Preparation of fluorescent cellulose nanocrystal polymer composites with thermo-responsiveness through light-induced ATRP
In recent years, cellulose nanocrystal (CNC) based materials have attracted great research attention for different applications owing to their unique properties and facile modification chemistry. In this work, CNC based thermo-responsive fluorescent composites were successfully prepared via the meta...
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| Veröffentlicht in: | Cellulose (London) 2020, Vol.27 (2), p.743-753 |
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| container_title | Cellulose (London) |
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| creator | Chen, Junyu Mao, Liucheng Qi, Hongxu Xu, Dazhuang Huang, Hongye Liu, Meiying Wen, Yuanqing Deng, Fengjie Zhang, Xiaoyong Wei, Yen |
| description | In recent years, cellulose nanocrystal (CNC) based materials have attracted great research attention for different applications owing to their unique properties and facile modification chemistry. In this work, CNC based thermo-responsive fluorescent composites were successfully prepared via the metal-free surface-initiated atom transfer radical polymerization (ATRP) of NIPAAm and a Schiff base containing dye (HDPAP). Results demonstrated CNC-poly (NIPAAm–HDPAP) composites display sensitive temperature-responsive coil-to-globule transition behavior at the temperature of lower critical solution temperature. The bright fluorescence offered by the Schiff base dye (HDPAP) was also confirmed by fluorescence spectra. Moreover, the preparation method of light meditated ATRP was proved to become the promising way in fabrication of multifunctional nanomaterials for its incomparable advantages, including low energy consumption, high efficiency, good monomer adaptation, free of transition metal ions.
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| doi_str_mv | 10.1007/s10570-019-02845-8 |
| format | Article |
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Graphic abstract</description><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coils</subject><subject>Composites</subject><subject>Dyes</subject><subject>Energy consumption</subject><subject>Fluorescence</subject><subject>Free surfaces</subject><subject>Glass</subject><subject>Imines</subject><subject>Nanocrystals</subject><subject>Nanomaterials</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer matrix composites</subject><subject>Polymer Sciences</subject><subject>Sustainable Development</subject><subject>Transition metals</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kMtKAzEUhoMoWKsv4CrgOprLXJJlKd5AUKSCu5BmTtop02RMMkrf3qkV3Lk6cM7__Qc-hC4ZvWaU1jeJ0bKmhDJFKJdFSeQRmrCy5kRK_n6MJlRV-5NQp-gspQ2lVNWcTdDuJUJvoslt8Dg47LohREgWfMYWum7oQgLsjQ827lI2He5Dt9tCxDZs-5DaDAl_tXmN8xriNpAR7oNP7Sd4SGncxjCs1rhrV-tMWt8MFho8W7y-nKMTZ7oEF79zit7ubhfzB_L0fP84nz0RK8oqEzBL5ig0htclcKmclY2jTNSFslSVpilqKJkaJTC1rGq1tFZIWSjFuLNN5cQUXR16-xg-BkhZb8IQ_fhSc1EIoaqCszHFDykbQ0oRnO5juzVxpxnVe8X6oFiPivWPYi1HSBygNIb9CuJf9T_UN9Tjgms</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Chen, Junyu</creator><creator>Mao, Liucheng</creator><creator>Qi, Hongxu</creator><creator>Xu, Dazhuang</creator><creator>Huang, Hongye</creator><creator>Liu, Meiying</creator><creator>Wen, Yuanqing</creator><creator>Deng, Fengjie</creator><creator>Zhang, Xiaoyong</creator><creator>Wei, Yen</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0001-8843-875X</orcidid></search><sort><creationdate>2020</creationdate><title>Preparation of fluorescent cellulose nanocrystal polymer composites with thermo-responsiveness through light-induced ATRP</title><author>Chen, Junyu ; 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In this work, CNC based thermo-responsive fluorescent composites were successfully prepared via the metal-free surface-initiated atom transfer radical polymerization (ATRP) of NIPAAm and a Schiff base containing dye (HDPAP). Results demonstrated CNC-poly (NIPAAm–HDPAP) composites display sensitive temperature-responsive coil-to-globule transition behavior at the temperature of lower critical solution temperature. The bright fluorescence offered by the Schiff base dye (HDPAP) was also confirmed by fluorescence spectra. Moreover, the preparation method of light meditated ATRP was proved to become the promising way in fabrication of multifunctional nanomaterials for its incomparable advantages, including low energy consumption, high efficiency, good monomer adaptation, free of transition metal ions.
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| subjects | Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Coils Composites Dyes Energy consumption Fluorescence Free surfaces Glass Imines Nanocrystals Nanomaterials Natural Materials Organic Chemistry Original Research Physical Chemistry Polymer matrix composites Polymer Sciences Sustainable Development Transition metals |
| title | Preparation of fluorescent cellulose nanocrystal polymer composites with thermo-responsiveness through light-induced ATRP |
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