A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia

The new mineral borisenkoite Cu 3 [(V,As)O 4 ] 2 was found in sublimates of the Yadovitaya fumarole at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia. Associated minerals are sanidine, hematite, lammerite, lammerite-β...

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Veröffentlicht in:Physics and chemistry of minerals 2020-03, Vol.47 (3), Article 17
Hauptverfasser: Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Vigasina, Marina F., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu
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container_title Physics and chemistry of minerals
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creator Pekov, Igor V.
Zubkova, Natalia V.
Yapaskurt, Vasiliy O.
Polekhovsky, Yury S.
Vigasina, Marina F.
Britvin, Sergey N.
Turchkova, Anna G.
Sidorov, Evgeny G.
Pushcharovsky, Dmitry Yu
description The new mineral borisenkoite Cu 3 [(V,As)O 4 ] 2 was found in sublimates of the Yadovitaya fumarole at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia. Associated minerals are sanidine, hematite, lammerite, lammerite-β, bradaczekite, zincobradaczekite, mcbirneyite, pseudolyonsite, lyonsite, starovaite, tenorite, rutile, tripuhyite, pseudobrookite, piypite, langbeinite, calciolangbeinite, aphthitalite, alumoklyuchevskite, palmierite, cupromolybdite, and corundum. Borisenkoite forms (1) prismatic crystals (up to 0.04 × 0.04 × 0.10 mm 3 ) usually combined in clusters up to 0.4 mm and (2) rims up to 0.05 mm in width around lammerite. Borisenkoite is red-brown, golden-brown or brown, with strong greasy to adamantine lustre. D calc is 4.69 g·cm −3 . Chemical composition (wt.%, electron-microprobe) is: CuO 53.25, ZnO 1.13, Fe 2 O 3 0.16, P 2 O 5 0.05, V 2 O 5 25.06, As 2 O 5 20.44, total 100.07. The empirical formula, based on 8 O apfu , is: (Cu 2.94 Zn 0.06 Fe 0.01 ) Σ3.01 (V 1.21 As 0.78 ) Σ1.99 O 8 . Borisenkoite is monoclinic, P 2 1 / c , a 6.3779(7), b 8.6021(9), c 11.3597(11) Å, β 92.013(8)º, V 622.84(11) Å 3 and Z  = 4. The strongest reflections in the powder XRD pattern [ d ,Å( I )( hkl )] are: 4.309(48)(− 102, 020), 3.424(40)(022, − 121), 2.994(48)(113, 210), 2.917(50)(− 211), 2.830(100)(004), 2.782(92)(031) and 2.568(38)(123). The crystal structure was solved from single-crystal XRD data and refined to R  = 0.0654. Borisenkoite is isotypic with lammerite-β. They form a limited solid-solution series extended from Cu 3 (AsO 4 ) 2 to Cu 3 (V 1.5 As 0.5 )O 8 , with gap between Cu 3 (As 1.75 V 0.25 )O 8 and Cu 3 (As 1.25 V 0.75 )O 8 . The assumption that As 5+ can stabilize borisenkoite structure is the reason to propose the simplified formula Cu 3 [(V,As)O 4 ] 2 avoiding the formal end-member formula Cu 3 (VO 4 ) 2 . Borisenkoite is named in honour of the Russian geochemist, mineralogist, and geologist Leonid Fedorovich Borisenko (1922–2000).
