A negative effect of carbon phase on specific capacity of electrode material consisted of nanosized bismuth vanadate embedded in carbonaceous matrix
•BiVO4 embedded and BiVO4 not embedded in carbonaceous matrix is obtained.•Crystallographic structure is the same pattern for both materials.•The presence of carbon phase stabilizes electrochemical properties of an electrode.•BiVO4 is electrochemical active towards reversible lithium intercalation....
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| Veröffentlicht in: | Synthetic metals 2019-11, Vol.257, p.116168, Article 116168 |
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| container_title | Synthetic metals |
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| creator | Nowak, Andrzej P. Trzciński, K. Szkoda, M. Karczewski, J. Gazda, M. Lisowska-Oleksiak, A. |
| description | •BiVO4 embedded and BiVO4 not embedded in carbonaceous matrix is obtained.•Crystallographic structure is the same pattern for both materials.•The presence of carbon phase stabilizes electrochemical properties of an electrode.•BiVO4 is electrochemical active towards reversible lithium intercalation.
Lithium-ion batteries (LIBs) are widely used all over the world. The LIBs belong to a renewable energy source and energy storage devices. The increase in energy demand causes that new materials of higher energy and higher power densities are still under investigation. Herein, we compare electrochemical properties of bismuth vanadate (BiVO4) embedded and not embedded into carbonaceous matrix as an anode material along with structural changes. Material incorporated into carbon phase (BiVO4@C) exhibited much better electrochemical stability but with lower specific capacity (128 mA h/g) in comparison with pure BiVO4 (217 mA h/g). XRD measurements showed the change in crystallographic structure due to lithium ion intercalation/extraction process. Hence, it seemed obvious that the presence of carbon affected the interfacial structural and electrochemical properties of bismuth vanadate based electrodes. |
| doi_str_mv | 10.1016/j.synthmet.2019.116168 |
| format | Article |
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Lithium-ion batteries (LIBs) are widely used all over the world. The LIBs belong to a renewable energy source and energy storage devices. The increase in energy demand causes that new materials of higher energy and higher power densities are still under investigation. Herein, we compare electrochemical properties of bismuth vanadate (BiVO4) embedded and not embedded into carbonaceous matrix as an anode material along with structural changes. Material incorporated into carbon phase (BiVO4@C) exhibited much better electrochemical stability but with lower specific capacity (128 mA h/g) in comparison with pure BiVO4 (217 mA h/g). XRD measurements showed the change in crystallographic structure due to lithium ion intercalation/extraction process. Hence, it seemed obvious that the presence of carbon affected the interfacial structural and electrochemical properties of bismuth vanadate based electrodes.</description><identifier>ISSN: 0379-6779</identifier><identifier>EISSN: 1879-3290</identifier><identifier>DOI: 10.1016/j.synthmet.2019.116168</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Anodes ; Bismuth oxides ; Carbon ; Crystal structure ; Crystallography ; Electrochemical analysis ; Electrode materials ; Electrodes ; Energy storage ; Lithium ; Lithium-ion batteries ; Negative electrode, Lithium-ion battery, Bismuth vanadate, Carbonaceus matrix ; Rechargeable batteries ; Vanadates</subject><ispartof>Synthetic metals, 2019-11, Vol.257, p.116168, Article 116168</ispartof><rights>2019 The Authors</rights><rights>Copyright Elsevier BV Nov 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c425t-bd2531a4fc8a86876c5e18eeab28da1413957ca30c750e42ecbf49dc293c8e823</citedby><cites>FETCH-LOGICAL-c425t-bd2531a4fc8a86876c5e18eeab28da1413957ca30c750e42ecbf49dc293c8e823</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.synthmet.2019.116168$$EHTML$$P50$$Gelsevier$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Nowak, Andrzej P.</creatorcontrib><creatorcontrib>Trzciński, K.</creatorcontrib><creatorcontrib>Szkoda, M.</creatorcontrib><creatorcontrib>Karczewski, J.</creatorcontrib><creatorcontrib>Gazda, M.</creatorcontrib><creatorcontrib>Lisowska-Oleksiak, A.</creatorcontrib><title>A negative effect of carbon phase on specific capacity of electrode material consisted of nanosized bismuth vanadate embedded in carbonaceous matrix</title><title>Synthetic metals</title><description>•BiVO4 embedded and BiVO4 not embedded in carbonaceous matrix is obtained.•Crystallographic structure is the same pattern for both materials.•The presence of carbon phase stabilizes electrochemical properties of an electrode.•BiVO4 is electrochemical active towards reversible lithium intercalation.
