Tri-functional phthalonitrile monomer as stiffness increasing additive for easy processable high performance resins
A new tri-functional phthalonitrile monomer tris(3-(3,4-dicyanophenoxy)phenyl) phosphate (TPP) was first synthesized and characterized with the intent of increasing the cross-linking rate of phthalonitrile resins. By combining TTP and di-functional phthalonitrile with aromatic diamine easy-processab...
Gespeichert in:
| Veröffentlicht in: | Reactive & functional polymers 2020-01, Vol.146, p.104409, Article 104409 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | 104409 |
| container_title | Reactive & functional polymers |
| container_volume | 146 |
| creator | Yakovlev, M.V. Morozov, O.S. Afanaseva, E.S. Bulgakov, B.A. Babkin, A.V. Kepman, A.V. |
| description | A new tri-functional phthalonitrile monomer tris(3-(3,4-dicyanophenoxy)phenyl) phosphate (TPP) was first synthesized and characterized with the intent of increasing the cross-linking rate of phthalonitrile resins. By combining TTP and di-functional phthalonitrile with aromatic diamine easy-processable formulations (η |
| doi_str_mv | 10.1016/j.reactfunctpolym.2019.104409 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_elsev</sourceid><recordid>TN_cdi_proquest_journals_2355279869</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1381514819310235</els_id><sourcerecordid>2355279869</sourcerecordid><originalsourceid>FETCH-LOGICAL-c361t-8a65ccdfe2c90cdcdc8f643e5437a63813b3aeca58f59014375746bc334242a33</originalsourceid><addsrcrecordid>eNqNkE1r3DAQhk1oIWmS_yAIORVvJOvD9qGHsrRJINBLAr0JrTzKarElV9Km7L_vbBxy6CnooGHmfebjraprRleMMnWzWyUwtrh9sGWO42FaNZT1WBOC9ifVGetaXjOlfn_CmHeslkx0p9WXnHeUshYrZ1V-TL5-7eBjMCOZt2Vrxhh8SX4EMsUQJ0jEZJKLdy5AzsQHi4OzD8_EDIMv_gWIi4lg7kDmFC2KzAbprX_ekhkSFicTLJAESOWL6rMzY4bLt_-8evr543F9Vz_8ur1ff3-oLVes1J1R0trBQWN7agd8nVOCgxS8NQrv4RtuwBrZOdlThlnZCrWxnItGNIbz8-pq6Ys7_dlDLnoX9wmvzLrhUjZt36keVd8WlU0x5wROz8lPJh00o_ros97p_3zWR5_14jPy3cL_hU102XrAS997UEolo71QPUaMrn0xR6fXcR8Kol8_jqL6dlEDevbiIek3YvAJbNFD9B9c-R_Jm7Rv</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2355279869</pqid></control><display><type>article</type><title>Tri-functional phthalonitrile monomer as stiffness increasing additive for easy processable high performance resins</title><source>Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><source>Access via ScienceDirect (Elsevier)</source><creator>Yakovlev, M.V. ; Morozov, O.S. ; Afanaseva, E.S. ; Bulgakov, B.A. ; Babkin, A.V. ; Kepman, A.V.</creator><creatorcontrib>Yakovlev, M.V. ; Morozov, O.S. ; Afanaseva, E.S. ; Bulgakov, B.A. ; Babkin, A.V. ; Kepman, A.V.</creatorcontrib><description>A new tri-functional phthalonitrile monomer tris(3-(3,4-dicyanophenoxy)phenyl) phosphate (TPP) was first synthesized and characterized with the intent of increasing the cross-linking rate of phthalonitrile resins. By combining TTP and di-functional phthalonitrile with aromatic diamine easy-processable formulations (η < 200 mPa·s at 150 °C) were developed. Thermosets were derived from the formulations by curing at 330 and 375 °C. The polymers that were post-cured at 375 °C demonstrated Young's moduli up to 7.2 GPa — which is the highest value reported for phthalonitriles. Thermal stability of these materials was on the high level featured to phthalonitriles (Tg > 450 °C, T5% > 500 °C, TOS5% > 500 °C, Yc at 900 °C > 80%). TPP, the introduced monomer, can be used as a stiffness increasing additive with common di-functional phthalonitriles, and easy-processable formulations for cost-effective techniques of composites manufacturing.</description><identifier>ISSN: 1381-5148</identifier><identifier>EISSN: 1873-166X</identifier><identifier>DOI: 10.1016/j.reactfunctpolym.2019.104409</identifier><language>eng</language><publisher>AMSTERDAM: Elsevier B.V</publisher><subject>Chemical synthesis ; Chemistry ; Chemistry, Applied ; Composite materials ; Crosslinking ; Diamines ; Engineering ; Engineering, Chemical ; Heat-resistance ; Mechanical properties ; Modulus of elasticity ; Monomers ; Phosphates ; Phthalonitrile ; Physical Sciences ; Polymer Science ; Polymers ; Resins ; Science & Technology ; Stiffness ; Technology ; Thermal stability ; Thermoset ; Young's modulus</subject><ispartof>Reactive & functional polymers, 2020-01, Vol.146, p.104409, Article 