A Specific Fluorescent Probe for Antimony Based on Aggregation Induced Emission

In order to find a simple way to detect SbIII in wastewater, TPE‐2IPH, a fluorogen with high physical and chemical stability was simply designed and prepared by the classical one‐step Schiff base reaction. The aggregation induced emission (AIE) property of TPE‐2IPH was tested in the mixture of THF a...

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2020-01, Vol.646 (2), p.47-52
Hauptverfasser: Huang, Yuansong, Lin, Junxiong, Wang, Lili, Cao, Zhihai, Wang, Yijia, Wu, Minghua
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container_issue 2
container_start_page 47
container_title Zeitschrift für anorganische und allgemeine Chemie (1950)
container_volume 646
creator Huang, Yuansong
Lin, Junxiong
Wang, Lili
Cao, Zhihai
Wang, Yijia
Wu, Minghua
description In order to find a simple way to detect SbIII in wastewater, TPE‐2IPH, a fluorogen with high physical and chemical stability was simply designed and prepared by the classical one‐step Schiff base reaction. The aggregation induced emission (AIE) property of TPE‐2IPH was tested in the mixture of THF and water as well as its fluorescent response to antimony. It could be found that TPE‐2IPH presented typical AIE property and its emission was greatly boosted with the addition of antimony when the water fraction was 90 %, which indicated that TPE‐2IPH was a perfect fluorescent probe for antimony. The mechanism was supposed to be the coordinate of antimony and the IPH functional groups in TPE‐2IPH under aggregate state. Moreover, TPE‐2IPH could distinguish antimony with other cations well, implying that it was a potential indicator for antimony with high selectivity and specificity.
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subjects Agglomeration
Aggregation induced emission
Antimony
Antimony detection
Coordination
Emission analysis
Fluorescent indicators
Functional groups
Imines
Organic chemistry
Selectivity
Specificity
Wastewater
title A Specific Fluorescent Probe for Antimony Based on Aggregation Induced Emission
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