Cotton fiber functionalized with 2D covalent organic frameworks for iodine capture
By using a rapid cryogenic reaction, cotton fiber was covalently functionalized with imine-linked two-dimensional covalent organic frameworks (2D COFs), which was synthesized via an imine condensation reaction between 1,3,5-tris(4-aminophenyl)benzene and terephthaldehyde. The resulting functionalize...
Gespeichert in:
| Veröffentlicht in: | Cellulose (London) 2020-02, Vol.27 (3), p.1517-1529 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1529 |
|---|---|
| container_issue | 3 |
| container_start_page | 1517 |
| container_title | Cellulose (London) |
| container_volume | 27 |
| creator | Li, Yongqiang Li, Yarong Zhao, Qinghua Li, Li Chen, Run He, Chiyang |
| description | By using a rapid cryogenic reaction, cotton fiber was covalently functionalized with imine-linked two-dimensional covalent organic frameworks (2D COFs), which was synthesized via an imine condensation reaction between 1,3,5-tris(4-aminophenyl)benzene and terephthaldehyde. The resulting functionalized cotton (COFs@cotton) was characterized by fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscope, thermo-gravimetric analysis, nitrogen adsorption–desorption analysis and elemental analysis. The presence of a lot of imine functional groups in combination with dispersed mesoporous holes results in rapid adsorption rate and relatively high iodine affinity with uptake capacities up to 533.9 mg/g, which was much higher than that of untreated cotton. In addition, COFs@cotton also shows remarkable capability as absorbent for iodine in solution. The adsorbed iodine can be completely extracted from COFs@cotton by being washed with ethanol, permitting the simple reuse of adsorbent. This new functionalization approach can be applied to different kind of imine-linked COFs, and the corresponding adsorbents show more extensive practical application prospect for iodine capture.
Graphic abstract |
| doi_str_mv | 10.1007/s10570-019-02877-0 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2350774331</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2350774331</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-e4c5a375614b413feff8bb063e365aa9d9c93d33f75816ed4960c67a559e23ce3</originalsourceid><addsrcrecordid>eNp9kE1LAzEURYMoWKt_wFXA9ehLMkkmS6mfUBBEwV3IZJI6tZ3UJGPRX-_UEdy5eot7z-VxEDolcE4A5EUiwCUUQFQBtJKygD00IVzSoqroyz6agBK7iKlDdJTSEgCUpGSCHmch59Bh39YuYt93NrehM6v2yzV42-ZXTK-wDR9m5bqMQ1yYrrXYR7N22xDfEvYh4jY0beewNZvcR3eMDrxZJXfye6fo-eb6aXZXzB9u72eX88IyLnLhSssNk1yQsi4J8877qq5BMMcEN0Y1yirWMOYlr4hwTakEWCEN58pRZh2borNxdxPDe-9S1svQx-H3pCnjIGXJGBladGzZGFKKzutNbNcmfmoCeudOj-704E7_uNMwQGyE0lDuFi7-Tf9DfQPEaXI4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2350774331</pqid></control><display><type>article</type><title>Cotton fiber functionalized with 2D covalent organic frameworks for iodine capture</title><source>SpringerLink Journals - AutoHoldings</source><creator>Li, Yongqiang ; Li, Yarong ; Zhao, Qinghua ; Li, Li ; Chen, Run ; He, Chiyang</creator><creatorcontrib>Li, Yongqiang ; Li, Yarong ; Zhao, Qinghua ; Li, Li ; Chen, Run ; He, Chiyang</creatorcontrib><description>By using a rapid cryogenic reaction, cotton fiber was covalently functionalized with imine-linked two-dimensional covalent organic frameworks (2D COFs), which was synthesized via an imine condensation reaction between 1,3,5-tris(4-aminophenyl)benzene and terephthaldehyde. The resulting functionalized cotton (COFs@cotton) was characterized by fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscope, thermo-gravimetric analysis, nitrogen adsorption–desorption analysis and elemental analysis. The presence of a lot of imine functional groups in combination with dispersed mesoporous holes results in rapid adsorption rate and relatively high iodine affinity with uptake capacities up to 533.9 mg/g, which was much higher than that of untreated cotton. In addition, COFs@cotton also shows remarkable capability as absorbent for iodine in solution. The adsorbed iodine can be completely extracted from COFs@cotton by being washed with ethanol, permitting the simple reuse of adsorbent. This new functionalization approach can be applied to different kind of imine-linked COFs, and the corresponding adsorbents show more extensive practical application prospect for iodine capture.
