Synthesis of Magnetic Chitosan-Fly Ash/Fe3O4 Composite for Adsorption of Reactive Orange 16 Dye: Optimization by Box–Behnken Design
A hybrid composite biopolymer of magnetic chitosan-fly ash/Fe 3 O 4 (CS-FA/Fe 3 O 4 ) was prepared to be an effective composite biosorbent for the removal of reactive orange 16 (RO16) dye from aqueous media. Various analytical techniques such as XRF, BET, XRD, FTIR, and SEM–EDX were utilized to char...
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| Veröffentlicht in: | Journal of polymers and the environment 2020-03, Vol.28 (3), p.1068-1082 |
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| creator | Jawad, Ali H. Malek, Nurul Najwa Abd Abdulhameed, Ahmed Saud Razuan, R. |
| description | A hybrid composite biopolymer of magnetic chitosan-fly ash/Fe
3
O
4
(CS-FA/Fe
3
O
4
) was prepared to be an effective composite biosorbent for the removal of reactive orange 16 (RO16) dye from aqueous media. Various analytical techniques such as XRF, BET, XRD, FTIR, and SEM–EDX were utilized to characterize of CS-FA/Fe
3
O
4
composite. The effects of adsorption process parameters namely adsorbent dose (A: 0.04–0.12 g), solution pH (B: 4–10), temperature (C: 30–50 °C), and time (E: 20–90 min) were optimized by using Box–Behnken design (BBD) in response surface methodology (RSM). The experimental results indicate that the highest RO16 removal was 73.1% by significant interaction between BC (p-value = 0.0002) and AD (p-value = 0.022). The optimum RO16 dye removal conditions were recorded at solution pH ~ 4, adsorbent dose (0.08 g), temperature (30 °C), and time (55 min). The adsorption process was well described by pseudo-second order (PSO) kinetic and Freundlich isotherm model. The adsorption capacity of CS-FA/Fe
3
O
4
composite for RO16 dye was 66.9 mg/g at 30 °C. The mechanism of the RO16 dye adsorption included many interactions such as electrostatic, n–π interaction, H-bonding, and Yoshida H-bonding. Furthermore, the CS-FA/Fe
3
O
4
composite exhibited a high ability to separate from the aqueous solution after adsorption process by external magnetic field. |
| doi_str_mv | 10.1007/s10924-020-01669-z |
| format | Article |
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3
O
4
(CS-FA/Fe
3
O
4
) was prepared to be an effective composite biosorbent for the removal of reactive orange 16 (RO16) dye from aqueous media. Various analytical techniques such as XRF, BET, XRD, FTIR, and SEM–EDX were utilized to characterize of CS-FA/Fe
3
O
4
composite. The effects of adsorption process parameters namely adsorbent dose (A: 0.04–0.12 g), solution pH (B: 4–10), temperature (C: 30–50 °C), and time (E: 20–90 min) were optimized by using Box–Behnken design (BBD) in response surface methodology (RSM). The experimental results indicate that the highest RO16 removal was 73.1% by significant interaction between BC (p-value = 0.0002) and AD (p-value = 0.022). The optimum RO16 dye removal conditions were recorded at solution pH ~ 4, adsorbent dose (0.08 g), temperature (30 °C), and time (55 min). The adsorption process was well described by pseudo-second order (PSO) kinetic and Freundlich isotherm model. The adsorption capacity of CS-FA/Fe
3
O
4
composite for RO16 dye was 66.9 mg/g at 30 °C. The mechanism of the RO16 dye adsorption included many interactions such as electrostatic, n–π interaction, H-bonding, and Yoshida H-bonding. Furthermore, the CS-FA/Fe
3
O
4
composite exhibited a high ability to separate from the aqueous solution after adsorption process by external magnetic field.</description><identifier>ISSN: 1566-2543</identifier><identifier>EISSN: 1572-8919</identifier><identifier>DOI: 10.1007/s10924-020-01669-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorbents ; Adsorption ; Aqueous solutions ; Biopolymers ; Bonding ; Chemistry ; Chemistry and Materials Science ; Chitosan ; Color removal ; Design optimization ; Dyes ; Electrostatic properties ; Environmental Chemistry ; Environmental Engineering/Biotechnology ; Fly ash ; Hybrid composites ; Industrial Chemistry/Chemical Engineering ; Iron oxides ; Magnetic fields ; Materials Science ; Original Paper ; pH effects ; Polymer Sciences ; Process parameters ; Response surface methodology</subject><ispartof>Journal of polymers and the environment, 2020-03, Vol.28 (3), p.1068-1082</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>Journal of Polymers and the Environment is a copyright of Springer, (2020). