Corrosion of nanocrystalline and coarse-grained nickel-iron (Ni-Fe) alloys in neutral and alkaline sulfate environments
•Similar overall polarization behaviour for conventional poly- and electrodeposited nanocrystalline Ni-Fe alloys.•Differences in anodic polarization behaviour in neutral environment attributed to sulfur impurities more so than grain size.•Negligible difference in corrosion behaviour in alkaline envi...
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| Veröffentlicht in: | Corrosion science 2020-02, Vol.163, p.108233, Article 108233 |
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| creator | Sabatini, Michael Monaco, Leo Erb, Uwe |
| description | •Similar overall polarization behaviour for conventional poly- and electrodeposited nanocrystalline Ni-Fe alloys.•Differences in anodic polarization behaviour in neutral environment attributed to sulfur impurities more so than grain size.•Negligible difference in corrosion behaviour in alkaline environment irrespective of grain size and composition.
Potentiodynamic polarization behaviour of electrodeposited nanocrystalline and conventional polycrystalline Ni-Fe alloys of similar compositions was investigated in neutral (pH 7) and alkaline (pH 10) 0.5 M Na2SO4 environments. In neutral solution, elevated current densities and delayed passivation were observed for all nanocrystalline materials, independent of composition. This behaviour was attributed to sulfur, present in the nanocrystalline materials as an impurity, more so than an effect of grain refinement. In alkaline solution, the effect of sulfur was exceeded by oxide film formation, and no significant difference in corrosion behaviour was observed as a function of grain size i.e. intercrystalline volume fraction. |
| doi_str_mv | 10.1016/j.corsci.2019.108233 |
| format | Article |
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Potentiodynamic polarization behaviour of electrodeposited nanocrystalline and conventional polycrystalline Ni-Fe alloys of similar compositions was investigated in neutral (pH 7) and alkaline (pH 10) 0.5 M Na2SO4 environments. In neutral solution, elevated current densities and delayed passivation were observed for all nanocrystalline materials, independent of composition. This behaviour was attributed to sulfur, present in the nanocrystalline materials as an impurity, more so than an effect of grain refinement. In alkaline solution, the effect of sulfur was exceeded by oxide film formation, and no significant difference in corrosion behaviour was observed as a function of grain size i.e. intercrystalline volume fraction.</description><identifier>ISSN: 0010-938X</identifier><identifier>EISSN: 1879-0496</identifier><identifier>DOI: 10.1016/j.corsci.2019.108233</identifier><language>eng</language><publisher>Amsterdam: Elsevier Ltd</publisher><subject>Corrosion ; Grain refinement ; Grain size ; Iron ; Nanocrystals ; Nickel ; Nickel base alloys ; Oxide coatings ; Potentiodynamic polarization ; Sodium sulfate ; Sulfate environments ; Sulfur</subject><ispartof>Corrosion science, 2020-02, Vol.163, p.108233, Article 108233</ispartof><rights>2019 Elsevier Ltd</rights><rights>Copyright Elsevier BV Feb 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c400t-4e7d8ec30c7f10ad2a0294ebc366ffb8cd02da707b5e71164e37c7036664a9923</citedby><cites>FETCH-LOGICAL-c400t-4e7d8ec30c7f10ad2a0294ebc366ffb8cd02da707b5e71164e37c7036664a9923</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.corsci.2019.108233$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Sabatini, Michael</creatorcontrib><creatorcontrib>Monaco, Leo</creatorcontrib><creatorcontrib>Erb, Uwe</creatorcontrib><title>Corrosion of nanocrystalline and coarse-grained nickel-iron (Ni-Fe) alloys in neutral and alkaline sulfate environments</title><title>Corrosion science</title><description>•Similar overall polarization behaviour for conventional poly- and electrodeposited nanocrystalline Ni-Fe alloys.•Differences in anodic polarization behaviour in neutral environment attributed to sulfur impurities more so than grain size.•Negligible difference in corrosion behaviour in alkaline environment irrespective of grain size and composition.
