Column Separation of Vanadium(V) from Complex Sulfuric Solution Using Trialkylamine-Impregnated Resins
Separation of V(V) from simulated complex vanadium-bearing (SCV) solution containing Al(III), Fe(III), P(V), and Si(IV) using trialkylamine (N235)-impregnated resins has been investigated. Batch experiments proved that the optimal pH for adsorption and separation of V(V) from impurities was 1.8. Col...
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| Veröffentlicht in: | JOM (1989) 2020-02, Vol.72 (2), p.953-961 |
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| creator | Chen, Bo Bao, Shenxu Zhang, Yimin |
| description | Separation of V(V) from simulated complex vanadium-bearing (SCV) solution containing Al(III), Fe(III), P(V), and Si(IV) using trialkylamine (N235)-impregnated resins has been investigated. Batch experiments proved that the optimal pH for adsorption and separation of V(V) from impurities was 1.8. Column experiments showed that V(V) was well adsorbed and separated from the impurities under conditions of flow rate of 1.0 mL min
−1
and bed height of 12 cm. Most of the impurities that adsorbed on the N235-impregnated resin were effectively eluted with only 2.92% loss of V(V) using 12 bed volumes (BV) of 2 wt.% Na
2
SO
4
. Afterwards, V(V) was concentrated about 3.4 times and most of it was recovered using cycle desorption with 1 BV of 14 wt.% Na
2
CO
3
. The concentration of the impurities in the initial feed solution was greatly decreased using the present method, implying that V(V) can be effectively separated from SCV solution by such column operations. |
| doi_str_mv | 10.1007/s11837-019-03944-4 |
| format | Article |
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−1
and bed height of 12 cm. Most of the impurities that adsorbed on the N235-impregnated resin were effectively eluted with only 2.92% loss of V(V) using 12 bed volumes (BV) of 2 wt.% Na
2
SO
4
. Afterwards, V(V) was concentrated about 3.4 times and most of it was recovered using cycle desorption with 1 BV of 14 wt.% Na
2
CO
3
. The concentration of the impurities in the initial feed solution was greatly decreased using the present method, implying that V(V) can be effectively separated from SCV solution by such column operations.</description><identifier>ISSN: 1047-4838</identifier><identifier>EISSN: 1543-1851</identifier><identifier>DOI: 10.1007/s11837-019-03944-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Aluminum ; Aqueous solutions ; Chemistry/Food Science ; Computer simulation ; Earth Sciences ; Effluents ; Electron microscopes ; Energy consumption ; Engineering ; Environment ; Experiments ; Flow velocity ; Impurities ; Iron ; Metals ; Physics ; Polymers ; Resins ; Separation ; Silicon ; Sodium carbonate ; Sodium sulfate ; Solvent extraction processes ; Sulfur ; Technical Article ; Vanadium</subject><ispartof>JOM (1989), 2020-02, Vol.72 (2), p.953-961</ispartof><rights>The Minerals, Metals & Materials Society 2019</rights><rights>Copyright Springer Nature B.V. Feb 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-825182ff15f7f6f64e6abe5ddbad3f7cb75204ec5d74e4930dec69b3b44c7bed3</citedby><cites>FETCH-LOGICAL-c356t-825182ff15f7f6f64e6abe5ddbad3f7cb75204ec5d74e4930dec69b3b44c7bed3</cites><orcidid>0000-0003-1295-3389</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11837-019-03944-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11837-019-03944-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Chen, Bo</creatorcontrib><creatorcontrib>Bao, Shenxu</creatorcontrib><creatorcontrib>Zhang, Yimin</creatorcontrib><title>Column Separation of Vanadium(V) from Complex Sulfuric Solution Using Trialkylamine-Impregnated Resins</title><title>JOM (1989)</title><addtitle>JOM</addtitle><description>Separation of V(V) from simulated complex vanadium-bearing (SCV) solution containing Al(III), Fe(III), P(V), and Si(IV) using trialkylamine (N235)-impregnated resins has been investigated. Batch experiments proved that the optimal pH for adsorption and separation of V(V) from impurities was 1.8. Column experiments showed that V(V) was well adsorbed and separated from the impurities under conditions of flow rate of 1.0 mL min
−1
and bed height of 12 cm. Most of the impurities that adsorbed on the N235-impregnated resin were effectively eluted with only 2.92% loss of V(V) using 12 bed volumes (BV) of 2 wt.% Na
2
SO
4
. Afterwards, V(V) was concentrated about 3.4 times and most of it was recovered using cycle desorption with 1 BV of 14 wt.% Na
2
CO
3
