Stable Eutectic Formation in Spray-Formed Cast Iron
Spray forming is an advanced casting process that produces refined and homogenous microstructure directly from the liquid metal regardless of the alloy system. However, the microstructure evolution during spray forming is complex because the process comprises two sequential steps with very different...
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Veröffentlicht in: | Metallurgical and materials transactions. A, Physical metallurgy and materials science Physical metallurgy and materials science, 2020-02, Vol.51 (2), p.798-808 |
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creator | Zepon, Guilherme Fernandes, Julia F. M. Otani, Lucas B. Bolfarini, Claudemiro |
description | Spray forming is an advanced casting process that produces refined and homogenous microstructure directly from the liquid metal regardless of the alloy system. However, the microstructure evolution during spray forming is complex because the process comprises two sequential steps with very different cooling rates,
i.e.
, atomization and deposition. It is well known that the microstructure of cast irons is highly dependent on the chemical composition and the cooling rate imposed to the liquid. In order to better understand the microstructural evolution during solidification by spray forming, this study investigated the solidification of two cast irons with different stable–metastable eutectic temperature interval (ΔTE
S−M
), 30 K and 17 K. The microstructures of both overspray powders presented a dendritic array of austenite with cementite in the inter-dendritic spacing. Despite the high cooling rates imposed to the alloys during the atomization step, the final microstructure was defined by the cooling conditions prevailing during the final step of deposit solidification and stable eutectic was formed. This was ascribed to the dynamic process involving heating and remelting of the low melting temperature phases present in the droplets that arrives completely or partially solid in the deposition zone. |
doi_str_mv | 10.1007/s11661-019-05549-7 |
format | Article |
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i.e.
, atomization and deposition. It is well known that the microstructure of cast irons is highly dependent on the chemical composition and the cooling rate imposed to the liquid. In order to better understand the microstructural evolution during solidification by spray forming, this study investigated the solidification of two cast irons with different stable–metastable eutectic temperature interval (ΔTE
S−M
), 30 K and 17 K. The microstructures of both overspray powders presented a dendritic array of austenite with cementite in the inter-dendritic spacing. Despite the high cooling rates imposed to the alloys during the atomization step, the final microstructure was defined by the cooling conditions prevailing during the final step of deposit solidification and stable eutectic was formed. This was ascribed to the dynamic process involving heating and remelting of the low melting temperature phases present in the droplets that arrives completely or partially solid in the deposition zone.</description><identifier>ISSN: 1073-5623</identifier><identifier>EISSN: 1543-1940</identifier><identifier>DOI: 10.1007/s11661-019-05549-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alloy systems ; Atomizing ; Cast iron ; Cementite ; Characterization and Evaluation of Materials ; Chemical composition ; Chemistry and Materials Science ; Cooling ; Cooling rate ; Dendritic powders ; Deposition ; Eutectic temperature ; Evolution ; Heat treating ; Liquid metals ; Materials Science ; Melt temperature ; Melting ; Metallic Materials ; Microstructure ; Nanotechnology ; Organic chemistry ; Solidification ; Spray casting ; Spray forming ; Structural Materials ; Surfaces and Interfaces ; Thin Films</subject><ispartof>Metallurgical and materials transactions. A, Physical metallurgy and materials science, 2020-02, Vol.51 (2), p.798-808</ispartof><rights>The Minerals, Metals & Materials Society and ASM International 2019</rights><rights>Metallurgical and Materials Transactions A is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-5782105721a5cabe9cb856edff53177e87f9d8dcfbbde222dc6609c4d55e2b733</citedby><cites>FETCH-LOGICAL-c319t-5782105721a5cabe9cb856edff53177e87f9d8dcfbbde222dc6609c4d55e2b733</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11661-019-05549-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11661-019-05549-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Zepon, Guilherme</creatorcontrib><creatorcontrib>Fernandes, Julia F. M.</creatorcontrib><creatorcontrib>Otani, Lucas B.</creatorcontrib><creatorcontrib>Bolfarini, Claudemiro</creatorcontrib><title>Stable Eutectic Formation in Spray-Formed Cast Iron</title><title>Metallurgical and materials transactions. A, Physical metallurgy and materials science</title><addtitle>Metall Mater Trans A</addtitle><description>Spray forming is an advanced casting process that produces refined and homogenous microstructure directly from the liquid metal regardless of the alloy system. However, the microstructure evolution during spray forming is complex because the process comprises two sequential steps with very different cooling rates,
i.e.
