Preparation and properties of fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite film
Fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite [R F -(AMPS) n -R F /PVA] films were prepared by casting homogeneous aqueous methanol solutions containing R F -(AMPS) n -R F /PVA composites, which were prepared by the reactions of the correspon...
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| Veröffentlicht in: | JCT research 2020-01, Vol.17 (1), p.219-230 |
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| creator | Katayama, Shinsuke Yasuta, Masato Sawada, Hideo |
| description | Fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite [R
F
-(AMPS)
n
-R
F
/PVA] films were prepared by casting homogeneous aqueous methanol solutions containing R
F
-(AMPS)
n
-R
F
/PVA composites, which were prepared by the reactions of the corresponding oligomer with PVA. The transparent colorless R
F
-(AMPS)
n
-R
F
/PVA composite films thus obtained were subjected to tensile testing to evaluate the values of Young’s modulus, tensile strength, and elongation at break. The R
F
-(AMPS)
n
-R
F
/PVA composites films are capable of greater Young’s modulus than the original PVA film (PVA/HCl film), which was prepared by casting the aqueous methanol solution of PVA in the presence of 1 N hydrochloric acid. The polymer film bearing a higher Young’s modulus is, in general, tough and brittle to providing lower elongation at break; however, we can observe a significant increase in both the tensile strength and elongation at break of the R
F
-(AMPS)
n
-R
F
/PVA composite films, compared to those of the PVA/HCl film. In addition, it was demonstrated that the R
F
-(AMPS)
n
-R
F
/PVA composite films can exhibit a higher water adsorption ability than that of the PVA/HCl film.
Graphic abstract |
| doi_str_mv | 10.1007/s11998-019-00259-6 |
| format | Article |
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F
-(AMPS)
n
-R
F
/PVA] films were prepared by casting homogeneous aqueous methanol solutions containing R
F
-(AMPS)
n
-R
F
/PVA composites, which were prepared by the reactions of the corresponding oligomer with PVA. The transparent colorless R
F
-(AMPS)
n
-R
F
/PVA composite films thus obtained were subjected to tensile testing to evaluate the values of Young’s modulus, tensile strength, and elongation at break. The R
F
-(AMPS)
n
-R
F
/PVA composites films are capable of greater Young’s modulus than the original PVA film (PVA/HCl film), which was prepared by casting the aqueous methanol solution of PVA in the presence of 1 N hydrochloric acid. The polymer film bearing a higher Young’s modulus is, in general, tough and brittle to providing lower elongation at break; however, we can observe a significant increase in both the tensile strength and elongation at break of the R
F
-(AMPS)
n
-R
F
/PVA composite films, compared to those of the PVA/HCl film. In addition, it was demonstrated that the R
F
-(AMPS)
n
-R
F
/PVA composite films can exhibit a higher water adsorption ability than that of the PVA/HCl film.
Graphic abstract</description><identifier>ISSN: 1547-0091</identifier><identifier>EISSN: 1935-3804</identifier><identifier>EISSN: 2168-8028</identifier><identifier>DOI: 10.1007/s11998-019-00259-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorbed water ; Chemical industry ; Chemistry and Materials Science ; Composite materials ; Corrosion and Coatings ; Elongation ; Hydrochloric acid ; Industrial Chemistry/Chemical Engineering ; Materials Science ; Methanol ; Modulus of elasticity ; Polymer films ; Polymer Sciences ; Polyvinyl alcohol ; Surfaces and Interfaces ; Tensile strength ; Thin Films ; Tribology</subject><ispartof>JCT research, 2020-01, Vol.17 (1), p.219-230</ispartof><rights>American Coatings Association 2019</rights><rights>2019© American Coatings Association 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-741e24caedde50075b727fde9158f3e28cd6847b5c45cd83799d0f4f4eff3c373</citedby><cites>FETCH-LOGICAL-c385t-741e24caedde50075b727fde9158f3e28cd6847b5c45cd83799d0f4f4eff3c373</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11998-019-00259-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11998-019-00259-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Katayama, Shinsuke</creatorcontrib><creatorcontrib>Yasuta, Masato</creatorcontrib><creatorcontrib>Sawada, Hideo</creatorcontrib><title>Preparation and properties of fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite film</title><title>JCT research</title><addtitle>J Coat Technol Res</addtitle><description>Fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite [R
F
-(AMPS)
n
-R
F
/PVA] films were prepared by casting homogeneous aqueous methanol solutions containing R
F
-(AMPS)
n
-R
F
/PVA composites, which were prepared by the reactions of the corresponding oligomer with PVA. The transparent colorless R
F
-(AMPS)
n
-R
F
/PVA composite films thus obtained were subjected to tensile testing to evaluate the values of Young’s modulus, tensile strength, and elongation at break. The R
F
-(AMPS)
n
-R
F
/PVA composites films are capable of greater Young’s modulus than the original PVA film (PVA/HCl film), which was prepared by casting the aqueous methanol solution of PVA in the presence of 1 N hydrochloric acid. The polymer film bearing a higher Young’s modulus is, in general, tough and brittle to providing lower elongation at break; however, we can observe a significant increase in both the tensile strength and elongation at break of the R
F
-(AMPS)
n
-R
F
/PVA composite films, compared to those of the PVA/HCl film. In addition, it was demonstrated that the R
F
-(AMPS)
n
-R
F
/PVA composite films can exhibit a higher water adsorption ability than that of the PVA/HCl film.