Lithium-ion batteries (LIBs) are widely used all over the world. The LIBs belong to a renewable energy source and energy storage devices. The increase in energy demand causes that new materials of higher energy and higher power densities are still under investigation. Herein, we compare electrochemical properties of bismuth vanadate (BiVO4) embedded and not embedded into carbonaceous matrix as an anode material along with structural changes. Material incorporated into carbon phase (BiVO4@C) exhibited much better electrochemical stability but with lower specific capacity (128 mA h/g) in comparison with pure BiVO4 (217 mA h/g). XRD measurements showed the change in crystallographic structure due to lithium ion intercalation/extraction process. Hence, it seemed obvious that the presence of carbon affected the interfacial structural and electrochemical properties of bismuth vanadate based electrodes.</description><subject>Anodes</subject><subject>Bismuth oxides</subject><subject>Carbon</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Electrochemical analysis</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Energy storage</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Negative electrode, Lithium-ion battery, Bismuth vanadate, Carbonaceus matrix</subject><subject>Rechargeable batteries</subject><subject>Vanadates</subject><issn>0379-6779</issn><issn>1879-3290</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkc9qGzEQxkVJoU7aVyiCnu1K2n_aW0No0kAgl-QsZkeztYxX2kqyqfMcfeBqcXLOSSO-33zDzMfYVyk2Usj2-26TTj5vJ8obJWS_kbKVrf7AVlJ3_bpSvbhgK1GVuu26_hO7TGknRCFVs2L_rrmn35DdkTiNI2HmYeQIcQiez1tIxEuRZkI3OizCDOjyaYFoX-gYLPEJMkUHe47BJ5cy2UX34ENyL-UzuDQd8pYfwYMtLKdpIGuL4vzrLEAKh7Q4Rff3M_s4wj7Rl9f3ij3f_ny6-bV-eLy7v7l-WGOtmrwerGoqCfWIGnSruxYbkpoIBqUtyFpWfdMhVAK7RlCtCIex7i2qvkJNWlVX7NvZd47hz4FSNrtwiL6MNKpqysnqXixUe6YwhpQijWaOboJ4MlKYJQGzM28JmCUBc06gNP44N1LZ4egomoSOPJJ1sZzO2ODes_gPLAuWjA</recordid><startdate>20191101</startdate><enddate>20191101</enddate><creator>Nowak, Andrzej P.</creator><creator>Trzciński, K.</creator><creator>Szkoda, M.</creator><creator>Karczewski, J.</creator><creator>Gazda, M.</creator><creator>Lisowska-Oleksiak, A.</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20191101</creationdate><title>A negative effect of carbon phase on specific capacity of electrode material consisted of nanosized bismuth vanadate embedded in carbonaceous matrix</title><author>Nowak, Andrzej P. ; Trzciński, K. ; Szkoda, M. ; Karczewski, J. ; Gazda, M. ; Lisowska-Oleksiak, A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c425t-bd2531a4fc8a86876c5e18eeab28da1413957ca30c750e42ecbf49dc293c8e823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Anodes</topic><topic>Bismuth oxides</topic><topic>Carbon</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Electrochemical analysis</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Energy storage</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Negative electrode, Lithium-ion battery, Bismuth vanadate, Carbonaceus matrix</topic><topic>Rechargeable batteries</topic><topic>Vanadates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nowak, Andrzej P.</creatorcontrib><creatorcontrib>Trzciński, K.</creatorcontrib><creatorcontrib>Szkoda, M.</creatorcontrib><creatorcontrib>Karczewski, J.</creatorcontrib><creatorcontrib>Gazda, M.</creatorcontrib><creatorcontrib>Lisowska-Oleksiak, A.</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Synthetic metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nowak, Andrzej P.</au><au>Trzciński, K.</au><au>Szkoda, M.</au><au>Karczewski, J.</au><au>Gazda, M.</au><au>Lisowska-Oleksiak, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A negative effect of carbon phase on specific capacity of electrode material consisted of nanosized bismuth vanadate embedded in carbonaceous matrix</atitle><jtitle>Synthetic metals</jtitle><date>2019-11-01</date><risdate>2019</risdate><volume>257</volume><spage>116168</spage><pages>116168-</pages><artnum>116168</artnum><issn>0379-6779</issn><eissn>1879-3290</eissn><abstract>•BiVO4 embedded and BiVO4 not embedded in carbonaceous matrix is obtained.•Crystallographic structure is the same pattern for both materials.•The presence of carbon phase stabilizes electrochemical properties of an electrode.•BiVO4 is electrochemical active towards reversible lithium intercalation.
Lithium-ion batteries (LIBs) are widely used all over the world. The LIBs belong to a renewable energy source and energy storage devices. The increase in energy demand causes that new materials of higher energy and higher power densities are still under investigation. Herein, we compare electrochemical properties of bismuth vanadate (BiVO4) embedded and not embedded into carbonaceous matrix as an anode material along with structural changes. Material incorporated into carbon phase (BiVO4@C) exhibited much better electrochemical stability but with lower specific capacity (128 mA h/g) in comparison with pure BiVO4 (217 mA h/g). XRD measurements showed the change in crystallographic structure due to lithium ion intercalation/extraction process. Hence, it seemed obvious that the presence of carbon affected the interfacial structural and electrochemical properties of bismuth vanadate based electrodes.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.synthmet.2019.116168</doi><oa>free_for_read</oa></addata></record> |
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| subjects | Anodes Bismuth oxides Carbon Crystal structure Crystallography Electrochemical analysis Electrode materials Electrodes Energy storage Lithium Lithium-ion batteries Negative electrode, Lithium-ion battery, Bismuth vanadate, Carbonaceus matrix Rechargeable batteries Vanadates |
| title | A negative effect of carbon phase on specific capacity of electrode material consisted of nanosized bismuth vanadate embedded in carbonaceous matrix |
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