New trend of Jebel Chakir landfill leachate pre-treatment by photocatalytic TiO2/Ag nanocomposite prior to fermentation using Candida tropicalis strain

The current study investigates the technical applicability of a combination of photocatalytic process with TiO2/Ag nanocomposite and the biological treatment using Candida tropicalis strain for pollutants removal from mature Jebel Chakir landfill leachate (LFL) under visible light irradiation (33Wcm...

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Veröffentlicht in:International biodeterioration & biodegradation 2020-01, Vol.146, p.104829, Article 104829
Hauptverfasser: Yasmin, Cherni, Lobna, Elleuch, Mouna, Messaoud, Kais, Djebali, Mariam, Kasmi, Rached, Salhi, Abdelwaheb, Chatti, Ismail, Trabelsi
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container_title International biodeterioration & biodegradation
container_volume 146
creator Yasmin, Cherni
Lobna, Elleuch
Mouna, Messaoud
Kais, Djebali
Mariam, Kasmi
Rached, Salhi
Abdelwaheb, Chatti
Ismail, Trabelsi
description The current study investigates the technical applicability of a combination of photocatalytic process with TiO2/Ag nanocomposite and the biological treatment using Candida tropicalis strain for pollutants removal from mature Jebel Chakir landfill leachate (LFL) under visible light irradiation (33Wcm−2). Interestingly, after the nanocomposite treatment, the degradation rate achieved under the optimum conditions 70, 71.25 and 49.1% for COD, TOC, and NH4+-N, respectively. Thereafter, the biological process was applied as a second treatment stage in order to enhance the quality of pre-treated LFL. About 90% of COD, 84.61% of TOC and 75% of NH4+-N were removed after the combined process. Furthermore, heavy metals, especially, Fe, Zn, Cu, Cd, and Pb were significantly reduced with the average removal rates of 50, 63.8, 83, 95 and 95%, respectively. The photocatalytic efficiency in organic pollutants removal was consistently higher than 60% after five cycles without any evident change and deactivation of nanocomposite. The overall results proved that TiO2/Ag exhibited an important photocatalytic activity and an excellent recyclability. In addition, the combination of TiO2/Ag photocatalytic process with biological treatment by C. tropicalis for toxic compounds removal from mature LFL may provide a more comprehensive potential for mature LFL treatment. [Display omitted] •Synthesis and characterization of TiO2/Ag nanocomposite was carried out.•Photocatalytic pre-treatment of mature LFL using Simplex design has been performed.•TiO2/Ag combined with biological treatment is effective for LFL treatment.•TiO2/Ag nanocomposite exhibit excellent recyclability.
doi_str_mv 10.1016/j.ibiod.2019.104829
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Interestingly, after the nanocomposite treatment, the degradation rate achieved under the optimum conditions 70, 71.25 and 49.1% for COD, TOC, and NH4+-N, respectively. Thereafter, the biological process was applied as a second treatment stage in order to enhance the quality of pre-treated LFL. About 90% of COD, 84.61% of TOC and 75% of NH4+-N were removed after the combined process. Furthermore, heavy metals, especially, Fe, Zn, Cu, Cd, and Pb were significantly reduced with the average removal rates of 50, 63.8, 83, 95 and 95%, respectively. The photocatalytic efficiency in organic pollutants removal was consistently higher than 60% after five cycles without any evident change and deactivation of nanocomposite. The overall results proved that TiO2/Ag exhibited an important photocatalytic activity and an excellent recyclability. In addition, the combination of TiO2/Ag photocatalytic process with biological treatment by C. tropicalis for toxic compounds removal from mature LFL may provide a more comprehensive potential for mature LFL treatment. 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Interestingly, after the nanocomposite treatment, the degradation rate achieved under the optimum conditions 70, 71.25 and 49.1% for COD, TOC, and NH4+-N, respectively. Thereafter, the biological process was applied as a second treatment stage in order to enhance the quality of pre-treated LFL. About 90% of COD, 84.61% of TOC and 75% of NH4+-N were removed after the combined process. Furthermore, heavy metals, especially, Fe, Zn, Cu, Cd, and Pb were significantly reduced with the average removal rates of 50, 63.8, 83, 95 and 95%, respectively. The photocatalytic efficiency in organic pollutants removal was consistently higher than 60% after five cycles without any evident change and deactivation of nanocomposite. The overall results proved that TiO2/Ag exhibited an important photocatalytic activity and an excellent recyclability. 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Interestingly, after the nanocomposite treatment, the degradation rate achieved under the optimum conditions 70, 71.25 and 49.1% for COD, TOC, and NH4+-N, respectively. Thereafter, the biological process was applied as a second treatment stage in order to enhance the quality of pre-treated LFL. About 90% of COD, 84.61% of TOC and 75% of NH4+-N were removed after the combined process. Furthermore, heavy metals, especially, Fe, Zn, Cu, Cd, and Pb were significantly reduced with the average removal rates of 50, 63.8, 83, 95 and 95%, respectively. The photocatalytic efficiency in organic pollutants removal was consistently higher than 60% after five cycles without any evident change and deactivation of nanocomposite. The overall results proved that TiO2/Ag exhibited an important photocatalytic activity and an excellent recyclability. In addition, the combination of TiO2/Ag photocatalytic process with biological treatment by C. tropicalis for toxic compounds removal from mature LFL may provide a more comprehensive potential for mature LFL treatment. [Display omitted] •Synthesis and characterization of TiO2/Ag nanocomposite was carried out.•Photocatalytic pre-treatment of mature LFL using Simplex design has been performed.•TiO2/Ag combined with biological treatment is effective for LFL treatment.•TiO2/Ag nanocomposite exhibit excellent recyclability.</abstract><cop>Barking</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.ibiod.2019.104829</doi></addata></record>
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subjects Biological activity
Biological treatment
Cadmium
Candida tropicalis
Catalytic activity
Combined process
Copper
Deactivation
Fermentation
Heavy metals
Iron
Irradiation
Landfill
Landfill leachate
Landfills
Leachates
Lead
Light irradiation
Nanocomposites
Photocatalysis
Photoreactor
Pollutant removal
Pollutants
Pretreatment
Radiation
Recyclability
Silver
TiO2/Ag
Titanium dioxide
Waste disposal sites
Waste treatment
Wastewater treatment
Water pollution treatment
Zinc
title New trend of Jebel Chakir landfill leachate pre-treatment by photocatalytic TiO2/Ag nanocomposite prior to fermentation using Candida tropicalis strain
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