Graphic abstract</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-019-02877-0</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Adsorbents ; Adsorption ; Benzene ; Bioorganic Chemistry ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Cotton ; Cotton fibers ; Covalence ; Ethanol ; Fourier transforms ; Functional groups ; Glass ; Gravimetric analysis ; Infrared analysis ; Iodine ; Natural Materials ; Organic Chemistry ; Original Research ; Physical Chemistry ; Polymer Sciences ; Sustainable Development ; X ray powder diffraction</subject><ispartof>Cellulose (London), 2020-02, Vol.27 (3), p.1517-1529</ispartof><rights>Springer Nature B.V. 2019</rights><rights>Cellulose is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-e4c5a375614b413feff8bb063e365aa9d9c93d33f75816ed4960c67a559e23ce3</citedby><cites>FETCH-LOGICAL-c356t-e4c5a375614b413feff8bb063e365aa9d9c93d33f75816ed4960c67a559e23ce3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-019-02877-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-019-02877-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Li, Yongqiang</creatorcontrib><creatorcontrib>Li, Yarong</creatorcontrib><creatorcontrib>Zhao, Qinghua</creatorcontrib><creatorcontrib>Li, Li</creatorcontrib><creatorcontrib>Chen, Run</creatorcontrib><creatorcontrib>He, Chiyang</creatorcontrib><title>Cotton fiber functionalized with 2D covalent organic frameworks for iodine capture</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>By using a rapid cryogenic reaction, cotton fiber was covalently functionalized with imine-linked two-dimensional covalent organic frameworks (2D COFs), which was synthesized via an imine condensation reaction between 1,3,5-tris(4-aminophenyl)benzene and terephthaldehyde. The resulting functionalized cotton (COFs@cotton) was characterized by fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscope, thermo-gravimetric analysis, nitrogen adsorption–desorption analysis and elemental analysis. The presence of a lot of imine functional groups in combination with dispersed mesoporous holes results in rapid adsorption rate and relatively high iodine affinity with uptake capacities up to 533.9 mg/g, which was much higher than that of untreated cotton. In addition, COFs@cotton also shows remarkable capability as absorbent for iodine in solution. The adsorbed iodine can be completely extracted from COFs@cotton by being washed with ethanol, permitting the simple reuse of adsorbent. This new functionalization approach can be applied to different kind of imine-linked COFs, and the corresponding adsorbents show more extensive practical application prospect for iodine capture.
Graphic abstract</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Benzene</subject><subject>Bioorganic Chemistry</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Cotton</subject><subject>Cotton fibers</subject><subject>Covalence</subject><subject>Ethanol</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Glass</subject><subject>Gravimetric analysis</subject><subject>Infrared analysis</subject><subject>Iodine</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Sustainable Development</subject><subject>X ray powder diffraction</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LAzEURYMoWKt_wFXA9ehLMkkmS6mfUBBEwV3IZJI6tZ3UJGPRX-_UEdy5eot7z-VxEDolcE4A5EUiwCUUQFQBtJKygD00IVzSoqroyz6agBK7iKlDdJTSEgCUpGSCHmch59Bh39YuYt93NrehM6v2yzV42-ZXTK-wDR9m5bqMQ1yYrrXYR7N22xDfEvYh4jY0beewNZvcR3eMDrxZJXfye6fo-eb6aXZXzB9u72eX88IyLnLhSssNk1yQsi4J8877qq5BMMcEN0Y1yirWMOYlr4hwTakEWCEN58pRZh2borNxdxPDe-9S1svQx-H3pCnjIGXJGBladGzZGFKKzutNbNcmfmoCeudOj-704E7_uNMwQGyE0lDuFi7-Tf9DfQPEaXI4</recordid><startdate>20200201</startdate><enddate>20200201</enddate><creator>Li, Yongqiang</creator><creator>Li, Yarong</creator><creator>Zhao, Qinghua</creator><creator>Li, Li</creator><creator>Chen, Run</creator><creator>He, Chiyang</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20200201</creationdate><title>Cotton fiber functionalized with 2D covalent organic frameworks for iodine