Polydopamine as reinforcement in the coating of nano-silver on polyurethane surface: Performance and mechanisms

•A facile, mild and green method was proposed for fabricating AgNPs on the polyurethane by using the polydopamine.•PDA was eff ;ectively reinforce the coating of nano-silver on polyurethane surface.•More nanosilvers were loaded onto the polyurethane at the DA concentration of 12 g/L.•Catechol groups...

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Veröffentlicht in:Progress in organic coatings 2019-12, Vol.137, p.105288, Article 105288
Hauptverfasser: Chen, Jianfeng, Wang, Qi, Luan, Mingxing, Mo, Jingwen, Yan, Yuefen, Li, Xiaobing
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container_issue
container_start_page 105288
container_title Progress in organic coatings
container_volume 137
creator Chen, Jianfeng
Wang, Qi
Luan, Mingxing
Mo, Jingwen
Yan, Yuefen
Li, Xiaobing
description •A facile, mild and green method was proposed for fabricating AgNPs on the polyurethane by using the polydopamine.•PDA was eff ;ectively reinforce the coating of nano-silver on polyurethane surface.•More nanosilvers were loaded onto the polyurethane at the DA concentration of 12 g/L.•Catechol groups of PDA chelated with [Ag(NH3)2]+ and reduced [Ag(NH3)2]+ to Ag0. Polyurethane (PU) is a popular medical polymer material and plays a vital role in many artificial organs and medical devices. The antibacterial properties of medical polyurethanes have always been a research hotspot for scientists. We studied the effect of polydopamine (PDA) modification and dopamine (DA) concentration on the coating of nano-silver on polyurethane surface, and investigated the bonding mechanism between nano-silver layer and modified polyurethane. We found that the polydopamine-modified polyurethane has a better nano-silver coating on the surface and a uniform distribution.We also found that the catechol groups in the PDA film could chelate with Ag+ or [Ag(NH3)2]+ and in situ reduce the Ag+ or [Ag(NH3)2]+ to Ag0 without extra reducing agent.
doi_str_mv 10.1016/j.porgcoat.2019.105288
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Polyurethane (PU) is a popular medical polymer material and plays a vital role in many artificial organs and medical devices. The antibacterial properties of medical polyurethanes have always been a research hotspot for scientists. We studied the effect of polydopamine (PDA) modification and dopamine (DA) concentration on the coating of nano-silver on polyurethane surface, and investigated the bonding mechanism between nano-silver layer and modified polyurethane. 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Polyurethane (PU) is a popular medical polymer material and plays a vital role in many artificial organs and medical devices. The antibacterial properties of medical polyurethanes have always been a research hotspot for scientists. We studied the effect of polydopamine (PDA) modification and dopamine (DA) concentration on the coating of nano-silver on polyurethane surface, and investigated the bonding mechanism between nano-silver layer and modified polyurethane. We found that the polydopamine-modified polyurethane has a better nano-silver coating on the surface and a uniform distribution.We also found that the catechol groups in the PDA film could chelate with Ag+ or [Ag(NH3)2]+ and in situ reduce the Ag+ or [Ag(NH3)2]+ to Ag0 without extra reducing agent.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.porgcoat.2019.105288</doi></addata></record>
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subjects Ammonia
Artificial organs
Binding mechanism
Binding strength
Catechol
Chelates
Coating
Dopamine
Medical devices
Medical electronics
Medical materials
Medical research
Nano-silver layer
Polydopamine
Polyurethane
Polyurethane resins
Reducing agents
Silver
title Polydopamine as reinforcement in the coating of nano-silver on polyurethane surface: Performance and mechanisms
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