Rapid and Efficient Construction of Indolizinoisoindole Skeletons by a Rhodium‐Catalyzed Tandem Reaction

Rapid and Efficient Construction of Indolizinoisoindole Skeletons by a Rhodium‐Catalyzed Tandem Reaction

A facile rhodium‐catalyzed tandem reaction of two molecules of acrylates with two molecules of 2‐phenylpyridines involving sequential C−H activation, Michael addition, [12+2] cycloaddition and oxidative aromatization has been described. A series of indolizino[3,4,5‐ab]isoindole compounds were effici...

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Veröffentlicht in:Asian journal of organic chemistry 2020-01, Vol.9 (1), p.68-72
Hauptverfasser: Liu, Chang, Wu, Shaonan, Sun, Wan, Meng, Haifang, Xing, Siyang, Zhu, Bolin
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Acrylates
Cascade chemical reactions
Cycloaddition
Organic chemistry
Rhodium
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container_title Asian journal of organic chemistry
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creator Liu, Chang
Wu, Shaonan
Sun, Wan
Meng, Haifang
Xing, Siyang
Zhu, Bolin
description A facile rhodium‐catalyzed tandem reaction of two molecules of acrylates with two molecules of 2‐phenylpyridines involving sequential C−H activation, Michael addition, [12+2] cycloaddition and oxidative aromatization has been described. A series of indolizino[3,4,5‐ab]isoindole compounds were efficiently afforded in good yields by the formation of two C−C bonds, two C=C bonds and one C−N bond.
doi_str_mv 10.1002/ajoc.201900660
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subjects Acrylates
Cascade chemical reactions
Cycloaddition
Organic chemistry
Rhodium
title Rapid and Efficient Construction of Indolizinoisoindole Skeletons by a Rhodium‐Catalyzed Tandem Reaction
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