Effects of Boron Nitride Coatings at High Temperatures and Electromagnetic Wave Absorption Properties of Carbon Fiber-Based Magnetic Materials

An electromagnetic (EM) wave-absorbing material with a three-layer structure is prepared by depositing magnetic particles and a high-temperature resistant coating on the surface of the carbon fiber (CF) with in situ hybridization. Accordingly, the structure, chemical composition, morphology, high-te...

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Veröffentlicht in:Journal of nanomaterials 2020, Vol.2020 (2020), p.1-12
Hauptverfasser: Long, Xiaoyun, Cheng, Jiahao, Ye, Wei, Sun, Qilong
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Cheng, Jiahao
Ye, Wei
Sun, Qilong
description An electromagnetic (EM) wave-absorbing material with a three-layer structure is prepared by depositing magnetic particles and a high-temperature resistant coating on the surface of the carbon fiber (CF) with in situ hybridization. Accordingly, the structure, chemical composition, morphology, high-temperature resistance, EM characteristics, and EM wave absorption of the composite materials were analyzed. The composite materials contained CFs, and the magnetic particles, such as Fe3O4, NiFe2O4, CoFe2O4, and Ni3Fe, distributed along the axial direction of the fiber, while boron nitride (BN) existed in the outermost coating layer. This preparation method improves the oxidation resistance and EM wave absorption performance of the CF. When the concentrations of the metal salt solution and the original BN solution are 0.625×1.5 mol L-1 [nFeCl3: nCoSO4: nNiSO4=2:2:1] and 4 mol L-1 [nH3BO3:nCONH22=1:3], respectively, the thermal decomposition temperature of the prepared CF/1.5FeCoNi/2BN is increased from 450°C to 754°C. In the frequency range of 10.6–26 GHz, the EM wave loss is less than −10 dB (the bandwidth spans 15.4 GHz). The CF-based composite material prepared in this study has the characteristics of light weight, wide absorption band, and strong oxidation resistance and constitutes the reference basis for the study of other high-temperature, EM wave-absorbing materials.
doi_str_mv 10.1155/2020/3672517
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Accordingly, the structure, chemical composition, morphology, high-temperature resistance, EM characteristics, and EM wave absorption of the composite materials were analyzed. The composite materials contained CFs, and the magnetic particles, such as Fe3O4, NiFe2O4, CoFe2O4, and Ni3Fe, distributed along the axial direction of the fiber, while boron nitride (BN) existed in the outermost coating layer. This preparation method improves the oxidation resistance and EM wave absorption performance of the CF. When the concentrations of the metal salt solution and the original BN solution are 0.625×1.5 mol L-1 [nFeCl3: nCoSO4: nNiSO4=2:2:1] and 4 mol L-1 [nH3BO3:nCONH22=1:3], respectively, the thermal decomposition temperature of the prepared CF/1.5FeCoNi/2BN is increased from 450°C to 754°C. In the frequency range of 10.6–26 GHz, the EM wave loss is less than −10 dB (the bandwidth spans 15.4 GHz). The CF-based composite material prepared in this study has the characteristics of light weight, wide absorption band, and strong oxidation resistance and constitutes the reference basis for the study of other high-temperature, EM wave-absorbing materials.</description><identifier>ISSN: 1687-4110</identifier><identifier>EISSN: 1687-4129</identifier><identifier>DOI: 10.1155/2020/3672517</identifier><language>eng</language><publisher>Cairo, Egypt: Hindawi Publishing Corporation</publisher><subject>Absorption spectra ; Boron ; Boron fibers ; Boron nitride ; Carbon fibers ; Chemical composition ; Cobalt ferrites ; Composite materials ; Electromagnetic radiation ; Fourier transforms ; Frequency ranges ; High temperature ; Iron compounds ; Iron oxides ; Magnetic materials ; Magnetic properties ; Morphology ; Nanomaterials ; Nickel base alloys ; Nickel compounds ; Nickel ferrites ; Organic chemistry ; Oxidation ; Oxidation resistance ; Saline solutions ; Thermal decomposition ; Wave resistance ; Weight reduction</subject><ispartof>Journal of nanomaterials, 2020, Vol.2020 (2020), p.1-12</ispartof><rights>Copyright © 2020 Qilong Sun et al.</rights><rights>Copyright © 2020 Qilong Sun et al. This is an open access article distributed under the Creative Commons Attribution License (the “License”), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. 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Accordingly, the structure, chemical composition, morphology, high-temperature resistance, EM characteristics, and EM wave absorption of the composite materials were analyzed. The composite materials contained CFs, and the magnetic particles, such as Fe3O4, NiFe2O4, CoFe2O4, and Ni3Fe, distributed along the axial direction of the fiber, while boron nitride (BN) existed in the outermost coating layer. This preparation method improves the oxidation resistance and EM wave absorption performance of the CF. When the concentrations of the metal salt solution and the original BN solution are 0.625×1.5 mol L-1 [nFeCl3: nCoSO4: nNiSO4=2:2:1] and 4 mol L-1 [nH3BO3:nCONH22=1:3], respectively, the thermal decomposition temperature of the prepared CF/1.5FeCoNi/2BN is increased from 450°C to 754°C. In the frequency range of 10.6–26 GHz, the EM wave loss is less than −10 dB (the bandwidth spans 15.4 GHz). The CF-based composite material prepared in this study has the characteristics of light weight, wide absorption band, and strong oxidation resistance and constitutes the reference basis for the study of other high-temperature, EM wave-absorbing materials.</abstract><cop>Cairo, Egypt</cop><pub>Hindawi Publishing Corporation</pub><doi>10.1155/2020/3672517</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-5275-7721</orcidid><oa>free_for_read</oa></addata></record>
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subjects Absorption spectra
Boron
Boron fibers
Boron nitride
Carbon fibers
Chemical composition
Cobalt ferrites
Composite materials
Electromagnetic radiation
Fourier transforms
Frequency ranges
High temperature
Iron compounds
Iron oxides
Magnetic materials
Magnetic properties
Morphology
Nanomaterials
Nickel base alloys
Nickel compounds
Nickel ferrites
Organic chemistry
Oxidation
Oxidation resistance
Saline solutions
Thermal decomposition
Wave resistance
Weight reduction
title Effects of Boron Nitride Coatings at High Temperatures and Electromagnetic Wave Absorption Properties of Carbon Fiber-Based Magnetic Materials
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