Characteristics of dye-sensitized solar cells (DSSCs) using liquid and gel polymer electrolytes with tetrapropylammonium salt
In this work, liquid electrolytes (LEs) and gel polymer electrolytes (GPEs) containing tetrapropylammonium iodide (TPAI) salt, propylene carbonate, ethylene carbonate, N , N -dimethylformamide and (I − /I 3 − ) redox couple have been prepared. For GPEs, the additional material was poly(ethylene oxid...
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| Veröffentlicht in: | Optical and quantum electronics 2020, Vol.52 (3), Article 152 |
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| creator | Abdukarimov, Abdullaziz Shah, Shahan Teo, L. P. Buraidah, M. H. Abidin, Z. H. Z. Mamatkarimov, O. O. Arof, A. K. |
| description | In this work, liquid electrolytes (LEs) and gel polymer electrolytes (GPEs) containing tetrapropylammonium iodide (TPAI) salt, propylene carbonate, ethylene carbonate,
N
,
N
-dimethylformamide and (I
−
/I
3
−
) redox couple have been prepared. For GPEs, the additional material was poly(ethylene oxide). The impedance of these electrolytes was measured using electrochemical impedance spectroscopy to determine their ionic conductivity. Conductivity was found to increase with salt content in LEs whereas in GPEs, conductivity was initially enhanced but it was followed by decrement. The highest ionic conductivity for the GPE and LE were 2.53 mS cm
−1
(0.20 g TPAI) and 8.98 mS cm
−1
(0.25 g TPAI), respectively at room temperature. Dye-sensitized solar cells (DSSCs) were fabricated using all LEs and the highest conducting GPE. At 100 mW cm
−2
illumination, DSSC with LE exhibited the efficiency of 6.61% with short circuit current density,
J
sc
= 18.69 mA cm
−2
, open circuit voltage,
V
oc
= 0.68 V and fill factor,
FF
= 0.52 whereas DSSC using GPE delivered the efficiency of 3.29% with
J
sc
= 11.78 mA cm
−2
,
V
oc
= 0.65 V,
FF
= 0.43. The highest incident photon conversion efficiency (IPCE) at 520 nm is 45.5% for DSSC with 0.25 g TPAI LE and 41.1% for DSSC with GPE at the same wavelength. |
| doi_str_mv | 10.1007/s11082-020-02264-1 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2365341627</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2365341627</sourcerecordid><originalsourceid>FETCH-LOGICAL-c358t-10d2a84f1390c0741c6d18675c896ff7677473ad053398d9df9a723eb35436d43</originalsourceid><addsrcrecordid>eNp9kM1LxDAQxYMouH78A54CXvRQnSRt0h5l_QTBgwreQkzSNZK2ayZFVvB_t7qCNw_DMPDem8ePkAMGJwxAnSJjUPMCOEzDZVmwDTJjleJFzdTTJpmBAFnUDWu2yQ7iKwDIsoIZ-Zy_mGRs9ilgDhbp0FK38gX6HkMOH95RHKJJ1PoYkR6d39_P8ZiOGPoFjeFtDI6a3tGFj3Q5xFXnE_XR25ymI3uk7yG_0OxzMss0LFfRdN3Qh7GjaGLeI1utiej3f_cueby8eJhfF7d3Vzfzs9vCiqrOBQPHTV22TDRgQZXMSsdqqSpbN7JtlVSqVMI4qIRoate4tjGKC_8sqlJIV4pdcrjOnTq8jR6zfh3G1E8vNReyEiWTXE0qvlbZNCAm3-plCp1JK81Af2PWa8x6wqx_MGs2mcTahJO4X_j0F_2P6wuDaoFu</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2365341627</pqid></control><display><type>article</type><title>Characteristics of dye-sensitized solar cells (DSSCs) using liquid and gel polymer electrolytes with tetrapropylammonium salt</title><source>SpringerLink Journals - AutoHoldings</source><creator>Abdukarimov, Abdullaziz ; Shah, Shahan ; Teo, L. P. ; Buraidah, M. H. ; Abidin, Z. H. Z. ; Mamatkarimov, O. O. ; Arof, A. K.</creator><creatorcontrib>Abdukarimov, Abdullaziz ; Shah, Shahan ; Teo, L. P. ; Buraidah, M. H. ; Abidin, Z. H. Z. ; Mamatkarimov, O. O. ; Arof, A. K.</creatorcontrib><description>In this work, liquid electrolytes (LEs) and gel polymer electrolytes (GPEs) containing tetrapropylammonium iodide (TPAI) salt, propylene carbonate, ethylene carbonate,