, atomization and deposition. It is well known that the microstructure of cast irons is highly dependent on the chemical composition and the cooling rate imposed to the liquid. In order to better understand the microstructural evolution during solidification by spray forming, this study investigated the solidification of two cast irons with different stable–metastable eutectic temperature interval (ΔTE
S−M
), 30 K and 17 K. The microstructures of both overspray powders presented a dendritic array of austenite with cementite in the inter-dendritic spacing. Despite the high cooling rates imposed to the alloys during the atomization step, the final microstructure was defined by the cooling conditions prevailing during the final step of deposit solidification and stable eutectic was formed. This was ascribed to the dynamic process involving heating and remelting of the low melting temperature phases present in the droplets that arrives completely or partially solid in the deposition zone.</description><subject>Alloy systems</subject><subject>Atomizing</subject><subject>Cast iron</subject><subject>Cementite</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical composition</subject><subject>Chemistry and Materials Science</subject><subject>Cooling</subject><subject>Cooling rate</subject><subject>Dendritic powders</subject><subject>Deposition</subject><subject>Eutectic temperature</subject><subject>Evolution</subject><subject>Heat treating</subject><subject>Liquid metals</subject><subject>Materials Science</subject><subject>Melt temperature</subject><subject>Melting</subject><subject>Metallic Materials</subject><subject>Microstructure</subject><subject>Nanotechnology</subject><subject>Organic chemistry</subject><subject>Solidification</subject><subject>Spray casting</subject><subject>Spray forming</subject><subject>Structural Materials</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><issn>1073-5623</issn><issn>1543-1940</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp9kEFLAzEQhYMoWKt_wNOC52gms0k2RymtFgoequeQTbKypd2tSfbQf-_WFbx5mmH43hveI-Qe2CMwpp4SgJRAGWjKhCg1VRdkBqJECrpkl-POFFIhOV6Tm5R2jI0oyhnBbbb1PhTLIQeXW1es-niwue27ou2K7THaEz2fgi8WNuViHfvullw1dp_C3e-ck4_V8n3xSjdvL-vF84Y6BJ2pUBUHJhQHK5ytg3Z1JWTwTSMQlAqVarSvvGvq2gfOuXdSMu1KL0TgtUKck4fJ9xj7ryGkbHb9ELvxpeGIWCFqqUaKT5SLfUoxNOYY24ONJwPMnMsxUzlmTGx-yjFnEU6iNMLdZ4h_1v-ovgEHW2Yh</recordid><startdate>20200201</startdate><enddate>20200201</enddate><creator>Zepon, Guilherme</creator><creator>Fernandes, Julia F. 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M. ; Otani, Lucas B. ; Bolfarini, Claudemiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-5782105721a5cabe9cb856edff53177e87f9d8dcfbbde222dc6609c4d55e2b733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alloy systems</topic><topic>Atomizing</topic><topic>Cast iron</topic><topic>Cementite</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical composition</topic><topic>Chemistry and Materials Science</topic><topic>Cooling</topic><topic>Cooling rate</topic><topic>Dendritic powders</topic><topic>Deposition</topic><topic>Eutectic temperature</topic><topic>Evolution</topic><topic>Heat treating</topic><topic>Liquid metals</topic><topic>Materials Science</topic><topic>Melt temperature</topic><topic>Melting</topic><topic>Metallic Materials</topic><topic>Microstructure</topic><topic>Nanotechnology</topic><topic>Organic chemistry</topic><topic>Solidification</topic><topic>Spray casting</topic><topic>Spray forming</topic><topic>Structural Materials</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zepon, Guilherme</creatorcontrib><creatorcontrib>Fernandes, Julia F. 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A, Physical metallurgy and materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zepon, Guilherme</au><au>Fernandes, Julia F. M.</au><au>Otani, Lucas B.</au><au>Bolfarini, Claudemiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stable Eutectic Formation in Spray-Formed Cast Iron</atitle><jtitle>Metallurgical and materials transactions. A, Physical metallurgy and materials science</jtitle><stitle>Metall Mater Trans A</stitle><date>2020-02-01</date><risdate>2020</risdate><volume>51</volume><issue>2</issue><spage>798</spage><epage>808</epage><pages>798-808</pages><issn>1073-5623</issn><eissn>1543-1940</eissn><abstract>Spray forming is an advanced casting process that produces refined and homogenous microstructure directly from the liquid metal regardless of the alloy system. However, the microstructure evolution during spray forming is complex because the process comprises two sequential steps with very different cooling rates,
i.e.
, atomization and deposition. It is well known that the microstructure of cast irons is highly dependent on the chemical composition and the cooling rate imposed to the liquid. In order to better understand the microstructural evolution during solidification by spray forming, this study investigated the solidification of two cast irons with different stable–metastable eutectic temperature interval (ΔTE
S−M
), 30 K and 17 K. The microstructures of both overspray powders presented a dendritic array of austenite with cementite in the inter-dendritic spacing. Despite the high cooling rates imposed to the alloys during the atomization step, the final microstructure was defined by the cooling conditions prevailing during the final step of deposit solidification and stable eutectic was formed. This was ascribed to the dynamic process involving heating and remelting of the low melting temperature phases present in the droplets that arrives completely or partially solid in the deposition zone.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11661-019-05549-7</doi><tpages>11</tpages></addata></record> |
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subjects | Alloy systems Atomizing Cast iron Cementite Characterization and Evaluation of Materials Chemical composition Chemistry and Materials Science Cooling Cooling rate Dendritic powders Deposition Eutectic temperature Evolution Heat treating Liquid metals Materials Science Melt temperature Melting Metallic Materials Microstructure Nanotechnology Organic chemistry Solidification Spray casting Spray forming Structural Materials Surfaces and Interfaces Thin Films |
title | Stable Eutectic Formation in Spray-Formed Cast Iron |
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