An impact of the molar ratio of Na2O/K2O on nanomechanical properties of glaze materials containing zirconium oxide
In this paper the nanomechanical properties of three groups of glass-ceramic materials were measured. The materials designated from the multicomponent system: SiO2-Al2O3-CaO-MgO-Na2O-K2O and the difference between them was the molar ratio of sodium oxide to potassium oxide, equal to, respectively 5....
Gespeichert in:
Veröffentlicht in: | Journal of alloys and compounds 2020-01, Vol.815, p.152411, Article 152411 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | |
container_start_page | 152411 |
container_title | Journal of alloys and compounds |
container_volume | 815 |
creator | Pasiut, Katarzyna Partyka, Janusz Bućko, Mirosław M. Grandys, Marek Kurpaska, Łukasz Piekarczyk, Wojciech |
description | In this paper the nanomechanical properties of three groups of glass-ceramic materials were measured. The materials designated from the multicomponent system: SiO2-Al2O3-CaO-MgO-Na2O-K2O and the difference between them was the molar ratio of sodium oxide to potassium oxide, equal to, respectively 5.45; 1.19; and 0.77. Zirconium oxide was added to those materials, in three different amounts (1.5; 3; 6 wt%). The obtained materials were characterized by the XRD method. The materials were also observed by means of a scanning electron microscope. The chemical compositions of amorphous and crystalline phases were analyzed by the EDS measurements. It has been discovered that the amorphous phase contains small amounts of zirconium cations, which positively affect its mechanical properties as confirmed by the results of a nanomechanical study. In addition, the presence of zirconium silicate and zirconium oxides in the phase composition improves mechanical properties. It was also shown that the molar ratio of alkali oxides (sodium oxide to potassium oxide) influences the amount of crystalline phase, i.e. mainly zirconium silicate. Sodium oxide, in contrast to potassium oxide, promotes the formation of more crystals in the analyzed materials and improves nanomechanical properties.
•The influence of Na2O/K2O molar ratio and added zirconium oxide on the presence of crystalline phases.•The influence of the addition of zirconium oxide on the nanomechanical properties.•The influence of Na2O/K2O molar ratio on the nanomechanical properties. |
doi_str_mv | 10.1016/j.jallcom.2019.152411 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2337160863</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0925838819336576</els_id><sourcerecordid>2337160863</sourcerecordid><originalsourceid>FETCH-LOGICAL-c384t-1a8e43fc485882e089ae447dce1b887b615eeed12b30eb3aa7b0c4e063a1972e3</originalsourceid><addsrcrecordid>eNqFkElLBDEQhYMoOC4_QQh47pksvaRPIuKG4lz0HKrTNZqmOxmTjOj8ejOMd09FFd97VfUIueBszhmvF8N8gHE0fpoLxts5r0TJ-QGZcdXIoqzr9pDMWCuqQkmljslJjANjmZR8RuK1o3Zag0nUr2j6QDr5EQINkKzfjV5ALBdPYkm9ow6cn9B8gLMGRroOfo0hWYw78H2EbVZDwmBhjNR4l8A6697p1obc2c1E_bft8YwcrTKB53_1lLzd3b7ePBTPy_vHm-vnwkhVpoKDwlKuTKkqpQQy1QKWZdMb5J1STVfzChF7LjrJsJMATcdMiayWwNtGoDwll3vffOjnBmPSg98El1dqIWXDa6ZqmalqT5ngYwy40utgJwg_mjO9y1cP-i9fvctX7_PNuqu9DvMLXxaDjsaiM9jbgCbp3tt_HH4BSNuHQQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2337160863</pqid></control><display><type>article</type><title>An impact of the molar ratio of Na2O/K2O on nanomechanical properties of glaze materials containing zirconium oxide</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Pasiut, Katarzyna ; Partyka, Janusz ; Bućko, Mirosław M. ; Grandys, Marek ; Kurpaska, Łukasz ; Piekarczyk, Wojciech</creator><creatorcontrib>Pasiut, Katarzyna ; Partyka, Janusz ; Bućko, Mirosław M. ; Grandys, Marek ; Kurpaska, Łukasz ; Piekarczyk, Wojciech</creatorcontrib><description>In this paper the nanomechanical properties of three groups of glass-ceramic materials were measured. The materials designated from the multicomponent system: SiO2-Al2O3-CaO-MgO-Na2O-K2O and the difference between them was the molar ratio of sodium oxide to potassium oxide, equal to, respectively 5.45; 1.19; and 