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-7a8bc7c7504a1af265e542cdbd64cbc912cff519ef5e884d1fffdc8babed518e3</citedby><cites>FETCH-LOGICAL-c356t-7a8bc7c7504a1af265e542cdbd64cbc912cff519ef5e884d1fffdc8babed518e3</cites><orcidid>0000-0002-4827-9093</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10924-020-01669-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10924-020-01669-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Jawad, Ali H.</creatorcontrib><creatorcontrib>Malek, Nurul Najwa Abd</creatorcontrib><creatorcontrib>Abdulhameed, Ahmed Saud</creatorcontrib><creatorcontrib>Razuan, R.</creatorcontrib><title>Synthesis of Magnetic Chitosan-Fly Ash/Fe3O4 Composite for Adsorption of Reactive Orange 16 Dye: Optimization by Box–Behnken Design</title><title>Journal of polymers and the environment</title><addtitle>J Polym Environ</addtitle><description>A hybrid composite biopolymer of magnetic chitosan-fly ash/Fe
3
O
4
(CS-FA/Fe
3
O
4
) was prepared to be an effective composite biosorbent for the removal of reactive orange 16 (RO16) dye from aqueous media. Various analytical techniques such as XRF, BET, XRD, FTIR, and SEM–EDX were utilized to characterize of CS-FA/Fe
3
O
4
composite. The effects of adsorption process parameters namely adsorbent dose (A: 0.04–0.12 g), solution pH (B: 4–10), temperature (C: 30–50 °C), and time (E: 20–90 min) were optimized by using Box–Behnken design (BBD) in response surface methodology (RSM). The experimental results indicate that the highest RO16 removal was 73.1% by significant interaction between BC (p-value = 0.0002) and AD (p-value = 0.022). The optimum RO16 dye removal conditions were recorded at solution pH ~ 4, adsorbent dose (0.08 g), temperature (30 °C), and time (55 min). The adsorption process was well described by pseudo-second order (PSO) kinetic and Freundlich isotherm model. The adsorption capacity of CS-FA/Fe
3
O
4
composite for RO16 dye was 66.9 mg/g at 30 °C. The mechanism of the RO16 dye adsorption included many interactions such as electrostatic, n–π interaction, H-bonding, and Yoshida H-bonding. Furthermore, the CS-FA/Fe
3
O
4
composite exhibited a high ability to separate from the aqueous solution after adsorption process by external magnetic field.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Biopolymers</subject><subject>Bonding</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chitosan</subject><subject>Color removal</subject><subject>Design optimization</subject><subject>Dyes</subject><subject>Electrostatic properties</subject><subject>Environmental Chemistry</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Fly ash</subject><subject>Hybrid composites</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Iron oxides</subject><subject>Magnetic fields</subject><subject>Materials Science</subject><subject>Original Paper</subject><subject>pH effects</subject><subject>Polymer Sciences</subject><subject>Process parameters</subject><subject>Response surface methodology</subject><issn>1566-2543</issn><issn>1572-8919</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kMtOwzAQRSMEEs8fYGWJtcF2bCdhVwoFJFAlHmvLccZtgNrFDoh0xYYv4A_5ElyKxI7VzOKcO5qbZfuUHFJCiqNIScU4JoxgQqWs8GIt26KiYLisaLW-3KXETPB8M9uO8YEQUiVxK_u47V03hdhG5C261hMHXWvQcNp2PmqHR089GsTp0QjyMUdDP5v72HaArA9o0EQf5l3r3dK9AW269hXQOGg3AUQlOu3hGI0TMWsX-oere3Ti377eP09g6h7BodN0euJ2sw2rnyLs_c6d7H50dje8wFfj88vh4AqbXMgOF7qsTWEKQbim2jIpQHBmmrqR3NSmosxYK2gFVkBZ8oZaaxtT1rqGRtAS8p3sYJU7D_75BWKnHvxLcOmkYrngkpScFoliK8oEH2MAq-ahnenQK0rUsm61qlulutVP3WqRpHwlxQSn_8Nf9D_WNzBthgo</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Jawad, Ali H.</creator><creator>Malek, Nurul Najwa Abd</creator><creator>Abdulhameed, Ahmed Saud</creator><creator>Razuan, R.