104409</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jan 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>26</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000510946900010</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c361t-8a65ccdfe2c90cdcdc8f643e5437a63813b3aeca58f59014375746bc334242a33</citedby><cites>FETCH-LOGICAL-c361t-8a65ccdfe2c90cdcdc8f643e5437a63813b3aeca58f59014375746bc334242a33</cites><orcidid>0000-0003-3852-1066</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.reactfunctpolym.2019.104409$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,28253,46000</link.rule.ids></links><search><creatorcontrib>Yakovlev, M.V.</creatorcontrib><creatorcontrib>Morozov, O.S.</creatorcontrib><creatorcontrib>Afanaseva, E.S.</creatorcontrib><creatorcontrib>Bulgakov, B.A.</creatorcontrib><creatorcontrib>Babkin, A.V.</creatorcontrib><creatorcontrib>Kepman, A.V.</creatorcontrib><title>Tri-functional phthalonitrile monomer as stiffness increasing additive for easy processable high performance resins</title><title>Reactive & functional polymers</title><addtitle>REACT FUNCT POLYM</addtitle><description>A new tri-functional phthalonitrile monomer tris(3-(3,4-dicyanophenoxy)phenyl) phosphate (TPP) was first synthesized and characterized with the intent of increasing the cross-linking rate of phthalonitrile resins. By combining TTP and di-functional phthalonitrile with aromatic diamine easy-processable formulations (η < 200 mPa·s at 150 °C) were developed. Thermosets were derived from the formulations by curing at 330 and 375 °C. The polymers that were post-cured at 375 °C demonstrated Young's moduli up to 7.2 GPa — which is the highest value reported for phthalonitriles. Thermal stability of these materials was on the high level featured to phthalonitriles (Tg > 450 °C, T5% > 500 °C, TOS5% > 500 °C, Yc at 900 °C > 80%). TPP, the introduced monomer, can be used as a stiffness increasing additive with common di-functional phthalonitriles, and easy-processable formulations for cost-effective techniques of composites manufacturing.</description><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry, Applied</subject><subject>Composite materials</subject><subject>Crosslinking</subject><subject>Diamines</subject><subject>Engineering</subject><subject>Engineering, Chemical</subject><subject>Heat-resistance</subject><subject>Mechanical properties</subject><subject>Modulus of elasticity</subject><subject>Monomers</subject><subject>Phosphates</subject><subject>Phthalonitrile</subject><subject>Physical Sciences</subject><subject>Polymer Science</subject><subject>Polymers</subject><subject>Resins</subject><subject>Science & Technology</subject><subject>Stiffness</subject><subject>Technology</subject><subject>Thermal stability</subject><subject>Thermoset</subject><subject>Young's modulus</subject><issn>1381-5148</issn><issn>1873-166X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkE1r3DAQhk1oIWmS_yAIORVvJOvD9qGHsrRJINBLAr0JrTzKarElV9Km7L_vbBxy6CnooGHmfebjraprRleMMnWzWyUwtrh9sGWO42FaNZT1WBOC9ifVGetaXjOlfn_CmHeslkx0p9WXnHeUshYrZ1V-TL5-7eBjMCOZt2Vrxhh8SX4EMsUQJ0jEZJKLdy5AzsQHi4OzD8_EDIMv_gWIi4lg7kDmFC2KzAbprX_ekhkSFicTLJAESOWL6rMzY4bLt_-8evr543F9Vz_8ur1ff3-oLVes1J1R0trBQWN7agd8nVOCgxS8NQrv4RtuwBrZOdlThlnZCrWxnItGNIbz8-pq6Ys7_dlDLnoX9wmvzLrhUjZt36keVd8WlU0x5wROz8lPJh00o_ros97p_3zWR5_14jPy3cL_hU102XrAS997UEolo71QPUaMrn0xR6fXcR8Kol8_jqL6dlEDevbiIek3YvAJbNFD9B9c-R_Jm7Rv</recordid><startdate>202001</startdate><enddate>202001</enddate><creator>Yakovlev, M.V.</creator><creator>Morozov, O.S.</creator><creator>Afanaseva, E.S.</creator><creator>Bulgakov, B.A.</creator><creator>Babkin, A.V.</creator><creator>Kepman, A.V.