N
,
N
-dimethylformamide and (I
−
/I
3
−
) redox couple have been prepared. For GPEs, the additional material was poly(ethylene oxide). The impedance of these electrolytes was measured using electrochemical impedance spectroscopy to determine their ionic conductivity. Conductivity was found to increase with salt content in LEs whereas in GPEs, conductivity was initially enhanced but it was followed by decrement. The highest ionic conductivity for the GPE and LE were 2.53 mS cm
−1
(0.20 g TPAI) and 8.98 mS cm
−1
(0.25 g TPAI), respectively at room temperature. Dye-sensitized solar cells (DSSCs) were fabricated using all LEs and the highest conducting GPE. At 100 mW cm
−2
illumination, DSSC with LE exhibited the efficiency of 6.61% with short circuit current density,
J
sc
= 18.69 mA cm
−2
, open circuit voltage,
V
oc
= 0.68 V and fill factor,
FF
= 0.52 whereas DSSC using GPE delivered the efficiency of 3.29% with
J
sc
= 11.78 mA cm
−2
,
V
oc
= 0.65 V,
FF
= 0.43. The highest incident photon conversion efficiency (IPCE) at 520 nm is 45.5% for DSSC with 0.25 g TPAI LE and 41.1% for DSSC with GPE at the same wavelength.</description><identifier>ISSN: 0306-8919</identifier><identifier>EISSN: 1572-817X</identifier><identifier>DOI: 10.1007/s11082-020-02264-1</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Circuits ; Computer Communication Networks ; Dye-sensitized solar cells ; Dyes ; Efficiency ; Electrical Engineering ; Electrochemical impedance spectroscopy ; Electrolytes ; Electrolytic cells ; Energy conversion efficiency ; Ethylene oxide ; Ion currents ; Lasers ; Open circuit voltage ; Optical Devices ; Optics ; Photonics ; Photovoltaic cells ; Physics ; Physics and Astronomy ; Polyethylene oxide ; Polymers ; Propylene ; Room temperature ; Short circuit currents</subject><ispartof>Optical and quantum electronics, 2020, Vol.52 (3), Article 152</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>2020© Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-10d2a84f1390c0741c6d18675c896ff7677473ad053398d9df9a723eb35436d43</citedby><cites>FETCH-LOGICAL-c358t-10d2a84f1390c0741c6d18675c896ff7677473ad053398d9df9a723eb35436d43</cites><orcidid>0000-0003-1731-3516</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11082-020-02264-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11082-020-02264-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Abdukarimov, Abdullaziz</creatorcontrib><creatorcontrib>Shah, Shahan</creatorcontrib><creatorcontrib>Teo, L. P.</creatorcontrib><creatorcontrib>Buraidah, M. H.</creatorcontrib><creatorcontrib>Abidin, Z. H. Z.</creatorcontrib><creatorcontrib>Mamatkarimov, O. O.</creatorcontrib><creatorcontrib>Arof, A. K.</creatorcontrib><title>Characteristics of dye-sensitized solar cells (DSSCs) using liquid and gel polymer electrolytes with tetrapropylammonium salt</title><title>Optical and quantum electronics</title><addtitle>Opt Quant Electron</addtitle><description>In this work, liquid electrolytes (LEs) and gel polymer electrolytes (GPEs) containing tetrapropylammonium iodide (TPAI) salt, propylene carbonate, ethylene carbonate,
N
,
N
-dimethylformamide and (I
−
/I
3
−
) redox couple have been prepared. For GPEs, the additional material was poly(ethylene oxide). The impedance of these electrolytes was measured using electrochemical impedance spectroscopy to determine their ionic conductivity. Conductivity was found to increase with salt content in LEs whereas in GPEs, conductivity was initially enhanced but it was followed by decrement. The highest ionic conductivity for the GPE and LE were 2.53 mS cm