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><orcidid>https://orcid.org/0000-0002-4827-9093</orcidid></search><sort><creationdate>20200301</creationdate><title>Synthesis of Magnetic Chitosan-Fly Ash/Fe3O4 Composite for Adsorption of Reactive Orange 16 Dye: Optimization by Box–Behnken Design</title><author>Jawad, Ali H. ; Malek, Nurul Najwa Abd ; Abdulhameed, Ahmed Saud ; Razuan, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-7a8bc7c7504a1af265e542cdbd64cbc912cff519ef5e884d1fffdc8babed518e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Biopolymers</topic><topic>Bonding</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chitosan</topic><topic>Color removal</topic><topic>Design optimization</topic><topic>Dyes</topic><topic>Electrostatic properties</topic><topic>Environmental Chemistry</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Fly ash</topic><topic>Hybrid composites</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Iron oxides</topic><topic>Magnetic fields</topic><topic>Materials Science</topic><topic>Original Paper</topic><topic>pH effects</topic><topic>Polymer Sciences</topic><topic>Process parameters</topic><topic>Response surface methodology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jawad, Ali H.</creatorcontrib><creatorcontrib>Malek, Nurul Najwa Abd</creatorcontrib><creatorcontrib>Abdulhameed, Ahmed Saud</creatorcontrib><creatorcontrib>Razuan, R.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of polymers and the environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jawad, Ali H.</au><au>Malek, Nurul Najwa Abd</au><au>Abdulhameed, Ahmed Saud</au><au>Razuan, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Magnetic Chitosan-Fly Ash/Fe3O4 Composite for Adsorption of Reactive Orange 16 Dye: Optimization by Box–Behnken Design</atitle><jtitle>Journal of polymers and the environment</jtitle><stitle>J Polym Environ</stitle><date>2020-03-01</date><risdate>2020</risdate><volume>28</volume><issue>3</issue><spage>1068</spage><epage>1082</epage><pages>1068-1082</pages><issn>1566-2543</issn><eissn>1572-8919</eissn><abstract>A hybrid composite biopolymer of magnetic chitosan-fly ash/Fe
3
O
4
(CS-FA/Fe
3
O
4
) was prepared to be an effective composite biosorbent for the removal of reactive orange 16 (RO16) dye from aqueous media. Various analytical techniques such as XRF, BET, XRD, FTIR, and SEM–EDX were utilized to characterize of CS-FA/Fe
3
O
4
composite. The effects of adsorption process parameters namely adsorbent dose (A: 0.04–0.12 g), solution pH (B: 4–10), temperature (C: 30–50 °C), and time (E: 20–90 min) were optimized by using Box–Behnken design (BBD) in response surface methodology (RSM). The experimental results indicate that the highest RO16 removal was 73.1% by significant interaction between BC (p-value = 0.0002) and AD (p-value = 0.022). The optimum RO16 dye removal conditions were recorded at solution pH ~ 4, adsorbent dose (0.08 g), temperature (30 °C), and time (55 min). The adsorption process was well described by pseudo-second order (PSO) kinetic and Freundlich isotherm model. The adsorption capacity of CS-FA/Fe
3
O
4
composite for RO16 dye was 66.9 mg/g at 30 °C. The mechanism of the RO16 dye adsorption included many interactions such as electrostatic, n–π interaction, H-bonding, and Yoshida H-bonding. Furthermore, the CS-FA/Fe
3
O
4
composite exhibited a high ability to separate from the aqueous solution after adsorption process by external magnetic field.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-020-01669-z</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0002-4827-9093</orcidid></addata></record> |
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| source | SpringerLink Journals |
| subjects | Adsorbents Adsorption Aqueous solutions Biopolymers Bonding Chemistry Chemistry and Materials Science Chitosan Color removal Design optimization Dyes Electrostatic properties Environmental Chemistry Environmental Engineering/Biotechnology Fly ash Hybrid composites Industrial Chemistry/Chemical Engineering Iron oxides Magnetic fields Materials Science Original Paper pH effects Polymer Sciences Process parameters Response surface methodology |
| title | Synthesis of Magnetic Chitosan-Fly Ash/Fe3O4 Composite for Adsorption of Reactive Orange 16 Dye: Optimization by Box–Behnken Design |
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