Chemically induced transformation of chemical vapour deposition grown bilayer graphene into fluorinated single-layer diamond
Notwithstanding the numerous density functional studies on the chemically induced transformation of multilayer graphene into a diamond-like film carried out to date, a comprehensive convincing experimental proof of such a conversion is still lacking. We show that the fluorination of graphene sheets...
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| Veröffentlicht in: | Nature nanotechnology 2020-01, Vol.15 (1), p.59-66 |
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| creator | Bakharev, Pavel V. Huang, Ming Saxena, Manav Lee, Suk Woo Joo, Se Hun Park, Sung O Dong, Jichen Camacho-Mojica, Dulce C. Jin, Sunghwan Kwon, Youngwoo Biswal, Mandakini Ding, Feng Kwak, Sang Kyu Lee, Zonghoon Ruoff, Rodney S. |
| description | Notwithstanding the numerous density functional studies on the chemically induced transformation of multilayer graphene into a diamond-like film carried out to date, a comprehensive convincing experimental proof of such a conversion is still lacking. We show that the fluorination of graphene sheets in Bernal (AB)-stacked bilayer graphene grown by chemical vapour deposition on a single-crystal CuNi(111) surface triggers the formation of interlayer carbon–carbon bonds, resulting in a fluorinated diamond monolayer (‘F-diamane’). Induced by fluorine chemisorption, the phase transition from (AB)-stacked bilayer graphene to single-layer diamond was studied and verified by X-ray photoelectron, UV photoelectron, Raman, UV-Vis and electron energy loss spectroscopies, transmission electron microscopy and density functional theory calculations.
The fluorination of graphene sheets in bilayer graphene grown by chemical vapour deposition on a single-crystal CuNi(111) surface results in a fluorinated diamond monolayer. |
| doi_str_mv | 10.1038/s41565-019-0582-z |
| format | Article |
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The fluorination of graphene sheets in bilayer graphene grown by chemical vapour deposition on a single-crystal CuNi(111) surface results in a fluorinated diamond monolayer.</description><identifier>ISSN: 1748-3387</identifier><identifier>EISSN: 1748-3395</identifier><identifier>DOI: 10.1038/s41565-019-0582-z</identifier><identifier>PMID: 31819243</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>119/118 ; 140/133 ; 140/146 ; 639/301/357/1018 ; 639/301/357/918 ; Bilayers ; Carbon ; Chemical vapor deposition ; Chemisorption ; Chemistry and Materials Science ; Covalent bonds ; Density functional theory ; Diamond films ; Diamonds ; Electron energy loss spectroscopy ; Energy dissipation ; Energy loss ; Fluorination ; Fluorine ; Graphene ; Interlayers ; Materials Science ; Materials Science, Multidisciplinary ; Monolayers ; Multilayers ; Nanoscience & Nanotechnology ; Nanotechnology ; Nanotechnology and Microengineering ; Organic chemistry ; Phase transitions ; Photoelectrons ; Science & Technology ; Science & Technology - Other Topics ; Sheets ; Single crystals ; Technology ; Transmission electron microscopy</subject><ispartof>Nature nanotechnology, 2020-01, Vol.15 (1), p.59-66</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Limited 2019</rights><rights>2019© The Author(s), under exclusive licence to Springer Nature Limited 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>211</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000510815600009</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c372t-96f2c7270a8ed365c2be695ab68592e97c375e0e86060fac8d783343377e8fe93</citedby><cites>FETCH-LOGICAL-c372t-96f2c7270a8ed365c2be695ab68592e97c375e0e86060fac8d783343377e8fe93</cites><orcidid>0000-0001-7458-6823 ; 0000-0002-0332-1534 ; 0000-0003-3246-4072 ; 0000-0002-6599-6764 ; 0000-0001-9153-9279 ; 0000-0003-2160-2281 ; 0000-0003-4636-3942 ; 0000-0003-4507-150X ; 0000-0002-9188-4619</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27931,27932,28255</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31819243$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bakharev, Pavel V.