An efficient CO2 fixation reaction with epoxides catalysed by in situ formed blue vanadium catalyst from dioxovanadium(+5) complex: moisture enhanced and atmospheric oxygen retarded catalytic activity

Two new dioxovanadium(+5) complexes, one anionic and other neutral, have been synthesized and characterized by X-ray crystallography in this work. While doing cycloaddition reaction of CO2 to epoxides, taking dioxovanadium(+5) complex as the catalyst, a blue vanadium complex was generated in situ, w...

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Veröffentlicht in:	New journal of chemistry 2020-02, Vol.44 (6), p.2547-2554
Hauptverfasser:	Borah, Rakhimoni, Deori, Naranarayan, Brahma, Sanfaori
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Catalysts Catalytic activity Crystallography Cycloaddition Fixation Flue gas Moisture Oxygen Tetrabutylammonium bromide Vanadium
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