Total Synthesis of Cercidinin A via a Sequential Site-selective Acylation Strategy

Total synthesis of cercidinin A (1) was achieved in 7 overall steps from d-glucose (9 steps from gallic acid) via sequential site-selective introduction of requisite galloyl groups into hydroxy groups of unprotected glucose. No protective groups were used for hydroxy groups of d-glucose throughout t...

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Veröffentlicht in:	Chemistry letters 2020-02, Vol.49 (2), p.182-185
Hauptverfasser:	Shibayama, Hiromitsu, Ueda, Yoshihiro, Kawabata, Takeo
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Sprache:	eng
Schlagworte:	Acylation Armor Gallic acid Glucose Synthesis
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creator	Shibayama, Hiromitsu Ueda, Yoshihiro Kawabata, Takeo
description	Total synthesis of cercidinin A (1) was achieved in 7 overall steps from d-glucose (9 steps from gallic acid) via sequential site-selective introduction of requisite galloyl groups into hydroxy groups of unprotected glucose. No protective groups were used for hydroxy groups of d-glucose throughout the total synthesis.
doi_str_mv	10.1246/cl.190872
format	Article
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Acylation Armor Gallic acid Glucose Synthesis
title	Total Synthesis of Cercidinin A via a Sequential Site-selective Acylation Strategy
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