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Associated minerals are sanidine, hematite, lammerite, lammerite-β, bradaczekite, zincobradaczekite, mcbirneyite, pseudolyonsite, lyonsite, starovaite, tenorite, rutile, tripuhyite, pseudobrookite, piypite, langbeinite, calciolangbeinite, aphthitalite, alumoklyuchevskite, palmierite, cupromolybdite, and corundum. Borisenkoite forms (1) prismatic crystals (up to 0.04 × 0.04 × 0.10 mm 3 ) usually combined in clusters up to 0.4 mm and (2) rims up to 0.05 mm in width around lammerite. Borisenkoite is red-brown, golden-brown or brown, with strong greasy to adamantine lustre. D calc is 4.69 g·cm −3 . Chemical composition (wt.%, electron-microprobe) is: CuO 53.25, ZnO 1.13, Fe 2 O 3 0.16, P 2 O 5 0.05, V 2 O 5 25.06, As 2 O 5 20.44, total 100.07. The empirical formula, based on 8 O apfu , is: (Cu 2.94 Zn 0.06 Fe 0.01 ) Σ3.01 (V 1.21 As 0.78 ) Σ1.99 O 8 . Borisenkoite is monoclinic, P 2 1 / c , a 6.3779(7), b 8.6021(9), c 11.3597(11) Å, β 92.013(8)º, V 622.84(11) Å 3 and Z  = 4. The strongest reflections in the powder XRD pattern [ d ,Å( I )( hkl )] are: 4.309(48)(− 102, 020), 3.424(40)(022, − 121), 2.994(48)(113, 210), 2.917(50)(− 211), 2.830(100)(004), 2.782(92)(031) and 2.568(38)(123). The crystal structure was solved from single-crystal XRD data and refined to R  = 0.0654. Borisenkoite is isotypic with lammerite-β. They form a limited solid-solution series extended from Cu 3 (AsO 4 ) 2 to Cu 3 (V 1.5 As 0.5 )O 8 , with gap between Cu 3 (As 1.75 V 0.25 )O 8 and Cu 3 (As 1.25 V 0.75 )O 8 . The assumption that As 5+ can stabilize borisenkoite structure is the reason to propose the simplified formula Cu 3 [(V,As)O 4 ] 2 avoiding the formal end-member formula Cu 3 (VO 4 ) 2 . 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Associated minerals are sanidine, hematite, lammerite, lammerite-β, bradaczekite, zincobradaczekite, mcbirneyite, pseudolyonsite, lyonsite, starovaite, tenorite, rutile, tripuhyite, pseudobrookite, piypite, langbeinite, calciolangbeinite, aphthitalite, alumoklyuchevskite, palmierite, cupromolybdite, and corundum. Borisenkoite forms (1) prismatic crystals (up to 0.04 × 0.04 × 0.10 mm 3 ) usually combined in clusters up to 0.4 mm and (2) rims up to 0.05 mm in width around lammerite. Borisenkoite is red-brown, golden-brown or brown, with strong greasy to adamantine lustre. D calc is 4.69 g·cm −3 . Chemical composition (wt.%, electron-microprobe) is: CuO 53.25, ZnO 1.13, Fe 2 O 3 0.16, P 2 O 5 0.05, V 2 O 5 25.06, As 2 O 5 20.44, total 100.07. The empirical formula, based on 8 O apfu , is: (Cu 2.94 Zn 0.06 Fe 0.01 ) Σ3.01 (V 1.21 As 0.78 ) Σ1.99 O 8 . Borisenkoite is monoclinic, P 2 1 / c , a 6.3779(7), b 8.6021(9), c 11.3597(11) Å, β 92.013(8)º, V 622.84(11) Å 3 and Z  = 4. The strongest reflections in the powder XRD pattern [ d ,Å( I )( hkl )] are: 4.309(48)(− 102, 020), 3.424(40)(022, − 121), 2.994(48)(113, 210), 2.917(50)(− 211), 2.830(100)(004), 2.782(92)(031) and 2.568(38)(123). The crystal structure was solved from single-crystal XRD data and refined to R  = 0.0654. Borisenkoite is isotypic with lammerite-β. They form a limited solid-solution series extended from Cu 3 (AsO 4 ) 2 to Cu 3 (V 1.5 As 0.5 )O 8 , with gap between Cu 3 (As 1.75 V 0.25 )O 8 and Cu 3 (As 1.25 V 0.75 )O 8 . The assumption that As 5+ can stabilize borisenkoite structure is the reason to propose the simplified formula Cu 3 [(V,As)O 4 ] 2 avoiding the formal end-member formula Cu 3 (VO 4 ) 2 . Borisenkoite is named in honour of the Russian geochemist, mineralogist, and geologist Leonid Fedorovich Borisenko (1922–2000).