Failure of Pump–Compressor Pipes in Highly Aggressive Oil-Field Media
The mechanisms and kinetics of the corrosion-mechanical failure of pump–compressor pipes made of a chromium–molybdenum 15Kh5MFBCh steel in oil-field media with high CO 2 and H 2 S contents and bacterial contamination are studied. The carbon dioxide corrosion resistance of the 15Kh5MFBCh steel is sho...
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Veröffentlicht in: | Russian metallurgy Metally 2019-10, Vol.2019 (10), p.1067-1073 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | The mechanisms and kinetics of the corrosion-mechanical failure of pump–compressor pipes made of a chromium–molybdenum 15Kh5MFBCh steel in oil-field media with high CO
2
and H
2
S contents and bacterial contamination are studied. The carbon dioxide corrosion resistance of the 15Kh5MFBCh steel is shown to be an order of magnitude higher than that of traditionally used manganese 35G2S-type steels. A passivating film, which mainly consists of chromium oxides, forms at the metal–corrosion product interface in CO
2
-saturated media, and iron sulfide layers additionally form in the media saturated by CO
2
and H
2
S. These layers break the protective film and degrade the corrosion resistance of the steel. |
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ISSN: | 0036-0295 1555-6255 1531-8648 |
DOI: | 10.1134/S0036029519100331 |