Oxygen Electroreduction on the Anthraquinone-Modified Thin-Film Carbon–Polymer Composite in Alkaline Solution
Technical carbon CH210 was processed by chemical reduction of the diazo derivative of anthraquinone for surface modification. The presence of anthraquinone groups on the carbon surface was confirmed by attenuated total internal reflection (ATR) IR spectroscopy. Carbon with the anthraquinone-modified...
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| Veröffentlicht in: | Russian journal of electrochemistry 2019-12, Vol.55 (12), p.1284-1291 |
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| container_title | Russian journal of electrochemistry |
| container_volume | 55 |
| creator | Chaika, M. Yu Volkov, V. V. Kravchenko, T. A. Konev, D. V. Gorshkov, V. S. Krysanov, V. A. Bosyachenko, A. A. |
| description | Technical carbon CH210 was processed by chemical reduction of the diazo derivative of anthraquinone for surface modification. The presence of anthraquinone groups on the carbon surface was confirmed by attenuated total internal reflection (ATR) IR spectroscopy. Carbon with the anthraquinone-modified surface was deposited on a glassy carbon support using a polymer binder. The behavior of the thus obtained catalyst in oxygen electroreduction in an alkaline medium was studied by the rotating disk electrode method. The kinetic characteristics of the reaction were determined: half-wave potential, limiting current, number of electrons, Tafel slope, exchange current, and charge transfer coefficient. Hydrogen peroxide is formed on the surface of the carbon–polymer composite at higher positive potentials than on technical carbon and glassy carbon electrodes. Therefore, the proposed material can be used as an effective electrocatalyst for this reaction. |
| doi_str_mv | 10.1134/S102319351911003X |
| format | Article |
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Yu ; Volkov, V. V. ; Kravchenko, T. A. ; Konev, D. V. ; Gorshkov, V. S. ; Krysanov, V. A. ; Bosyachenko, A. A.</creator><creatorcontrib>Chaika, M. Yu ; Volkov, V. V. ; Kravchenko, T. A. ; Konev, D. V. ; Gorshkov, V. S. ; Krysanov, V. A. ; Bosyachenko, A. A.</creatorcontrib><description>Technical carbon CH210 was processed by chemical reduction of the diazo derivative of anthraquinone for surface modification. The presence of anthraquinone groups on the carbon surface was confirmed by attenuated total internal reflection (ATR) IR spectroscopy. Carbon with the anthraquinone-modified surface was deposited on a glassy carbon support using a polymer binder. The behavior of the thus obtained catalyst in oxygen electroreduction in an alkaline medium was studied by the rotating disk electrode method. The kinetic characteristics of the reaction were determined: half-wave potential, limiting current, number of electrons, Tafel slope, exchange current, and charge transfer coefficient. Hydrogen peroxide is formed on the surface of the carbon–polymer composite at higher positive potentials than on technical carbon and glassy carbon electrodes. Therefore, the proposed material can be used as an effective electrocatalyst for this reaction.</description><identifier>ISSN: 1023-1935</identifier><identifier>EISSN: 1608-3342</identifier><identifier>DOI: 10.1134/S102319351911003X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anthraquinones ; Carbon ; Charge exchange ; Charge transfer ; Chemical reduction ; Chemistry ; Chemistry and Materials Science ; Electrochemistry ; Electrodes ; Electrowinning ; Glassy carbon ; Hydrogen peroxide ; Infrared spectroscopy ; Organic chemistry ; Physical Chemistry ; Polymer films ; Polymer matrix composites ; Polymers ; Rotating disks ; Thin films</subject><ispartof>Russian journal of electrochemistry, 2019-12, Vol.55 (12), p.1284-1291</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>2019© Pleiades Publishing, Ltd. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-ce2fdf1c20875036cf852902120515facc437ed6c1625b27c932e5d43391fb3c3</citedby><cites>FETCH-LOGICAL-c316t-ce2fdf1c20875036cf852902120515facc437ed6c1625b27c932e5d43391fb3c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S102319351911003X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S102319351911003X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Chaika, M. Yu</creatorcontrib><creatorcontrib>Volkov, V. V.</creatorcontrib><creatorcontrib>Kravchenko, T. A.</creatorcontrib><creatorcontrib>Konev, D. V.</creatorcontrib><creatorcontrib>Gorshkov, V. S.</creatorcontrib><creatorcontrib>Krysanov, V. A.</creatorcontrib><creatorcontrib>Bosyachenko, A. A.