Synthesis and gas permeation analysis of TiO2 nanotube-embedded cellulose acetate mixed matrix membranes
Pristine cellulose acetate (CA) membranes and CA mixed matrix membranes (MMM) embedded with titania (TiO 2 ) nanotubes (Tnts) were synthesized by loading different weight percentages of Tnts (2%, 5%, 7%, 10%) in them by employing solution casting technique. The Tnts were prepared by hydrothermal tre...
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| Veröffentlicht in: | Chemical papers 2020-03, Vol.74 (3), p.821-828 |
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| creator | Rashid, M. Hamza Farrukh, Sarah Javed, Sofia Hussain, Arshad Fan, X. Ali, Sarim Ayoub, Muhammad |
| description | Pristine cellulose acetate (CA) membranes and CA mixed matrix membranes (MMM) embedded with titania (TiO
2
) nanotubes (Tnts) were synthesized by loading different weight percentages of Tnts (2%, 5%, 7%, 10%) in them by employing solution casting technique. The Tnts were prepared by hydrothermal treatment of TiO
2
nanoparticles in aqueous NaOH solution. Permeability of different gases; CO
2
, N
2
, O
2
and CH
4
, was studied across these membranes and the results were compared for pure and mixed matrix membranes. Effect of pressure on permeability of different gases was also studied. The membranes were then analyzed by Scanning Electron Microscopy (SEM), Tensile Testing (TT) and Fourier transformation infrared spectroscopy (FTIR) techniques. Results showed that homogeneous dispersion of tubes was achieved up till 5 wt%-CA loading. The average permeation of CO
2
obtained was 25 barrer at 5 bar pressure. It was further identified that the ultimate tensile strength of mixed matrix membranes was roughly 7 times greater than the pristine membranes.
Graphic abstract |
| doi_str_mv | 10.1007/s11696-019-00913-8 |
| format | Article |
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2
) nanotubes (Tnts) were synthesized by loading different weight percentages of Tnts (2%, 5%, 7%, 10%) in them by employing solution casting technique. The Tnts were prepared by hydrothermal treatment of TiO
2
nanoparticles in aqueous NaOH solution. Permeability of different gases; CO
2
, N
2
, O
2
and CH
4
, was studied across these membranes and the results were compared for pure and mixed matrix membranes. Effect of pressure on permeability of different gases was also studied. The membranes were then analyzed by Scanning Electron Microscopy (SEM), Tensile Testing (TT) and Fourier transformation infrared spectroscopy (FTIR) techniques. Results showed that homogeneous dispersion of tubes was achieved up till 5 wt%-CA loading. The average permeation of CO
2
obtained was 25 barrer at 5 bar pressure. It was further identified that the ultimate tensile strength of mixed matrix membranes was roughly 7 times greater than the pristine membranes.
