Boron Dipirrins: Mechanism of Formation, Spectral and Photophysical Properties, and Directions of Functionalization
Boron dipyrrins (Bodipy) are unique complexes occupying an intermediate position between classical coordination and organometallic compounds. The enormous interest of researchers from all over the world to the compounds of this class has by now provided an endless stream of publications that require...
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| Veröffentlicht in: | Russian journal of general chemistry 2019-12, Vol.89 (12), p.2682-2699 |
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| container_title | Russian journal of general chemistry |
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| creator | Rumyantsev, E. V. Marfin, Y. S. |
| description | Boron dipyrrins (Bodipy) are unique complexes occupying an intermediate position between classical coordination and organometallic compounds. The enormous interest of researchers from all over the world to the compounds of this class has by now provided an endless stream of publications that requires generalization. Existing reviews and original publications do not fully cover the structural diversity of Bodipy and their possible applications in engineering, medicine, analytical chemistry, optics, photonics, etc. In this paper, w e present the results, mainly of our own research, which for the first time allowed us to establish the physicochemical principles of the formation of Bodipy (the reasons for the low rates of complexation of ligands with boron trifluoride), changes in the spectral and photophysical properties of alkylated Bodipy complexes with the separation of contributions from universal and specific solvation, and examples of functionalization of inorganic and organic polymer materials based on Bodipy of different structures. Examples of the current team’s Bodipy research in different practical areas are presented. |
| doi_str_mv | 10.1134/S1070363219120454 |
| format | Article |
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Existing reviews and original publications do not fully cover the structural diversity of Bodipy and their possible applications in engineering, medicine, analytical chemistry, optics, photonics, etc. In this paper, w e present the results, mainly of our own research, which for the first time allowed us to establish the physicochemical principles of the formation of Bodipy (the reasons for the low rates of complexation of ligands with boron trifluoride), changes in the spectral and photophysical properties of alkylated Bodipy complexes with the separation of contributions from universal and specific solvation, and examples of functionalization of inorganic and organic polymer materials based on Bodipy of different structures. Examples of the current team’s Bodipy research in different practical areas are presented.</description><subject>Alkylation</subject><subject>Analytical chemistry</subject><subject>Boron</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Documents</subject><subject>Organic chemistry</subject><subject>Organometallic compounds</subject><subject>Photonics</subject><subject>Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)</subject><subject>Solvation</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kcFOwzAMhiMEEmPwANwqcV2Hk7RNx21sDJBATBqcqzRNtkxdUpLuMJ6erEXigFAOif3_n-XYCF1jGGNMk9sVBgY0owRPMIEkTU7QAGeQx5SmcBreQY6P-jm68H4LgAEyMkD-3jprorlutHPa-LvoVYoNN9rvIquihXU73mprRtGqkaJ1vI64qaLlxra22Ry8FiGzdLaRrtXSjzp1rl3wBsp3NfamC3itv7pal-hM8drLq597iD4WD--zp_jl7fF5Nn2JBU3TNsYcIGUVZFwQxUiScEpVykRa5hJKmhBCK56XZQWl5AkInFe5IKUKE1AJLys6RDd93cbZz730bbG1exf68AWhac5wmAALrnHvWvNaFtooG34pwqnkTgtrpNIhP2WEAWYsnwQA94Bw1nsnVdE4vePuUGAojsso_iwjMKRnfPCatXS_rfwPfQNXiYx9</recordid><startdate>20191201</startdate><enddate>20191201</enddate><creator>Rumyantsev, E. 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| subjects | Alkylation Analytical chemistry Boron Chemistry Chemistry and Materials Science Chemistry/Food Science Documents Organic chemistry Organometallic compounds Photonics Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal) Solvation |
| title | Boron Dipirrins: Mechanism of Formation, Spectral and Photophysical Properties, and Directions of Functionalization |
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