capture</title><author>Li, Yongqiang ; Li, Yarong ; Zhao, Qinghua ; Li, Li ; Chen, Run ; He, Chiyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-e4c5a375614b413feff8bb063e365aa9d9c93d33f75816ed4960c67a559e23ce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Benzene</topic><topic>Bioorganic Chemistry</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Cotton</topic><topic>Cotton fibers</topic><topic>Covalence</topic><topic>Ethanol</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Glass</topic><topic>Gravimetric analysis</topic><topic>Infrared analysis</topic><topic>Iodine</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Sustainable Development</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Yongqiang</creatorcontrib><creatorcontrib>Li, Yarong</creatorcontrib><creatorcontrib>Zhao, Qinghua</creatorcontrib><creatorcontrib>Li, Li</creatorcontrib><creatorcontrib>Chen, Run</creatorcontrib><creatorcontrib>He, Chiyang</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Yongqiang</au><au>Li, Yarong</au><au>Zhao, Qinghua</au><au>Li, Li</au><au>Chen, Run</au><au>He, Chiyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cotton fiber functionalized with 2D covalent organic frameworks for iodine capture</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2020-02-01</date><risdate>2020</risdate><volume>27</volume><issue>3</issue><spage>1517</spage><epage>1529</epage><pages>1517-1529</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>By using a rapid cryogenic reaction, cotton fiber was covalently functionalized with imine-linked two-dimensional covalent organic frameworks (2D COFs), which was synthesized via an imine condensation reaction between 1,3,5-tris(4-aminophenyl)benzene and terephthaldehyde. The resulting functionalized cotton (COFs@cotton) was characterized by fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscope, thermo-gravimetric analysis, nitrogen adsorption–desorption analysis and elemental analysis. The presence of a lot of imine functional groups in combination with dispersed mesoporous holes results in rapid adsorption rate and relatively high iodine affinity with uptake capacities up to 533.9 mg/g, which was much higher than that of untreated cotton. In addition, COFs@cotton also shows remarkable capability as absorbent for iodine in solution. The adsorbed iodine can be completely extracted from COFs@cotton by being washed with ethanol, permitting the simple reuse of adsorbent. This new functionalization approach can be applied to different kind of imine-linked COFs, and the corresponding adsorbents show more extensive practical application prospect for iodine capture.
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-019-02877-0</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0969-0239 |
| ispartof | Cellulose (London), 2020-02, Vol.27 (3), p.1517-1529 |
| issn | 0969-0239 1572-882X |
| language | eng |
| recordid | cdi_proquest_journals_2350774331 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Adsorbents Adsorption Benzene Bioorganic Chemistry Ceramics Chemistry Chemistry and Materials Science Composites Cotton Cotton fibers Covalence Ethanol Fourier transforms Functional groups Glass Gravimetric analysis Infrared analysis Iodine Natural Materials Organic Chemistry Original Research Physical Chemistry Polymer Sciences Sustainable Development X ray powder diffraction |
| title | Cotton fiber functionalized with 2D covalent organic frameworks for iodine capture |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-21T16%3A05%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Cotton%20fiber%20functionalized%20with%202D%20covalent%20organic%20frameworks%20for%20iodine%20capture&rft.jtitle=Cellulose%20(London)&rft.au=Li,%20Yongqiang&rft.date=2020-02-01&rft.volume=27&rft.issue=3&rft.spage=1517&rft.epage=1529&rft.pages=1517-1529&rft.issn=0969-0239&rft.eissn=1572-882X&rft_id=info:doi/10.1007/s10570-019-02877-0&rft_dat=%3Cproquest_cross%3E2350774331%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2350774331&rft_id=info:pmid/&rfr_iscdi=true |