−1
(0.20 g TPAI) and 8.98 mS cm
−1
(0.25 g TPAI), respectively at room temperature. Dye-sensitized solar cells (DSSCs) were fabricated using all LEs and the highest conducting GPE. At 100 mW cm
−2
illumination, DSSC with LE exhibited the efficiency of 6.61% with short circuit current density,
J
sc
= 18.69 mA cm
−2
, open circuit voltage,
V
oc
= 0.68 V and fill factor,
FF
= 0.52 whereas DSSC using GPE delivered the efficiency of 3.29% with
J
sc
= 11.78 mA cm
−2
,
V
oc
= 0.65 V,
FF
= 0.43. The highest incident photon conversion efficiency (IPCE) at 520 nm is 45.5% for DSSC with 0.25 g TPAI LE and 41.1% for DSSC with GPE at the same wavelength.</description><subject>Characterization and Evaluation of Materials</subject><subject>Circuits</subject><subject>Computer Communication Networks</subject><subject>Dye-sensitized solar cells</subject><subject>Dyes</subject><subject>Efficiency</subject><subject>Electrical Engineering</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrolytes</subject><subject>Electrolytic cells</subject><subject>Energy conversion efficiency</subject><subject>Ethylene oxide</subject><subject>Ion currents</subject><subject>Lasers</subject><subject>Open circuit voltage</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Photonics</subject><subject>Photovoltaic cells</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Polyethylene oxide</subject><subject>Polymers</subject><subject>Propylene</subject><subject>Room temperature</subject><subject>Short circuit currents</subject><issn>0306-8919</issn><issn>1572-817X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kM1LxDAQxYMouH78A54CXvRQnSRt0h5l_QTBgwreQkzSNZK2ayZFVvB_t7qCNw_DMPDem8ePkAMGJwxAnSJjUPMCOEzDZVmwDTJjleJFzdTTJpmBAFnUDWu2yQ7iKwDIsoIZ-Zy_mGRs9ilgDhbp0FK38gX6HkMOH95RHKJJ1PoYkR6d39_P8ZiOGPoFjeFtDI6a3tGFj3Q5xFXnE_XR25ymI3uk7yG_0OxzMss0LFfRdN3Qh7GjaGLeI1utiej3f_cueby8eJhfF7d3Vzfzs9vCiqrOBQPHTV22TDRgQZXMSsdqqSpbN7JtlVSqVMI4qIRoate4tjGKC_8sqlJIV4pdcrjOnTq8jR6zfh3G1E8vNReyEiWTXE0qvlbZNCAm3-plCp1JK81Af2PWa8x6wqx_MGs2mcTahJO4X_j0F_2P6wuDaoFu</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Abdukarimov, Abdullaziz</creator><creator>Shah, Shahan</creator><creator>Teo, L. P.</creator><creator>Buraidah, M. H.</creator><creator>Abidin, Z. H. Z.</creator><creator>Mamatkarimov, O. O.</creator><creator>Arof, A. K.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1731-3516</orcidid></search><sort><creationdate>2020</creationdate><title>Characteristics of dye-sensitized solar cells (DSSCs) using liquid and gel polymer electrolytes with tetrapropylammonium salt</title><author>Abdukarimov, Abdullaziz ; Shah, Shahan ; Teo, L. P. ; Buraidah, M. H. ; Abidin, Z. H. Z. ; Mamatkarimov, O. O. ; Arof, A. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-10d2a84f1390c0741c6d18675c896ff7677473ad053398d9df9a723eb35436d43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Circuits</topic><topic>Computer Communication Networks</topic><topic>Dye-sensitized solar cells</topic><topic>Dyes</topic><topic>Efficiency</topic><topic>Electrical Engineering</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrolytes</topic><topic>Electrolytic cells</topic><topic>Energy conversion efficiency</topic><topic>Ethylene oxide</topic><topic>Ion currents</topic><topic>Lasers</topic><topic>Open circuit voltage</topic><topic>Optical Devices</topic><topic>Optics</topic><topic>Photonics</topic><topic>Photovoltaic cells</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Polyethylene oxide</topic><topic>Polymers</topic><topic>Propylene</topic><topic>Room temperature</topic><topic>Short circuit currents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abdukarimov, Abdullaziz</creatorcontrib><creatorcontrib>Shah, Shahan</creatorcontrib><creatorcontrib>Teo, L. P.