</creator><general>Elsevier B.V</general><general>Elsevier</general><general>Elsevier BV</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-3852-1066</orcidid></search><sort><creationdate>202001</creationdate><title>Tri-functional phthalonitrile monomer as stiffness increasing additive for easy processable high performance resins</title><author>Yakovlev, M.V. ; Morozov, O.S. ; Afanaseva, E.S. ; Bulgakov, B.A. ; Babkin, A.V. ; Kepman, A.V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-8a65ccdfe2c90cdcdc8f643e5437a63813b3aeca58f59014375746bc334242a33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry, Applied</topic><topic>Composite materials</topic><topic>Crosslinking</topic><topic>Diamines</topic><topic>Engineering</topic><topic>Engineering, Chemical</topic><topic>Heat-resistance</topic><topic>Mechanical properties</topic><topic>Modulus of elasticity</topic><topic>Monomers</topic><topic>Phosphates</topic><topic>Phthalonitrile</topic><topic>Physical Sciences</topic><topic>Polymer Science</topic><topic>Polymers</topic><topic>Resins</topic><topic>Science & Technology</topic><topic>Stiffness</topic><topic>Technology</topic><topic>Thermal stability</topic><topic>Thermoset</topic><topic>Young's modulus</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yakovlev, M.V.</creatorcontrib><creatorcontrib>Morozov, O.S.</creatorcontrib><creatorcontrib>Afanaseva, E.S.</creatorcontrib><creatorcontrib>Bulgakov, B.A.</creatorcontrib><creatorcontrib>Babkin, A.V.</creatorcontrib><creatorcontrib>Kepman, A.V.</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Reactive & functional polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yakovlev, M.V.</au><au>Morozov, O.S.</au><au>Afanaseva, E.S.</au><au>Bulgakov, B.A.</au><au>Babkin, A.V.</au><au>Kepman, A.V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tri-functional phthalonitrile monomer as stiffness increasing additive for easy processable high performance resins</atitle><jtitle>Reactive & functional polymers</jtitle><stitle>REACT FUNCT POLYM</stitle><date>2020-01</date><risdate>2020</risdate><volume>146</volume><spage>104409</spage><pages>104409-</pages><artnum>104409</artnum><issn>1381-5148</issn><eissn>1873-166X</eissn><abstract>A new tri-functional phthalonitrile monomer tris(3-(3,4-dicyanophenoxy)phenyl) phosphate (TPP) was first synthesized and characterized with the intent of increasing the cross-linking rate of phthalonitrile resins. By combining TTP and di-functional phthalonitrile with aromatic diamine easy-processable formulations (η < 200 mPa·s at 150 °C) were developed. Thermosets were derived from the formulations by curing at 330 and 375 °C. The polymers that were post-cured at 375 °C demonstrated Young's moduli up to 7.2 GPa — which is the highest value reported for phthalonitriles. Thermal stability of these materials was on the high level featured to phthalonitriles (Tg > 450 °C, T5% > 500 °C, TOS5% > 500 °C, Yc at 900 °C > 80%). TPP, the introduced monomer, can be used as a stiffness increasing additive with common di-functional phthalonitriles, and easy-processable formulations for cost-effective techniques of composites manufacturing.</abstract><cop>AMSTERDAM</cop><pub>Elsevier B.V</pub><doi>10.1016/j.reactfunctpolym.2019.104409</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-3852-1066</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1381-5148 |
| ispartof | Reactive & functional polymers, 2020-01, Vol.146, p.104409, Article 104409 |
| issn | 1381-5148 1873-166X |
| language | eng |
| recordid | cdi_proquest_journals_2355279869 |
| source | Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; Access via ScienceDirect (Elsevier) |
| subjects | Chemical synthesis Chemistry Chemistry, Applied Composite materials Crosslinking Diamines Engineering Engineering, Chemical Heat-resistance Mechanical properties Modulus of elasticity Monomers Phosphates Phthalonitrile Physical Sciences Polymer Science Polymers Resins Science & Technology Stiffness Technology Thermal stability Thermoset Young's modulus |
| title | Tri-functional phthalonitrile monomer as stiffness increasing additive for easy processable high performance resins |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-12T10%3A58%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_elsev&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Tri-functional%20phthalonitrile%20monomer%20as%20stiffness%20increasing%20additive%20for%20easy%20processable%20high%20performance%20resins&rft.jtitle=Reactive%20&%20functional%20polymers&rft.au=Yakovlev,%20M.V.&rft.date=2020-01&rft.volume=146&rft.spage=104409&rft.pages=104409-&rft.artnum=104409&rft.issn=1381-5148&rft.eissn=1873-166X&rft_id=info:doi/10.1016/j.reactfunctpolym.2019.104409&rft_dat=%3Cproquest_elsev%3E2355279869%3C/proquest_elsev%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2355279869&rft_id=info:pmid/&rft_els_id=S1381514819310235&rfr_iscdi=true |