Graphic abstract</description><identifier>ISSN: 2585-7290</identifier><identifier>ISSN: 0366-6352</identifier><identifier>EISSN: 1336-9075</identifier><identifier>DOI: 10.1007/s11696-019-00913-8</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Biochemistry ; Biotechnology ; Carbon dioxide ; Cellulose acetate ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Fourier transforms ; Gas permeation ; Hydrothermal treatment ; Industrial Chemistry/Chemical Engineering ; Materials Science ; Medicinal Chemistry ; Membranes ; Nanoparticles ; Nanotubes ; Original Paper ; Penetration ; Permeability ; Pressure effects ; Sodium hydroxide ; Titanium dioxide ; Tubes ; Ultimate tensile strength</subject><ispartof>Chemical papers, 2020-03, Vol.74 (3), p.821-828</ispartof><rights>Institute of Chemistry, Slovak Academy of Sciences 2019</rights><rights>2019© Institute of Chemistry, Slovak Academy of Sciences 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-71a5d7abdaf933c7cf1bfa0e52192933f9abbb98eb5cbbdd5cb6600a8f5a9d863</citedby><cites>FETCH-LOGICAL-c356t-71a5d7abdaf933c7cf1bfa0e52192933f9abbb98eb5cbbdd5cb6600a8f5a9d863</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11696-019-00913-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11696-019-00913-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Rashid, M. Hamza</creatorcontrib><creatorcontrib>Farrukh, Sarah</creatorcontrib><creatorcontrib>Javed, Sofia</creatorcontrib><creatorcontrib>Hussain, Arshad</creatorcontrib><creatorcontrib>Fan, X.</creatorcontrib><creatorcontrib>Ali, Sarim</creatorcontrib><creatorcontrib>Ayoub, Muhammad</creatorcontrib><title>Synthesis and gas permeation analysis of TiO2 nanotube-embedded cellulose acetate mixed matrix membranes</title><title>Chemical papers</title><addtitle>Chem. Pap</addtitle><description>Pristine cellulose acetate (CA) membranes and CA mixed matrix membranes (MMM) embedded with titania (TiO
2
) nanotubes (Tnts) were synthesized by loading different weight percentages of Tnts (2%, 5%, 7%, 10%) in them by employing solution casting technique. The Tnts were prepared by hydrothermal treatment of TiO
2
nanoparticles in aqueous NaOH solution. Permeability of different gases; CO
2
, N
2
, O
2
and CH
4
, was studied across these membranes and the results were compared for pure and mixed matrix membranes. Effect of pressure on permeability of different gases was also studied. The membranes were then analyzed by Scanning Electron Microscopy (SEM), Tensile Testing (TT) and Fourier transformation infrared spectroscopy (FTIR) techniques. Results showed that homogeneous dispersion of tubes was achieved up till 5 wt%-CA loading. The average permeation of CO
2
obtained was 25 barrer at 5 bar pressure. It was further identified that the ultimate tensile strength of mixed matrix membranes was roughly 7 times greater than the pristine membranes.
Graphic abstract</description><subject>Biochemistry</subject><subject>Biotechnology</subject><subject>Carbon dioxide</subject><subject>Cellulose acetate</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Fourier transforms</subject><subject>Gas permeation</subject><subject>Hydrothermal treatment</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Materials Science</subject><subject>Medicinal Chemistry</subject><subject>Membranes</subject><subject>Nanoparticles</subject><subject>Nanotubes</subject><subject>Original Paper</subject><subject>Penetration</subject><subject>Permeability</subject><subject>Pressure effects</subject><subject>Sodium hydroxide</subject><subject>Titanium dioxide</subject><subject>Tubes</subject><subject>Ultimate tensile strength</subject><issn>2585-7290</issn><issn>0366-6352</issn><issn>1336-9075</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kEtrwzAQhEVpoSHNH-hJ0LNaPSLbOpbQFwRyaHoWK2uduPiRSjYk_75KXeitl12YnRnYj5Bbwe8F5_lDFCIzGePCMM6NUKy4IDOhVMYMz_UlmUldaJZLw6_JIsba8eUyV7LI8hnZv5-6YY-xjhQ6T3cQ6QFDizDUfZckaE7nW1_Rbb2RtIOuH0aHDFuH3qOnJTbN2PQRKZQ4wIC0rY9Jb2EI9ZG2yRigw3hDripoIi5-95x8PD9tV69svXl5Wz2uWal0NrBcgPY5OA-VUarMy0q4CjhqKYxMSmXAOWcKdLp0zvs0s4xzKCoNxheZmpO7qfcQ-q8R42A_-zGkP6KVSnOjCsmXySUnVxn6GANW9hDqFsLJCm7PUO0E1Sao9geqLVJITaGYzN0Ow1_1P6lv8ZN8mA</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Rashid, M. Hamza</creator><creator>Farrukh, Sarah</creator><creator>Javed, Sofia</creator><creator>Hussain, Arshad</creator><creator>Fan, X.