Graphic abstract</description><subject>Adsorbed water</subject><subject>Chemical industry</subject><subject>Chemistry and Materials Science</subject><subject>Composite materials</subject><subject>Corrosion and Coatings</subject><subject>Elongation</subject><subject>Hydrochloric acid</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Materials Science</subject><subject>Methanol</subject><subject>Modulus of elasticity</subject><subject>Polymer films</subject><subject>Polymer Sciences</subject><subject>Polyvinyl alcohol</subject><subject>Surfaces and Interfaces</subject><subject>Tensile strength</subject><subject>Thin Films</subject><subject>Tribology</subject><issn>1547-0091</issn><issn>1935-3804</issn><issn>2168-8028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kL1OHTEQhVdRIoUQXoDKUhpSGPx7bZcIBYKEBAXUlrHHYOJdb-y9kfYVeGp8cyOlo5qR5jtnZs4wHFNySglRZ41SYzQm1GBCmDR482E4oIZLzDURH3svheojQz8PX1p76ZDSmh8Mr3cVZlfdksqE3BTQXMsMdUnQUIko5m2pxeVfa0YwBezdPENADDtf1-zGFApmeITlec07pZugbXMsU_LI-RRQyempjFDP5pLXkz9p6kYu-_Jc8nfkyziXlhZAMeXx6_Aputzg6F89HB4uf9xf_MQ3t1fXF-c32HMtF6wEBSa8gxBA9t_lo2IqBjBU6siBaR82WqhH6YX0QXNlTCBRRAExcs8VPxy-7X37wb-30Bb7UrZ16ist44IzLYTYUWxP-VpaqxDtXNPo6mopsbvM7T5z2zO3fzO3my7ie1Hr8PQE9b_1O6o3EoeIWg</recordid><startdate>20200101</startdate><enddate>20200101</enddate><creator>Katayama, Shinsuke</creator><creator>Yasuta, Masato</creator><creator>Sawada, Hideo</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200101</creationdate><title>Preparation and properties of fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite film</title><author>Katayama, Shinsuke ; Yasuta, Masato ; Sawada, Hideo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-741e24caedde50075b727fde9158f3e28cd6847b5c45cd83799d0f4f4eff3c373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorbed water</topic><topic>Chemical industry</topic><topic>Chemistry and Materials Science</topic><topic>Composite materials</topic><topic>Corrosion and Coatings</topic><topic>Elongation</topic><topic>Hydrochloric acid</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Materials Science</topic><topic>Methanol</topic><topic>Modulus of elasticity</topic><topic>Polymer films</topic><topic>Polymer Sciences</topic><topic>Polyvinyl alcohol</topic><topic>Surfaces and Interfaces</topic><topic>Tensile strength</topic><topic>Thin Films</topic><topic>Tribology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Katayama, Shinsuke</creatorcontrib><creatorcontrib>Yasuta, Masato</creatorcontrib><creatorcontrib>Sawada, Hideo</creatorcontrib><collection>CrossRef</collection><jtitle>JCT research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Katayama, Shinsuke</au><au>Yasuta, Masato</au><au>Sawada, Hideo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and properties of fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite film</atitle><jtitle>JCT research</jtitle><stitle>J Coat Technol Res</stitle><date>2020-01-01</date><risdate>2020</risdate><volume>17</volume><issue>1</issue><spage>219</spage><epage>230</epage><pages>219-230</pages><issn>1547-0091</issn><eissn>1935-3804</eissn><eissn>2168-8028</eissn><abstract>Fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite [R
F
-(AMPS)
n
-R
F
/PVA] films were prepared by casting homogeneous aqueous methanol solutions containing R
F
-(AMPS)
n
-R
F
/PVA composites, which were prepared by the reactions of the corresponding oligomer with PVA. The transparent colorless R
F
-(AMPS)
n
-R
F
/PVA composite films thus obtained were subjected to tensile testing to evaluate the values of Young’s modulus, tensile strength, and elongation at break. The R
F
-(AMPS)
n
-R
F
/PVA composites films are capable of greater Young’s modulus than the original PVA film (PVA/HCl film), which was prepared by casting the aqueous methanol solution of PVA in the presence of 1 N hydrochloric acid. The polymer film bearing a higher Young’s modulus is, in general, tough and brittle to providing lower elongation at break; however, we can observe a significant increase in both the tensile strength and elongation at break of the R
F
-(AMPS)
n
-R
F
/PVA composite films, compared to those of the PVA/HCl film. In addition, it was demonstrated that the R
F
-(AMPS)
n
-R
F
/PVA composite films can exhibit a higher water adsorption ability than that of the PVA/HCl film.
Graphic abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11998-019-00259-6</doi><tpages>12</tpages></addata></record> |
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| identifier | ISSN: 1547-0091 |
| ispartof | JCT research, 2020-01, Vol.17 (1), p.219-230 |
| issn | 1547-0091 1935-3804 2168-8028 |
| language | eng |
| recordid | cdi_proquest_journals_2343284447 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Adsorbed water Chemical industry Chemistry and Materials Science Composite materials Corrosion and Coatings Elongation Hydrochloric acid Industrial Chemistry/Chemical Engineering Materials Science Methanol Modulus of elasticity Polymer films Polymer Sciences Polyvinyl alcohol Surfaces and Interfaces Tensile strength Thin Films Tribology |
| title | Preparation and properties of fluoroalkyl end-capped 2-acrylamido-2-methylpropanesulfonic acid oligomer/poly(vinyl alcohol) composite film |
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