Initiators for Radical Cation-induced [2 + 2]- and [4 + 2]-Cycloadditions of Electron-rich Alkenes

The radical cation-induced [2 + 2]- and [4 + 2]-cycloadditions of electron-rich alkenes afford cyclobutanes and cyclohexenes, which are used in the synthesis of natural products. The key intermediate is the alkene radical cation, which is generated from alkene by a one-electron oxidant. These cycloa...

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Veröffentlicht in:	Chemistry letters 2020-01, Vol.49 (1), p.107-113
Hauptverfasser:	Horibe, Takahiro, Ishihara, Kazuaki
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Apexes Assembly Cages Cations Electrons Graph theory Hydrogen bonding Initiators Metal-organic frameworks Natural products Organic chemistry Oxidizing agents
Online-Zugang:	Volltext
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