A lutidine-promoted photoredox catalytic atom-transfer radical cyclization reaction for the synthesis of 4-bromo-3,3-dialkyl-octahydro-indol-2-ones

Reported herein is a visible-light-catalyzed photoredox atom-transfer radical cyclization (ATRC) halo-alkylation of 1,6-dienes with α-halo-ketones as the ATRC reagent. This process exhibits high atom economy, high step economy, and high redox economy, which can directly construct a 4-bromo-3,3-dialk...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-02, Vol.56 (14), p.226-229
Hauptverfasser:	Zhao, Quan-Sheng, Xu, Guo-Qiang, Xu, Ji-Tao, Wang, Zhu-Yin, Xu, Peng-Fei
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylation Chemical synthesis Crystallography Dienes Ketones Reagents
Online-Zugang:	Volltext
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