</creatorcontrib><title>Oxygen Electroreduction on the Anthraquinone-Modified Thin-Film Carbon–Polymer Composite in Alkaline Solution</title><title>Russian journal of electrochemistry</title><addtitle>Russ J Electrochem</addtitle><description>Technical carbon CH210 was processed by chemical reduction of the diazo derivative of anthraquinone for surface modification. The presence of anthraquinone groups on the carbon surface was confirmed by attenuated total internal reflection (ATR) IR spectroscopy. Carbon with the anthraquinone-modified surface was deposited on a glassy carbon support using a polymer binder. The behavior of the thus obtained catalyst in oxygen electroreduction in an alkaline medium was studied by the rotating disk electrode method. The kinetic characteristics of the reaction were determined: half-wave potential, limiting current, number of electrons, Tafel slope, exchange current, and charge transfer coefficient. Hydrogen peroxide is formed on the surface of the carbon–polymer composite at higher positive potentials than on technical carbon and glassy carbon electrodes. Therefore, the proposed material can be used as an effective electrocatalyst for this reaction.</description><subject>Anthraquinones</subject><subject>Carbon</subject><subject>Charge exchange</subject><subject>Charge transfer</subject><subject>Chemical reduction</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Electrowinning</subject><subject>Glassy carbon</subject><subject>Hydrogen peroxide</subject><subject>Infrared spectroscopy</subject><subject>Organic chemistry</subject><subject>Physical Chemistry</subject><subject>Polymer films</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>Rotating disks</subject><subject>Thin films</subject><issn>1023-1935</issn><issn>1608-3342</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1UN1KwzAUDqLgnD6AdwGvqzlJ07WXY2wqTCZsgnelS0-2zDbZ0hbcne_gG_okZkzwQoQD58D3d_gIuQZ2CyDiuzkwLiATEjIAxsTrCelBwtJIiJifhjvA0QE_JxdNs2GMpQPIesTN3vcrtHRcoWq981h2qjXO0jDtGunQtmtf7DpjncXoyZVGGyzpYm1sNDFVTUeFXzr79fH57Kp9jZ6OXL11jWmRGkuH1VtRGYt07qru4HtJznRRNXj1s_vkZTJejB6i6ez-cTScRkpA0kYKuS41KB7elEwkSqeSZ4wDZxKkLpSKxQDLREHC5ZIPVCY4yjIWIgO9FEr0yc3Rd-vdrsOmzTeu8zZE5lwkMpSSxhBYcGQp75rGo8633tSF3-fA8kOv-Z9eg4YfNU3g2hX6X-f_Rd_aLHuW</recordid><startdate>20191201</startdate><enddate>20191201</enddate><creator>Chaika, M. Yu</creator><creator>Volkov, V. V.</creator><creator>Kravchenko, T. A.</creator><creator>Konev, D. V.</creator><creator>Gorshkov, V. S.</creator><creator>Krysanov, V. A.</creator><creator>Bosyachenko, A. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20191201</creationdate><title>Oxygen Electroreduction on the Anthraquinone-Modified Thin-Film Carbon–Polymer Composite in Alkaline Solution</title><author>Chaika, M. Yu ; Volkov, V. V. ; Kravchenko, T. A. ; Konev, D. V. ; Gorshkov, V. S. ; Krysanov, V. A. ; Bosyachenko, A. 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Yu</creatorcontrib><creatorcontrib>Volkov, V. V.</creatorcontrib><creatorcontrib>Kravchenko, T. A.</creatorcontrib><creatorcontrib>Konev, D. V.</creatorcontrib><creatorcontrib>Gorshkov, V. S.</creatorcontrib><creatorcontrib>Krysanov, V. A.</creatorcontrib><creatorcontrib>Bosyachenko, A. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chaika, M. Yu</au><au>Volkov, V. V.</au><au>Kravchenko, T. A.</au><au>Konev, D. V.</au><au>Gorshkov, V. S.</au><au>Krysanov, V. A.</au><au>Bosyachenko, A. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxygen Electroreduction on the Anthraquinone-Modified Thin-Film Carbon–Polymer Composite in Alkaline Solution</atitle><jtitle>Russian journal of electrochemistry</jtitle><stitle>Russ J Electrochem</stitle><date>2019-12-01</date><risdate>2019</risdate><volume>55</volume><issue>12</issue><spage>1284</spage><epage>1291</epage><pages>1284-1291</pages><issn>1023-1935</issn><eissn>1608-3342</eissn><abstract>Technical carbon CH210 was processed by chemical reduction of the diazo derivative of anthraquinone for surface modification. The presence of anthraquinone groups on the carbon surface was confirmed by attenuated total internal reflection (ATR) IR spectroscopy. Carbon with the anthraquinone-modified surface was deposited on a glassy carbon support using a polymer binder. The behavior of the thus obtained catalyst in oxygen electroreduction in an alkaline medium was studied by the rotating disk electrode method. The kinetic characteristics of the reaction were determined: half-wave potential, limiting current, number of electrons, Tafel slope, exchange current, and charge transfer coefficient. Hydrogen peroxide is formed on the surface of the carbon–polymer composite at higher positive potentials than on technical carbon and glassy carbon electrodes. Therefore, the proposed material can be used as an effective electrocatalyst for this reaction.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S102319351911003X</doi><tpages>8</tpages></addata></record> |
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| subjects | Anthraquinones Carbon Charge exchange Charge transfer Chemical reduction Chemistry Chemistry and Materials Science Electrochemistry Electrodes Electrowinning Glassy carbon Hydrogen peroxide Infrared spectroscopy Organic chemistry Physical Chemistry Polymer films Polymer matrix composites Polymers Rotating disks Thin films |
| title | Oxygen Electroreduction on the Anthraquinone-Modified Thin-Film Carbon–Polymer Composite in Alkaline Solution |
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