X-ray Photoelectron Spectroscopy of 1-Butyl-2,3-Dimethylimidazolium Ionic Liquids: Charge Correction Methods and Electronic Environment of the Anion
In this study, six 1-butyl-2,3-dimethylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable fitting model is developed for the C 1 s region. The charge correction method is discussed in detail. It suggests that the aliphatic carbon component can be used as an intern...
Gespeichert in:
| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2019-12, Vol.93 (13), p.2676-2680 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2680 |
|---|---|
| container_issue | 13 |
| container_start_page | 2676 |
| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 93 |
| creator | Li, Wei Men, Shuang |
| description | In this study, six 1-butyl-2,3-dimethylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable fitting model is developed for the C 1
s
region. The charge correction method is discussed in detail. It suggests that the aliphatic carbon component can be used as an internal reference only if the Kamlet-Taft hydrogen bond acceptor ability value is larger than 0.57. The electronic environment of each anion-based component is compared to that of 1-butyl-3-methylimidazolium ionic liquids. It is found that noticeable binding energy shift can be observed in the spectra of S 2
p
for [TfO]
–
and P 2
p
for [PF
6
]
–
. |
| doi_str_mv | 10.1134/S0036024419130326 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2343277752</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2343277752</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-ab6904a68ef4cfcba083937b01f1c51fa3ad5b299abe76b9b8bc91b5546c5dbe3</originalsourceid><addsrcrecordid>eNp1kN9KwzAYxYMoOKcP4F3AW6NJk_7zbs6pg4nCFHZXkjRdM9pmJq1Qn8MHNnUDL8Sr78D3O-fAAeCc4CtCKLteYkwjHDBGUkIxDaIDMCIhJSiJ6OoQjIY3Gv7H4MS5DcbMo2wEvlbI8h6-lKY1qlKytaaBy-2PcNJse2gKSNBt1_YVCi4putO1asu-0rXO-aepdFfDuWm0hAv93unc3cBpye1awamx1udoH_jkLSZ3kDc5nO1bvGPWfGivatW0Q01bKjhpPH8KjgpeOXW2v2Pwdj97nT6ixfPDfDpZIElJ1CIuohQzHiWqYLKQguOEpjQWmBREhqTglOehCNKUCxVHIhWJkCkRYcgiGeZC0TG42OVurXnvlGuzjels4yuzgDIaxHEcBp4iO0r6SZxVRba1uua2zwjOhvGzP-N7T7DzOM82a2V_k_83fQONaYir</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2343277752</pqid></control><display><type>article</type><title>X-ray Photoelectron Spectroscopy of 1-Butyl-2,3-Dimethylimidazolium Ionic Liquids: Charge Correction Methods and Electronic Environment of the Anion</title><source>SpringerLink Journals - AutoHoldings</source><creator>Li, Wei ; Men, Shuang</creator><creatorcontrib>Li, Wei ; Men, Shuang</creatorcontrib><description>In this study, six 1-butyl-2,3-dimethylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable fitting model is developed for the C 1
s
region. The charge correction method is discussed in detail. It suggests that the aliphatic carbon component can be used as an internal reference only if the Kamlet-Taft hydrogen bond acceptor ability value is larger than 0.57. The electronic environment of each anion-based component is compared to that of 1-butyl-3-methylimidazolium ionic liquids. It is found that noticeable binding energy shift can be observed in the spectra of S 2
p
for [TfO]
–
and P 2
p
for [PF
6
]
–
.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024419130326</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aliphatic compounds ; Anions ; Chemistry ; Chemistry and Materials Science ; Hydrogen bonds ; Ionic liquids ; Ions ; Photoelectron spectroscopy ; Photoelectrons ; Physical Chemistry ; Physical Chemistry of Solutions ; Solvents ; Spectrum analysis ; X ray photoelectron spectroscopy</subject><ispartof>Russian Journal of Physical Chemistry A, 2019-12, Vol.93 (13), p.2676-2680</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>2019© Pleiades Publishing, Ltd. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-ab6904a68ef4cfcba083937b01f1c51fa3ad5b299abe76b9b8bc91b5546c5dbe3</citedby><cites>FETCH-LOGICAL-c316t-ab6904a68ef4cfcba083937b01f1c51fa3ad5b299abe76b9b8bc91b5546c5dbe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024419130326$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024419130326$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Li, Wei</creatorcontrib><creatorcontrib>Men, Shuang</creatorcontrib><title>X-ray Photoelectron Spectroscopy of 1-Butyl-2,3-Dimethylimidazolium Ionic Liquids: Charge Correction Methods and Electronic Environment of the Anion</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>In this study, six 1-butyl-2,3-dimethylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable fitting model is developed for the C 1
s