. The concentration of the impurities in the initial feed solution was greatly decreased using the present method, implying that V(V) can be effectively separated from SCV solution by such column operations.</description><subject>Adsorption</subject><subject>Aluminum</subject><subject>Aqueous solutions</subject><subject>Chemistry/Food Science</subject><subject>Computer simulation</subject><subject>Earth Sciences</subject><subject>Effluents</subject><subject>Electron microscopes</subject><subject>Energy consumption</subject><subject>Engineering</subject><subject>Environment</subject><subject>Experiments</subject><subject>Flow velocity</subject><subject>Impurities</subject><subject>Iron</subject><subject>Metals</subject><subject>Physics</subject><subject>Polymers</subject><subject>Resins</subject><subject>Separation</subject><subject>Silicon</subject><subject>Sodium carbonate</subject><subject>Sodium sulfate</subject><subject>Solvent extraction processes</subject><subject>Sulfur</subject><subject>Technical Article</subject><subject>Vanadium</subject><issn>1047-4838</issn><issn>1543-1851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kMtKxDAUQIMoOI7-gKuAG11EkyZp2qUUHwMDgvPYhrRJho5tWpMWnL83TgV3ru5dnHMvHACuCb4nGIuHQEhGBcIkR5jmjCF2AmaEM4pIxslp3DETiGU0OwcXIexxlFhOZsAWXTO2Dq5Mr7wa6s7BzsKtckrXY3u7vYPWdy0surZvzBdcjY0dfV3BVdSO9CbUbgfXvlbNx6FRbe0MWrS9NzunBqPhu4lAuARnVjXBXP3OOdg8P62LV7R8e1kUj0tUUZ4OKEs4yRJrCbfCpjZlJlWl4VqXSlMrqlLwBDNTcS2YYTnF2lRpXtKSsUqURtM5uJnu9r77HE0Y5L4bvYsvZUJZKpIEZyJSyURVvgvBGyt7X7fKHyTB8qennHrK2FMee0oWJTpJIcJuZ_zf6X-sb8sLemg</recordid><startdate>20200201</startdate><enddate>20200201</enddate><creator>Chen, Bo</creator><creator>Bao, Shenxu</creator><creator>Zhang, Yimin</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>4T-</scope><scope>4U-</scope><scope>7SR</scope><scope>7TA</scope><scope>7WY</scope><scope>7XB</scope><scope>883</scope><scope>88I</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FRNLG</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>M0F</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>S0X</scope><orcidid>https://orcid.org/0000-0003-1295-3389</orcidid></search><sort><creationdate>20200201</creationdate><title>Column Separation of Vanadium(V) from Complex Sulfuric Solution Using Trialkylamine-Impregnated Resins</title><author>Chen, Bo ; Bao, Shenxu ; Zhang, Yimin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-825182ff15f7f6f64e6abe5ddbad3f7cb75204ec5d74e4930dec69b3b44c7bed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorption</topic><topic>Aluminum</topic><topic>Aqueous solutions</topic><topic>Chemistry/Food Science</topic><topic>Computer simulation</topic><topic>Earth Sciences</topic><topic>Effluents</topic><topic>Electron microscopes</topic><topic>Energy consumption</topic><topic>Engineering</topic><topic>Environment</topic><topic>Experiments</topic><topic>Flow velocity</topic><topic>Impurities</topic><topic>Iron</topic><topic>Metals</topic><topic>Physics</topic><topic>Polymers</topic><topic>Resins</topic><topic>Separation</topic><topic>Silicon</topic><topic>Sodium carbonate</topic><topic>Sodium sulfate</topic><topic>Solvent extraction processes</topic><topic>Sulfur</topic><topic>Technical Article</topic><topic>Vanadium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Bo</creatorcontrib><creatorcontrib>Bao, Shenxu</creatorcontrib><creatorcontrib>Zhang, Yimin</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>University Readers</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Access via ABI/INFORM (ProQuest)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Trade & Industry (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Business Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>Materials Science Database</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Trade & Industry</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>JOM (1989)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Bo</au><au>Bao, Shenxu</au><au>Zhang, Yimin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Column Separation of Vanadium(V) from Complex Sulfuric Solution Using Trialkylamine-Impregnated Resins</atitle><jtitle>JOM (1989)</jtitle><stitle>JOM</stitle><date>2020-02-01</date><risdate>2020</risdate><volume>72</volume><issue>2</issue><spage>953</spage><epage>961</epage><pages>953-961</pages><issn>1047-4838</issn><eissn>1543-1851</eissn><abstract>Separation of V(V) from simulated complex vanadium-bearing (SCV) solution containing Al(III), Fe(III), P(V), and Si(IV) using trialkylamine (N235)-impregnated resins has been investigated. Batch experiments proved that the optimal pH for adsorption and separation of V(V) from impurities was 1.8. Column experiments showed that V(V) was well adsorbed and separated from the impurities under conditions of flow rate of 1.0 mL min
−1
and bed height of 12 cm. Most of the impurities that adsorbed on the N235-impregnated resin were effectively eluted with only 2.92% loss of V(V) using 12 bed volumes (BV) of 2 wt.% Na
2
SO
4
. Afterwards, V(V) was concentrated about 3.4 times and most of it was recovered using cycle desorption with 1 BV of 14 wt.% Na
2
CO
3
. The concentration of the impurities in the initial feed solution was greatly decreased using the present method, implying that V(V) can be effectively separated from SCV solution by such column operations.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11837-019-03944-4</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-1295-3389</orcidid></addata></record> |
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| subjects | Adsorption Aluminum Aqueous solutions Chemistry/Food Science Computer simulation Earth Sciences Effluents Electron microscopes Energy consumption Engineering Environment Experiments Flow velocity Impurities Iron Metals Physics Polymers Resins Separation Silicon Sodium carbonate Sodium sulfate Solvent extraction processes Sulfur Technical Article Vanadium |
| title | Column Separation of Vanadium(V) from Complex Sulfuric Solution Using Trialkylamine-Impregnated Resins |
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