Syntheses, structures and catalytic activity of tetranuclear Mg complexes in the ROP of cyclic esters under industrially relevant conditions

Four tetranuclear magnesium complexes were synthesized and fully characterized. They are excellent catalysts for the ring-opening polymerization (ROP) of bulk racemic -lactide ( rac -LA) and -caprolactone ( -CL) even with low catalyst loading under industrially relevant conditions without additional...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-01, Vol.49 (2), p.375-387
Hauptverfasser:	Ghosh, Swarup, Wölper, Christoph, Tjaberings, Alexander, Gröschel, André H, Schulz, Stephan
Format:	Artikel
Sprache:	eng
Schlagworte:	Addition polymerization Biocompatibility Bulk polymerization Catalysts Catalytic activity Crystallography Esters Infrared spectroscopy Initiators Magnesium Molecular weight Molecular weight distribution Monomers NMR Nuclear magnetic resonance Polymerization Ring opening polymerization
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!