0.77. Zirconium oxide was added to those materials, in three different amounts (1.5; 3; 6 wt%). The obtained materials were characterized by the XRD method. The materials were also observed by means of a scanning electron microscope. The chemical compositions of amorphous and crystalline phases were analyzed by the EDS measurements. It has been discovered that the amorphous phase contains small amounts of zirconium cations, which positively affect its mechanical properties as confirmed by the results of a nanomechanical study. In addition, the presence of zirconium silicate and zirconium oxides in the phase composition improves mechanical properties. It was also shown that the molar ratio of alkali oxides (sodium oxide to potassium oxide) influences the amount of crystalline phase, i.e. mainly zirconium silicate. Sodium oxide, in contrast to potassium oxide, promotes the formation of more crystals in the analyzed materials and improves nanomechanical properties.
•The influence of Na2O/K2O molar ratio and added zirconium oxide on the presence of crystalline phases.•The influence of the addition of zirconium oxide on the nanomechanical properties.•The influence of Na2O/K2O molar ratio on the nanomechanical properties.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2019.152411</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Aluminum oxide ; Ceramics industry ; Chemical composition ; Crystal structure ; Crystallinity ; Glass ceramics ; Glass-ceramic materials ; Mechanical properties ; Nanomechanical properties ; Organic chemistry ; Phase composition ; Potassium ; Silicon dioxide ; Sodium ; Young’s modulus ; Zirconium ; Zirconium oxide ; Zirconium oxides ; Zirconium silicate</subject><ispartof>Journal of alloys and compounds, 2020-01, Vol.815, p.152411, Article 152411</ispartof><rights>2019 The Authors</rights><rights>Copyright Elsevier BV Jan 30, 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c384t-1a8e43fc485882e089ae447dce1b887b615eeed12b30eb3aa7b0c4e063a1972e3</citedby><cites>FETCH-LOGICAL-c384t-1a8e43fc485882e089ae447dce1b887b615eeed12b30eb3aa7b0c4e063a1972e3</cites><orcidid>0000-0002-6337-6852 ; 0000-0002-5184-5711</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2019.152411$$EHTML$$P50$$Gelsevier$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Pasiut, Katarzyna</creatorcontrib><creatorcontrib>Partyka, Janusz</creatorcontrib><creatorcontrib>Bućko, Mirosław M.</creatorcontrib><creatorcontrib>Grandys, Marek</creatorcontrib><creatorcontrib>Kurpaska, Łukasz</creatorcontrib><creatorcontrib>Piekarczyk, Wojciech</creatorcontrib><title>An impact of the molar ratio of Na2O/K2O on nanomechanical properties of glaze materials containing zirconium oxide</title><title>Journal of alloys and compounds</title><description>In this paper the nanomechanical properties of three groups of glass-ceramic materials were measured. The materials designated from the multicomponent system: SiO2-Al2O3-CaO-MgO-Na2O-K2O and the difference between them was the molar ratio of sodium oxide to potassium oxide, equal to, respectively 5.45; 1.19; and 0.77. Zirconium oxide was added to those materials, in three different amounts (1.5; 3; 6 wt%). The obtained materials were characterized by the XRD method. The materials were also observed by means of a scanning electron microscope. The chemical compositions of amorphous and crystalline phases were analyzed by the EDS measurements. It has been discovered that the amorphous phase contains small amounts of zirconium cations, which positively affect its mechanical properties as confirmed by the results of a nanomechanical study. In addition, the presence of zirconium silicate and zirconium oxides in the phase composition improves mechanical properties. It was also shown that the molar ratio of alkali oxides (sodium oxide to potassium oxide) influences the amount of crystalline phase, i.e. mainly zirconium silicate. Sodium oxide, in contrast to potassium oxide, promotes the formation of more crystals in the analyzed materials and improves nanomechanical properties.