</creatorcontrib><creatorcontrib>Huang, Ming</creatorcontrib><creatorcontrib>Saxena, Manav</creatorcontrib><creatorcontrib>Lee, Suk Woo</creatorcontrib><creatorcontrib>Joo, Se Hun</creatorcontrib><creatorcontrib>Park, Sung O</creatorcontrib><creatorcontrib>Dong, Jichen</creatorcontrib><creatorcontrib>Camacho-Mojica, Dulce C.</creatorcontrib><creatorcontrib>Jin, Sunghwan</creatorcontrib><creatorcontrib>Kwon, Youngwoo</creatorcontrib><creatorcontrib>Biswal, Mandakini</creatorcontrib><creatorcontrib>Ding, Feng</creatorcontrib><creatorcontrib>Kwak, Sang Kyu</creatorcontrib><creatorcontrib>Lee, Zonghoon</creatorcontrib><creatorcontrib>Ruoff, Rodney S.</creatorcontrib><title>Chemically induced transformation of chemical vapour deposition grown bilayer graphene into fluorinated single-layer diamond</title><title>Nature nanotechnology</title><addtitle>Nat. Nanotechnol</addtitle><addtitle>NAT NANOTECHNOL</addtitle><addtitle>Nat Nanotechnol</addtitle><description>Notwithstanding the numerous density functional studies on the chemically induced transformation of multilayer graphene into a diamond-like film carried out to date, a comprehensive convincing experimental proof of such a conversion is still lacking. We show that the fluorination of graphene sheets in Bernal (AB)-stacked bilayer graphene grown by chemical vapour deposition on a single-crystal CuNi(111) surface triggers the formation of interlayer carbon–carbon bonds, resulting in a fluorinated diamond monolayer (‘F-diamane’). Induced by fluorine chemisorption, the phase transition from (AB)-stacked bilayer graphene to single-layer diamond was studied and verified by X-ray photoelectron, UV photoelectron, Raman, UV-Vis and electron energy loss spectroscopies, transmission electron microscopy and density functional theory calculations.
The fluorination of graphene sheets in bilayer graphene grown by chemical vapour deposition on a single-crystal CuNi(111) surface results in a fluorinated diamond monolayer.</description><subject>119/118</subject><subject>140/133</subject><subject>140/146</subject><subject>639/301/357/1018</subject><subject>639/301/357/918</subject><subject>Bilayers</subject><subject>Carbon</subject><subject>Chemical vapor deposition</subject><subject>Chemisorption</subject><subject>Chemistry and Materials Science</subject><subject>Covalent bonds</subject><subject>Density functional theory</subject><subject>Diamond films</subject><subject>Diamonds</subject><subject>Electron energy loss spectroscopy</subject><subject>Energy dissipation</subject><subject>Energy loss</subject><subject>Fluorination</subject><subject>Fluorine</subject><subject>Graphene</subject><subject>Interlayers</subject><subject>Materials Science</subject><subject>Materials Science, 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Induced by fluorine chemisorption, the phase transition from (AB)-stacked bilayer graphene to single-layer diamond was studied and verified by X-ray photoelectron, UV photoelectron, Raman, UV-Vis and electron energy loss spectroscopies, transmission electron microscopy and density functional theory calculations.
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| subjects | 119/118 140/133 140/146 639/301/357/1018 639/301/357/918 Bilayers Carbon Chemical vapor deposition Chemisorption Chemistry and Materials Science Covalent bonds Density functional theory Diamond films Diamonds Electron energy loss spectroscopy Energy dissipation Energy loss Fluorination Fluorine Graphene Interlayers Materials Science Materials Science, Multidisciplinary Monolayers Multilayers Nanoscience & Nanotechnology Nanotechnology Nanotechnology and Microengineering Organic chemistry Phase transitions Photoelectrons Science & Technology Science & Technology - Other Topics Sheets Single crystals Technology Transmission electron microscopy |
| title | Chemically induced transformation of chemical vapour deposition grown bilayer graphene into fluorinated single-layer diamond |
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