</description><subject>Arsenic ions</subject><subject>Chemical composition</subject><subject>Cinder cones</subject><subject>Corundum</subject><subject>Crystal structure</subject><subject>Crystallography and Scattering Methods</subject><subject>Crystals</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Geochemistry</subject><subject>Hematite</subject><subject>Mineral Resources</subject><subject>Mineralogy</subject><subject>Organic chemistry</subject><subject>Original Paper</subject><subject>Phosphorus pentoxide</subject><subject>Single crystals</subject><subject>Solid solutions</subject><subject>Volcanoes</subject><subject>Zinc oxide</subject><issn>0342-1791</issn><issn>1432-2021</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kc-KFDEQxoMoOK6-gKeAF4WOVv70dOc4DKsrLizI6kUkpNOJnZ3uZEy6defmO_gQ3n0QH8InMe4I4sW61KG-76sqfgg9pPCUAjTPMgBbSwIMCFBoKTncQisqOCMMGL2NVsAFI7SR9C66l_MVQBk29Qp92-BgP-PJB5v0iLuYfLZhF_1sK7xd-LvHb6tNfnIh3rMK69DjebDY5zjFtB_iknG2ydv8j_Hnl6-jnqYymC358R37gN0y6RRHb7C9HvSoZx9DxtHdxF3GsdNm8Dv8KY5Gh1jhV3oyg553usKvl5y9vo_uOD1m--BPP0Fvnp9ebs_I-cWLl9vNOTGMiwMxru_qHnira-GkbBtmbGucWzNJoReua1zraNvUupdGMia46GHdsbYUK0fwE_TomLtP8eNi86yu4pJCWakYr6VomRTromJHlUkx52Sd2idfPjwoCuo3EHUEogoQdQNEHYqJH025iMMHm_5G_8f1Cz8kko4</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Pekov, Igor V.</creator><creator>Zubkova, Natalia V.</creator><creator>Yapaskurt, Vasiliy O.</creator><creator>Polekhovsky, Yury S.</creator><creator>Vigasina, Marina F.</creator><creator>Britvin, Sergey N.</creator><creator>Turchkova, Anna G.</creator><creator>Sidorov, Evgeny G.</creator><creator>Pushcharovsky, Dmitry Yu</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200301</creationdate><title>A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia</title><author>Pekov, Igor V. ; Zubkova, Natalia V. ; Yapaskurt, Vasiliy O. ; Polekhovsky, Yury S. ; Vigasina, Marina F. ; Britvin, Sergey N. ; Turchkova, Anna G. ; Sidorov, Evgeny G. ; Pushcharovsky, Dmitry Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c234y-cfdb5d038a54f99872ce8cff62910d4fb7f8f1875ad9c922434d06b288882bac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Arsenic ions</topic><topic>Chemical composition</topic><topic>Cinder cones</topic><topic>Corundum</topic><topic>Crystal structure</topic><topic>Crystallography and Scattering Methods</topic><topic>Crystals</topic><topic>Earth and Environmental Science</topic><topic>Earth Sciences</topic><topic>Geochemistry</topic><topic>Hematite</topic><topic>Mineral Resources</topic><topic>Mineralogy</topic><topic>Organic chemistry</topic><topic>Original Paper</topic><topic>Phosphorus pentoxide</topic><topic>Single crystals</topic><topic>Solid solutions</topic><topic>Volcanoes</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pekov, Igor V.</creatorcontrib><creatorcontrib>Zubkova, Natalia V.</creatorcontrib><creatorcontrib>Yapaskurt, Vasiliy O.</creatorcontrib><creatorcontrib>Polekhovsky, Yury S.</creatorcontrib><creatorcontrib>Vigasina, Marina F.</creatorcontrib><creatorcontrib>Britvin, Sergey N.</creatorcontrib><creatorcontrib>Turchkova, Anna G.