</creator><creator>Ali, Sarim</creator><creator>Ayoub, Muhammad</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20200301</creationdate><title>Synthesis and gas permeation analysis of TiO2 nanotube-embedded cellulose acetate mixed matrix membranes</title><author>Rashid, M. Hamza ; Farrukh, Sarah ; Javed, Sofia ; Hussain, Arshad ; Fan, X. ; Ali, Sarim ; Ayoub, Muhammad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-71a5d7abdaf933c7cf1bfa0e52192933f9abbb98eb5cbbdd5cb6600a8f5a9d863</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Biochemistry</topic><topic>Biotechnology</topic><topic>Carbon dioxide</topic><topic>Cellulose acetate</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Fourier transforms</topic><topic>Gas permeation</topic><topic>Hydrothermal treatment</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Materials Science</topic><topic>Medicinal Chemistry</topic><topic>Membranes</topic><topic>Nanoparticles</topic><topic>Nanotubes</topic><topic>Original Paper</topic><topic>Penetration</topic><topic>Permeability</topic><topic>Pressure effects</topic><topic>Sodium hydroxide</topic><topic>Titanium dioxide</topic><topic>Tubes</topic><topic>Ultimate tensile strength</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rashid, M. Hamza</creatorcontrib><creatorcontrib>Farrukh, Sarah</creatorcontrib><creatorcontrib>Javed, Sofia</creatorcontrib><creatorcontrib>Hussain, Arshad</creatorcontrib><creatorcontrib>Fan, X.</creatorcontrib><creatorcontrib>Ali, Sarim</creatorcontrib><creatorcontrib>Ayoub, Muhammad</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical papers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rashid, M. Hamza</au><au>Farrukh, Sarah</au><au>Javed, Sofia</au><au>Hussain, Arshad</au><au>Fan, X.</au><au>Ali, Sarim</au><au>Ayoub, Muhammad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and gas permeation analysis of TiO2 nanotube-embedded cellulose acetate mixed matrix membranes</atitle><jtitle>Chemical papers</jtitle><stitle>Chem. Pap</stitle><date>2020-03-01</date><risdate>2020</risdate><volume>74</volume><issue>3</issue><spage>821</spage><epage>828</epage><pages>821-828</pages><issn>2585-7290</issn><issn>0366-6352</issn><eissn>1336-9075</eissn><abstract>Pristine cellulose acetate (CA) membranes and CA mixed matrix membranes (MMM) embedded with titania (TiO
2
) nanotubes (Tnts) were synthesized by loading different weight percentages of Tnts (2%, 5%, 7%, 10%) in them by employing solution casting technique. The Tnts were prepared by hydrothermal treatment of TiO
2
nanoparticles in aqueous NaOH solution. Permeability of different gases; CO
2
, N
2
, O
2
and CH
4
, was studied across these membranes and the results were compared for pure and mixed matrix membranes. Effect of pressure on permeability of different gases was also studied. The membranes were then analyzed by Scanning Electron Microscopy (SEM), Tensile Testing (TT) and Fourier transformation infrared spectroscopy (FTIR) techniques. Results showed that homogeneous dispersion of tubes was achieved up till 5 wt%-CA loading. The average permeation of CO
2
obtained was 25 barrer at 5 bar pressure. It was further identified that the ultimate tensile strength of mixed matrix membranes was roughly 7 times greater than the pristine membranes.
Graphic abstract</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11696-019-00913-8</doi><tpages>8</tpages></addata></record> |
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| language | eng |
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| subjects | Biochemistry Biotechnology Carbon dioxide Cellulose acetate Chemistry Chemistry and Materials Science Chemistry/Food Science Fourier transforms Gas permeation Hydrothermal treatment Industrial Chemistry/Chemical Engineering Materials Science Medicinal Chemistry Membranes Nanoparticles Nanotubes Original Paper Penetration Permeability Pressure effects Sodium hydroxide Titanium dioxide Tubes Ultimate tensile strength |
| title | Synthesis and gas permeation analysis of TiO2 nanotube-embedded cellulose acetate mixed matrix membranes |
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