</creatorcontrib><creatorcontrib>Buraidah, M. H.</creatorcontrib><creatorcontrib>Abidin, Z. H. Z.</creatorcontrib><creatorcontrib>Mamatkarimov, O. O.</creatorcontrib><creatorcontrib>Arof, A. K.</creatorcontrib><collection>CrossRef</collection><jtitle>Optical and quantum electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abdukarimov, Abdullaziz</au><au>Shah, Shahan</au><au>Teo, L. P.</au><au>Buraidah, M. H.</au><au>Abidin, Z. H. Z.</au><au>Mamatkarimov, O. O.</au><au>Arof, A. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characteristics of dye-sensitized solar cells (DSSCs) using liquid and gel polymer electrolytes with tetrapropylammonium salt</atitle><jtitle>Optical and quantum electronics</jtitle><stitle>Opt Quant Electron</stitle><date>2020</date><risdate>2020</risdate><volume>52</volume><issue>3</issue><artnum>152</artnum><issn>0306-8919</issn><eissn>1572-817X</eissn><abstract>In this work, liquid electrolytes (LEs) and gel polymer electrolytes (GPEs) containing tetrapropylammonium iodide (TPAI) salt, propylene carbonate, ethylene carbonate,
N
,
N
-dimethylformamide and (I
−
/I
3
−
) redox couple have been prepared. For GPEs, the additional material was poly(ethylene oxide). The impedance of these electrolytes was measured using electrochemical impedance spectroscopy to determine their ionic conductivity. Conductivity was found to increase with salt content in LEs whereas in GPEs, conductivity was initially enhanced but it was followed by decrement. The highest ionic conductivity for the GPE and LE were 2.53 mS cm
−1
(0.20 g TPAI) and 8.98 mS cm
−1
(0.25 g TPAI), respectively at room temperature. Dye-sensitized solar cells (DSSCs) were fabricated using all LEs and the highest conducting GPE. At 100 mW cm
−2
illumination, DSSC with LE exhibited the efficiency of 6.61% with short circuit current density,
J
sc
= 18.69 mA cm
−2
, open circuit voltage,
V
oc
= 0.68 V and fill factor,
FF
= 0.52 whereas DSSC using GPE delivered the efficiency of 3.29% with
J
sc
= 11.78 mA cm
−2
,
V
oc
= 0.65 V,
FF
= 0.43. The highest incident photon conversion efficiency (IPCE) at 520 nm is 45.5% for DSSC with 0.25 g TPAI LE and 41.1% for DSSC with GPE at the same wavelength.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11082-020-02264-1</doi><orcidid>https://orcid.org/0000-0003-1731-3516</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Optical and quantum electronics, 2020, Vol.52 (3), Article 152 |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Characterization and Evaluation of Materials Circuits Computer Communication Networks Dye-sensitized solar cells Dyes Efficiency Electrical Engineering Electrochemical impedance spectroscopy Electrolytes Electrolytic cells Energy conversion efficiency Ethylene oxide Ion currents Lasers Open circuit voltage Optical Devices Optics Photonics Photovoltaic cells Physics Physics and Astronomy Polyethylene oxide Polymers Propylene Room temperature Short circuit currents |
| title | Characteristics of dye-sensitized solar cells (DSSCs) using liquid and gel polymer electrolytes with tetrapropylammonium salt |
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