Potentiodynamic polarization behaviour of electrodeposited nanocrystalline and conventional polycrystalline Ni-Fe alloys of similar compositions was investigated in neutral (pH 7) and alkaline (pH 10) 0.5 M Na2SO4 environments. In neutral solution, elevated current densities and delayed passivation were observed for all nanocrystalline materials, independent of composition. This behaviour was attributed to sulfur, present in the nanocrystalline materials as an impurity, more so than an effect of grain refinement. In alkaline solution, the effect of sulfur was exceeded by oxide film formation, and no significant difference in corrosion behaviour was observed as a function of grain size i.e. intercrystalline volume fraction.</description><subject>Corrosion</subject><subject>Grain refinement</subject><subject>Grain size</subject><subject>Iron</subject><subject>Nanocrystals</subject><subject>Nickel</subject><subject>Nickel base alloys</subject><subject>Oxide coatings</subject><subject>Potentiodynamic polarization</subject><subject>Sodium sulfate</subject><subject>Sulfate environments</subject><subject>Sulfur</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKv_wEPAix5SJ5t0Py6CFKtC0YuCt5BmZyXtNtFkt9J_b9r17CkweZ53mJeQSw4TDjy_XU2MD9HYSQa8SqMyE-KIjHhZVAxklR-TEQAHVony45ScxbgCgMTCiPzMfAg-Wu-ob6jTzpuwi51uW-uQaldT43WIyD6DTpOaOmvW2DIbknH9Ytkcb2ii_S5S66jDvgu6PYi6XetDSuzbRndI0W332gZdF8_JSaPbiBd_75i8zx_eZk9s8fr4PLtfMCMBOiaxqEs0AkzRcNB1piGrJC6NyPOmWZamhqzWBRTLKRac5xJFYQpIv7nUVZWJMbkacr-C_-4xdmrl--DSSpWJaSWkgBISJQfKpC5iwEZ9BbvRYac4qH3FaqWGitW-YjVUnLS7QcN0wdZiUIlAZ7C2AU2nam__D_gFJlaIFQ</recordid><startdate>202002</startdate><enddate>202002</enddate><creator>Sabatini, Michael</creator><creator>Monaco, Leo</creator><creator>Erb, Uwe</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>202002</creationdate><title>Corrosion of nanocrystalline and coarse-grained nickel-iron (Ni-Fe) alloys in neutral and alkaline sulfate environments</title><author>Sabatini, Michael ; Monaco, Leo ; Erb, Uwe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c400t-4e7d8ec30c7f10ad2a0294ebc366ffb8cd02da707b5e71164e37c7036664a9923</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Corrosion</topic><topic>Grain refinement</topic><topic>Grain size</topic><topic>Iron</topic><topic>Nanocrystals</topic><topic>Nickel</topic><topic>Nickel base alloys</topic><topic>Oxide coatings</topic><topic>Potentiodynamic polarization</topic><topic>Sodium sulfate</topic><topic>Sulfate environments</topic><topic>Sulfur</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sabatini, Michael</creatorcontrib><creatorcontrib>Monaco, Leo</creatorcontrib><creatorcontrib>Erb, Uwe</creatorcontrib><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Corrosion science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sabatini, Michael</au><au>Monaco, Leo</au><au>Erb, Uwe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corrosion of nanocrystalline and coarse-grained nickel-iron (Ni-Fe) alloys in neutral and alkaline sulfate environments</atitle><jtitle>Corrosion science</jtitle><date>2020-02</date><risdate>2020</risdate><volume>163</volume><spage>108233</spage><pages>108233-</pages><artnum>108233</artnum><issn>0010-938X</issn><eissn>1879-0496</eissn><abstract>•Similar overall polarization behaviour for conventional poly- and electrodeposited nanocrystalline Ni-Fe alloys.•Differences in anodic polarization behaviour in neutral environment attributed to sulfur impurities more so than grain size.•Negligible difference in corrosion behaviour in alkaline environment irrespective of grain size and composition.
Potentiodynamic polarization behaviour of electrodeposited nanocrystalline and conventional polycrystalline Ni-Fe alloys of similar compositions was investigated in neutral (pH 7) and alkaline (pH 10) 0.5 M Na2SO4 environments. In neutral solution, elevated current densities and delayed passivation were observed for all nanocrystalline materials, independent of composition. This behaviour was attributed to sulfur, present in the nanocrystalline materials as an impurity, more so than an effect of grain refinement. In alkaline solution, the effect of sulfur was exceeded by oxide film formation, and no significant difference in corrosion behaviour was observed as a function of grain size i.e. intercrystalline volume fraction.</abstract><cop>Amsterdam</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.corsci.2019.108233</doi></addata></record> |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Corrosion Grain refinement Grain size Iron Nanocrystals Nickel Nickel base alloys Oxide coatings Potentiodynamic polarization Sodium sulfate Sulfate environments Sulfur |
| title | Corrosion of nanocrystalline and coarse-grained nickel-iron (Ni-Fe) alloys in neutral and alkaline sulfate environments |
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