A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane units

[2.2]Paracyclophane (pCp) scaffolds, unlike many π-conjugated building blocks, have been rarely explored in supramolecular self-assembly. Herein we report the synthesis and characterization of two ligands, pCpd3py and pCpd4py, composed of a pCp core functionalized at its 7- and 15-positions respecti...

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Veröffentlicht in:	Inorganic chemistry frontiers 2020-01, Vol.7 (1), p.232-238
Hauptverfasser:	Diego Rota Martir, Delforce, Lucie, Cordes, David B, Slawin, Alexandra M Z, Warriner, Stuart L, Jacquemin, Denis, Zysman-Colman, Eli
Format:	Artikel
Sprache:	eng
Schlagworte:	Cages Crystal structure Crystallography Density functional theory Emission analysis Inorganic chemistry Ligands Mathematical analysis NMR spectroscopy Optoelectronics Palladium Self-assembly Time dependence
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