•The influence of Na2O/K2O molar ratio and added zirconium oxide on the presence of crystalline phases.•The influence of the addition of zirconium oxide on the nanomechanical properties.•The influence of Na2O/K2O molar ratio on the nanomechanical properties.</description><subject>Aluminum oxide</subject><subject>Ceramics industry</subject><subject>Chemical composition</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Glass ceramics</subject><subject>Glass-ceramic materials</subject><subject>Mechanical properties</subject><subject>Nanomechanical properties</subject><subject>Organic chemistry</subject><subject>Phase composition</subject><subject>Potassium</subject><subject>Silicon dioxide</subject><subject>Sodium</subject><subject>Young’s modulus</subject><subject>Zirconium</subject><subject>Zirconium oxide</subject><subject>Zirconium oxides</subject><subject>Zirconium silicate</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkElLBDEQhYMoOC4_QQh47pksvaRPIuKG4lz0HKrTNZqmOxmTjOj8ejOMd09FFd97VfUIueBszhmvF8N8gHE0fpoLxts5r0TJ-QGZcdXIoqzr9pDMWCuqQkmljslJjANjmZR8RuK1o3Zag0nUr2j6QDr5EQINkKzfjV5ALBdPYkm9ow6cn9B8gLMGRroOfo0hWYw78H2EbVZDwmBhjNR4l8A6697p1obc2c1E_bft8YwcrTKB53_1lLzd3b7ePBTPy_vHm-vnwkhVpoKDwlKuTKkqpQQy1QKWZdMb5J1STVfzChF7LjrJsJMATcdMiayWwNtGoDwll3vffOjnBmPSg98El1dqIWXDa6ZqmalqT5ngYwy40utgJwg_mjO9y1cP-i9fvctX7_PNuqu9DvMLXxaDjsaiM9jbgCbp3tt_HH4BSNuHQQ</recordid><startdate>20200130</startdate><enddate>20200130</enddate><creator>Pasiut, Katarzyna</creator><creator>Partyka, Janusz</creator><creator>Bućko, Mirosław M.</creator><creator>Grandys, Marek</creator><creator>Kurpaska, Łukasz</creator><creator>Piekarczyk, Wojciech</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-6337-6852</orcidid><orcidid>https://orcid.org/0000-0002-5184-5711</orcidid></search><sort><creationdate>20200130</creationdate><title>An impact of the molar ratio of Na2O/K2O on nanomechanical properties of glaze materials containing zirconium oxide</title><author>Pasiut, Katarzyna ; Partyka, Janusz ; Bućko, Mirosław M. ; Grandys, Marek ; Kurpaska, Łukasz ; Piekarczyk, Wojciech</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-1a8e43fc485882e089ae447dce1b887b615eeed12b30eb3aa7b0c4e063a1972e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aluminum oxide</topic><topic>Ceramics industry</topic><topic>Chemical composition</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Glass ceramics</topic><topic>Glass-ceramic materials</topic><topic>Mechanical properties</topic><topic>Nanomechanical properties</topic><topic>Organic chemistry</topic><topic>Phase composition</topic><topic>Potassium</topic><topic>Silicon dioxide</topic><topic>Sodium</topic><topic>Young’s modulus</topic><topic>Zirconium</topic><topic>Zirconium oxide</topic><topic>Zirconium oxides</topic><topic>Zirconium silicate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pasiut, Katarzyna</creatorcontrib><creatorcontrib>Partyka, Janusz</creatorcontrib><creatorcontrib>Bućko, Mirosław M.</creatorcontrib><creatorcontrib>Grandys, Marek</creatorcontrib><creatorcontrib>Kurpaska, Łukasz</creatorcontrib><creatorcontrib>Piekarczyk, Wojciech</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pasiut, Katarzyna</au><au>Partyka, Janusz</au><au>Bućko, Mirosław M.