Tri-n-butylphosphine-Catalyzed Phosphonoethylation Reactions of Hydrophosphoryl Compounds

Tri-n-butylphosphine-Catalyzed Phosphonoethylation Reactions of Hydrophosphoryl Compounds

An efficient method for the synthesis of 1,2-bisphosphoryl compounds based on the addition of hydrophosphoryl derivatives to O,O -diethyl vinylphosphonate was developed. The reaction proceeds in mild conditions under catalysis with tri- n -butylphosphine and leads to the formation of the correspondi...

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Veröffentlicht in:Russian journal of general chemistry 2019-11, Vol.89 (11), p.2207-2211
Hauptverfasser: Il’in, A. V., Antonova, A. A., Khusainova, N. G., Galkin, V. I.
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemical reactions
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Oxides
Phosphonates
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Zusammenfassung:An efficient method for the synthesis of 1,2-bisphosphoryl compounds based on the addition of hydrophosphoryl derivatives to O,O -diethyl vinylphosphonate was developed. The reaction proceeds in mild conditions under catalysis with tri- n -butylphosphine and leads to the formation of the corresponding target products with high yield.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363219110070