</creatorcontrib><creatorcontrib>Sidorov, Evgeny G.</creatorcontrib><creatorcontrib>Pushcharovsky, Dmitry Yu</creatorcontrib><collection>CrossRef</collection><jtitle>Physics and chemistry of minerals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pekov, Igor V.</au><au>Zubkova, Natalia V.</au><au>Yapaskurt, Vasiliy O.</au><au>Polekhovsky, Yury S.</au><au>Vigasina, Marina F.</au><au>Britvin, Sergey N.</au><au>Turchkova, Anna G.</au><au>Sidorov, Evgeny G.</au><au>Pushcharovsky, Dmitry Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia</atitle><jtitle>Physics and chemistry of minerals</jtitle><stitle>Phys Chem Minerals</stitle><date>2020-03-01</date><risdate>2020</risdate><volume>47</volume><issue>3</issue><artnum>17</artnum><issn>0342-1791</issn><eissn>1432-2021</eissn><abstract>The new mineral borisenkoite Cu 3 [(V,As)O 4 ] 2 was found in sublimates of the Yadovitaya fumarole at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia. Associated minerals are sanidine, hematite, lammerite, lammerite-β, bradaczekite, zincobradaczekite, mcbirneyite, pseudolyonsite, lyonsite, starovaite, tenorite, rutile, tripuhyite, pseudobrookite, piypite, langbeinite, calciolangbeinite, aphthitalite, alumoklyuchevskite, palmierite, cupromolybdite, and corundum. Borisenkoite forms (1) prismatic crystals (up to 0.04 × 0.04 × 0.10 mm 3 ) usually combined in clusters up to 0.4 mm and (2) rims up to 0.05 mm in width around lammerite. Borisenkoite is red-brown, golden-brown or brown, with strong greasy to adamantine lustre. D calc is 4.69 g·cm −3 . Chemical composition (wt.%, electron-microprobe) is: CuO 53.25, ZnO 1.13, Fe 2 O 3 0.16, P 2 O 5 0.05, V 2 O 5 25.06, As 2 O 5 20.44, total 100.07. The empirical formula, based on 8 O apfu , is: (Cu 2.94 Zn 0.06 Fe 0.01 ) Σ3.01 (V 1.21 As 0.78 ) Σ1.99 O 8 . Borisenkoite is monoclinic, P 2 1 / c , a 6.3779(7), b 8.6021(9), c 11.3597(11) Å, β 92.013(8)º, V 622.84(11) Å 3 and Z  = 4. The strongest reflections in the powder XRD pattern [ d ,Å( I )( hkl )] are: 4.309(48)(− 102, 020), 3.424(40)(022, − 121), 2.994(48)(113, 210), 2.917(50)(− 211), 2.830(100)(004), 2.782(92)(031) and 2.568(38)(123). The crystal structure was solved from single-crystal XRD data and refined to R  = 0.0654. Borisenkoite is isotypic with lammerite-β. They form a limited solid-solution series extended from Cu 3 (AsO 4 ) 2 to Cu 3 (V 1.5 As 0.5 )O 8 , with gap between Cu 3 (As 1.75 V 0.25 )O 8 and Cu 3 (As 1.25 V 0.75 )O 8 . The assumption that As 5+ can stabilize borisenkoite structure is the reason to propose the simplified formula Cu 3 [(V,As)O 4 ] 2 avoiding the formal end-member formula Cu 3 (VO 4 ) 2 . Borisenkoite is named in honour of the Russian geochemist, mineralogist, and geologist Leonid Fedorovich Borisenko (1922–2000).</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00269-020-01081-y</doi></addata></record>
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subjects Arsenic ions
Chemical composition
Cinder cones
Corundum
Crystal structure
Crystallography and Scattering Methods
Crystals
Earth and Environmental Science
Earth Sciences
Geochemistry
Hematite
Mineral Resources
Mineralogy
Organic chemistry
Original Paper
Phosphorus pentoxide
Single crystals
Solid solutions
Volcanoes
Zinc oxide
title A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia
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