</au><au>Grandys, Marek</au><au>Kurpaska, Łukasz</au><au>Piekarczyk, Wojciech</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An impact of the molar ratio of Na2O/K2O on nanomechanical properties of glaze materials containing zirconium oxide</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2020-01-30</date><risdate>2020</risdate><volume>815</volume><spage>152411</spage><pages>152411-</pages><artnum>152411</artnum><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>In this paper the nanomechanical properties of three groups of glass-ceramic materials were measured. The materials designated from the multicomponent system: SiO2-Al2O3-CaO-MgO-Na2O-K2O and the difference between them was the molar ratio of sodium oxide to potassium oxide, equal to, respectively 5.45; 1.19; and 0.77. Zirconium oxide was added to those materials, in three different amounts (1.5; 3; 6 wt%). The obtained materials were characterized by the XRD method. The materials were also observed by means of a scanning electron microscope. The chemical compositions of amorphous and crystalline phases were analyzed by the EDS measurements. It has been discovered that the amorphous phase contains small amounts of zirconium cations, which positively affect its mechanical properties as confirmed by the results of a nanomechanical study. In addition, the presence of zirconium silicate and zirconium oxides in the phase composition improves mechanical properties. It was also shown that the molar ratio of alkali oxides (sodium oxide to potassium oxide) influences the amount of crystalline phase, i.e. mainly zirconium silicate. Sodium oxide, in contrast to potassium oxide, promotes the formation of more crystals in the analyzed materials and improves nanomechanical properties.
•The influence of Na2O/K2O molar ratio and added zirconium oxide on the presence of crystalline phases.•The influence of the addition of zirconium oxide on the nanomechanical properties.•The influence of Na2O/K2O molar ratio on the nanomechanical properties.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2019.152411</doi><orcidid>https://orcid.org/0000-0002-6337-6852</orcidid><orcidid>https://orcid.org/0000-0002-5184-5711</orcidid><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0925-8388 |
ispartof | Journal of alloys and compounds, 2020-01, Vol.815, p.152411, Article 152411 |
issn | 0925-8388 1873-4669 |
language | eng |
recordid | cdi_proquest_journals_2337160863 |
source | Elsevier ScienceDirect Journals Complete |
subjects | Aluminum oxide Ceramics industry Chemical composition Crystal structure Crystallinity Glass ceramics Glass-ceramic materials Mechanical properties Nanomechanical properties Organic chemistry Phase composition Potassium Silicon dioxide Sodium Young’s modulus Zirconium Zirconium oxide Zirconium oxides Zirconium silicate |
title | An impact of the molar ratio of Na2O/K2O on nanomechanical properties of glaze materials containing zirconium oxide |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T12%3A25%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20impact%20of%20the%20molar%20ratio%20of%20Na2O/K2O%20on%20nanomechanical%20properties%20of%20glaze%20materials%20containing%20zirconium%20oxide&rft.jtitle=Journal%20of%20alloys%20and%20compounds&rft.au=Pasiut,%20Katarzyna&rft.date=2020-01-30&rft.volume=815&rft.spage=152411&rft.pages=152411-&rft.artnum=152411&rft.issn=0925-8388&rft.eissn=1873-4669&rft_id=info:doi/10.1016/j.jallcom.2019.152411&rft_dat=%3Cproquest_cross%3E2337160863%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2337160863&rft_id=info:pmid/&rft_els_id=S0925838819336576&rfr_iscdi=true |