ; Silver ; Spectroscopy ; Spectrum analysis ; Stabilizers (agents) ; Voltammetry ; X ray powder diffraction</subject><ispartof>Journal of the Iranian Chemical Society, 2020-04, Vol.17 (4), p.893-900</ispartof><rights>Iranian Chemical Society 2019</rights><rights>2019© Iranian Chemical Society 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-f0e389300f51f83b58c46e20a3d40ff6008d9054dde8836db8bf2952cd8c78203</citedby><cites>FETCH-LOGICAL-c356t-f0e389300f51f83b58c46e20a3d40ff6008d9054dde8836db8bf2952cd8c78203</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13738-019-01822-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13738-019-01822-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Shivakumar, M.</creatorcontrib><creatorcontrib>Dharmaprakash, M. S.</creatorcontrib><creatorcontrib>Manjappa, S.</creatorcontrib><creatorcontrib>Nagashree, K. L.</creatorcontrib><title>Green synthesis of silver nanoparticles (SNPs)-modified electrode for electrochemical detection of nitrobenzene</title><title>Journal of the Iranian Chemical Society</title><addtitle>J IRAN CHEM SOC</addtitle><description>Nitrobenzene (NB) is a highly toxic and hazardous compound that needs to be detected at the low level. The current work describes an eco-friendly synthesis of silver nanoparticles (SNPs) using a
Eucalyptus
extract as reducing and stabilizing agent and its use for electrochemical detection of NB. The synthesized SNPs were characterized by following techniques UV–visible spectroscopy, powder X-ray diffraction, FESEM, HRTEM and TEM, FTIR spectroscopy. Further electrochemical investigation of SNPs-modified glassy carbon electrode (SNPs/GCE) is carried out by cyclic voltammetric and differential pulse voltammetric techniques. The prepared NPs exhibit excellent electrochemical behaviour towards reduction of NB and show a linear response in the range 5–40 µM, sensitivity of 2.262 µA µM
−1
cm
−2
and limit of detection of 0.027 µM. SNPs/GCE shows good selectivity towards NB detection. Also, the system exhibits a considerable recovery towards NB detection in of water and waste samples.</description><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemical analysis</subject><subject>Electrodes</subject><subject>Eucalyptus</subject><subject>Glassy carbon</subject><subject>Inorganic Chemistry</subject><subject>Low level</subject><subject>Nanoparticles</subject><subject>Nitrobenzene</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><subject>Silver</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Stabilizers (agents)</subject><subject>Voltammetry</subject><subject>X ray powder diffraction</subject><issn>1735-207X</issn><issn>1735-2428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LAzEQDaJgrf4BTwte9LA6m-xH9ihFqyAqqOAt7CYTm7JNarIV2l9v6lq8eRjm6703zCPkNIPLDKC6ChmrGE8hq2NwStPNHhllFStSmlO-v6uhej8kRyHMAYoKinxE3NQj2iSsbT_DYELidBJM94U-sY11y8b3RnYYkvOXx-dwkS6cMtqgSrBD2XunMNHO7zo5w4WRTZco7OPAOLvVsyauWrQbtHhMDnTTBTz5zWPydnvzOrlLH56m95Prh1SyouxTDch4zQB0kWnO2oLLvEQKDVM5aF0CcFXHB5RCzlmpWt5qWhdUKi4rToGNydmgu_Tuc4WhF3O38jaeFJSVdQ15SXlE0QElvQvBoxZLbxaNX4sMxNZYMRgrorHix1ixiSQ2kEIE2w_0f9L_sL4BR9Z9xg</recordid><startdate>20200401</startdate><enddate>20200401</enddate><creator>Shivakumar, M.</creator><creator>Dharmaprakash, M. S.</creator><creator>Manjappa, S.</creator><creator>Nagashree, K. L.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200401</creationdate><title>Green synthesis of silver nanoparticles (SNPs)-modified electrode for electrochemical detection of nitrobenzene</title><author>Shivakumar, M. ; Dharmaprakash, M. S. ; Manjappa, S. ; Nagashree, K. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-f0e389300f51f83b58c46e20a3d40ff6008d9054dde8836db8bf2952cd8c78203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrochemical analysis</topic><topic>Electrodes</topic><topic>Eucalyptus</topic><topic>Glassy carbon</topic><topic>Inorganic Chemistry</topic><topic>Low level</topic><topic>Nanoparticles</topic><topic>Nitrobenzene</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><topic>Silver</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Stabilizers (agents)</topic><topic>Voltammetry</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shivakumar, M.</creatorcontrib><creatorcontrib>Dharmaprakash, M. S.</creatorcontrib><creatorcontrib>Manjappa, S.</creatorcontrib><creatorcontrib>Nagashree, K. L.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Iranian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shivakumar, M.</au><au>Dharmaprakash, M. S.</au><au>Manjappa, S.</au><au>Nagashree, K. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Green synthesis of silver nanoparticles (SNPs)-modified electrode for electrochemical detection of nitrobenzene</atitle><jtitle>Journal of the Iranian Chemical Society</jtitle><stitle>J IRAN CHEM SOC</stitle><date>2020-04-01</date><risdate>2020</risdate><volume>17</volume><issue>4</issue><spage>893</spage><epage>900</epage><pages>893-900</pages><issn>1735-207X</issn><eissn>1735-2428</eissn><abstract>Nitrobenzene (NB) is a highly toxic and hazardous compound that needs to be detected at the low level. The current work describes an eco-friendly synthesis of silver nanoparticles (SNPs) using a
Eucalyptus
extract as reducing and stabilizing agent and its use for electrochemical detection of NB. The synthesized SNPs were characterized by following techniques UV–visible spectroscopy, powder X-ray diffraction, FESEM, HRTEM and TEM, FTIR spectroscopy. Further electrochemical investigation of SNPs-modified glassy carbon electrode (SNPs/GCE) is carried out by cyclic voltammetric and differential pulse voltammetric techniques. The prepared NPs exhibit excellent electrochemical behaviour towards reduction of NB and show a linear response in the range 5–40 µM, sensitivity of 2.262 µA µM
−1
cm
−2
and limit of detection of 0.027 µM. SNPs/GCE shows good selectivity towards NB detection. Also, the system exhibits a considerable recovery towards NB detection in of water and waste samples.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13738-019-01822-z</doi><tpages>8</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Analytical Chemistry Biochemistry Chemical synthesis Chemistry Chemistry and Materials Science Electrochemical analysis Electrodes Eucalyptus Glassy carbon Inorganic Chemistry Low level Nanoparticles Nitrobenzene Organic Chemistry Original Paper Physical Chemistry Selectivity Silver Spectroscopy Spectrum analysis Stabilizers (agents) Voltammetry X ray powder diffraction |
| title | Green synthesis of silver nanoparticles (SNPs)-modified electrode for electrochemical detection of nitrobenzene |
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