region. The charge correction method is discussed in detail. It suggests that the aliphatic carbon component can be used as an internal reference only if the Kamlet-Taft hydrogen bond acceptor ability value is larger than 0.57. The electronic environment of each anion-based component is compared to that of 1-butyl-3-methylimidazolium ionic liquids. It is found that noticeable binding energy shift can be observed in the spectra of S 2
p
for [TfO]
–
and P 2
p
for [PF
6
]
–
.</description><subject>Aliphatic compounds</subject><subject>Anions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Hydrogen bonds</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Photoelectron spectroscopy</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Physical Chemistry of Solutions</subject><subject>Solvents</subject><subject>Spectrum analysis</subject><subject>X ray photoelectron spectroscopy</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kN9KwzAYxYMoOKcP4F3AW6NJk_7zbs6pg4nCFHZXkjRdM9pmJq1Qn8MHNnUDL8Sr78D3O-fAAeCc4CtCKLteYkwjHDBGUkIxDaIDMCIhJSiJ6OoQjIY3Gv7H4MS5DcbMo2wEvlbI8h6-lKY1qlKytaaBy-2PcNJse2gKSNBt1_YVCi4putO1asu-0rXO-aepdFfDuWm0hAv93unc3cBpye1awamx1udoH_jkLSZ3kDc5nO1bvGPWfGivatW0Q01bKjhpPH8KjgpeOXW2v2Pwdj97nT6ixfPDfDpZIElJ1CIuohQzHiWqYLKQguOEpjQWmBREhqTglOehCNKUCxVHIhWJkCkRYcgiGeZC0TG42OVurXnvlGuzjels4yuzgDIaxHEcBp4iO0r6SZxVRba1uua2zwjOhvGzP-N7T7DzOM82a2V_k_83fQONaYir</recordid><startdate>20191201</startdate><enddate>20191201</enddate><creator>Li, Wei</creator><creator>Men, Shuang</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20191201</creationdate><title>X-ray Photoelectron Spectroscopy of 1-Butyl-2,3-Dimethylimidazolium Ionic Liquids: Charge Correction Methods and Electronic Environment of the Anion</title><author>Li, Wei ; Men, Shuang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-ab6904a68ef4cfcba083937b01f1c51fa3ad5b299abe76b9b8bc91b5546c5dbe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aliphatic compounds</topic><topic>Anions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Hydrogen bonds</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Photoelectron spectroscopy</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Physical Chemistry of Solutions</topic><topic>Solvents</topic><topic>Spectrum analysis</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Wei</creatorcontrib><creatorcontrib>Men, Shuang</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Wei</au><au>Men, Shuang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>X-ray Photoelectron Spectroscopy of 1-Butyl-2,3-Dimethylimidazolium Ionic Liquids: Charge Correction Methods and Electronic Environment of the Anion</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2019-12-01</date><risdate>2019</risdate><volume>93</volume><issue>13</issue><spage>2676</spage><epage>2680</epage><pages>2676-2680</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>In this study, six 1-butyl-2,3-dimethylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable fitting model is developed for the C 1
s
region. The charge correction method is discussed in detail. It suggests that the aliphatic carbon component can be used as an internal reference only if the Kamlet-Taft hydrogen bond acceptor ability value is larger than 0.57. The electronic environment of each anion-based component is compared to that of 1-butyl-3-methylimidazolium ionic liquids. It is found that noticeable binding energy shift can be observed in the spectra of S 2
p
for [TfO]
–
and P 2
p
for [PF
6
]
–
.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024419130326</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0244 |
| ispartof | Russian Journal of Physical Chemistry A, 2019-12, Vol.93 (13), p.2676-2680 |
| issn | 0036-0244 1531-863X |
| language | eng |
| recordid | cdi_proquest_journals_2343277752 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Aliphatic compounds Anions Chemistry Chemistry and Materials Science Hydrogen bonds Ionic liquids Ions Photoelectron spectroscopy Photoelectrons Physical Chemistry Physical Chemistry of Solutions Solvents Spectrum analysis X ray photoelectron spectroscopy |
| title | X-ray Photoelectron Spectroscopy of 1-Butyl-2,3-Dimethylimidazolium Ionic Liquids: Charge Correction Methods and Electronic Environment of the Anion |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-17T01%3A57%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=X-ray%20Photoelectron%20Spectroscopy%20of%201-Butyl-2,3-Dimethylimidazolium%20Ionic%20Liquids:%20Charge%20Correction%20Methods%20and%20Electronic%20Environment%20of%20the%20Anion&rft.jtitle=Russian%20Journal%20of%20Physical%20Chemistry%20A&rft.au=Li,%20Wei&rft.date=2019-12-01&rft.volume=93&rft.issue=13&rft.spage=2676&rft.epage=2680&rft.pages=2676-2680&rft.issn=0036-0244&rft.eissn=1531-863X&rft_id=info:doi/10.1134/S0036024419130326&rft_dat=%3Cproquest_cross%3E2343277752%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2343277752&rft_id=info:pmid/&rfr_iscdi=true |