Catenated and spirocyclic polychalcogenides from potassium carbonate and elemental chalcogens
The reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph 3 P) 2 N) produces catena -[S 12 ] 2− , the longest structurally characterised polysulfide dianion, or spiro -[Se 11 ] 2− as ion-separated [PPN] + salts. Reaction of potassium carbo...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019-12, Vol.55 (99), p.14965-14967 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Liebing, Phil Kühling, Marcel Swanson, Claudia Feneberg, Martin Hilfert, Liane Goldhahn, Rüdiger Chivers, Tristram Edelmann, Frank T |
| description | The reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph
3
P)
2
N) produces
catena
-[S
12
]
2−
, the longest structurally characterised polysulfide dianion, or
spiro
-[Se
11
]
2−
as ion-separated [PPN]
+
salts.
Reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph
3
P)
2
N) produces
catena
-[S
12
]
2−
, the longest structurally characterised polysulfide dianion, or
spiro
-[Se
11
]
2−
as ion-separated [PPN]
+
salts. |
| doi_str_mv | 10.1039/c9cc08347b |
| format | Article |
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3
P)
2
N) produces
catena
-[S
12
]
2−
, the longest structurally characterised polysulfide dianion, or
spiro
-[Se
11
]
2−
as ion-separated [PPN]
+
salts.
Reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph
3
P)
2
N) produces
catena
-[S
12
]
2−
, the longest structurally characterised polysulfide dianion, or
spiro
-[Se
11
]
2−
as ion-separated [PPN]
+
salts.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc08347b</identifier><identifier>PMID: 31774421</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Acetone ; Anions ; Chemical industry ; Crystallography ; Potash ; Potassium ; Potassium carbonate ; Selenium ; Supply & demand</subject><ispartof>Chemical communications (Cambridge, England), 2019-12, Vol.55 (99), p.14965-14967</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-d99e1359f1ebe8b1a4d0a403c04949a31b627d32a454e83579cb9bc4cae544053</citedby><cites>FETCH-LOGICAL-c429t-d99e1359f1ebe8b1a4d0a403c04949a31b627d32a454e83579cb9bc4cae544053</cites><orcidid>0000-0001-5209-0018 ; 0000-0001-8296-2331 ; 0000-0002-0659-1759 ; 0000-0003-4253-0061 ; 0000-0002-4660-1691</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31774421$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liebing, Phil</creatorcontrib><creatorcontrib>Kühling, Marcel</creatorcontrib><creatorcontrib>Swanson, Claudia</creatorcontrib><creatorcontrib>Feneberg, Martin</creatorcontrib><creatorcontrib>Hilfert, Liane</creatorcontrib><creatorcontrib>Goldhahn, Rüdiger</creatorcontrib><creatorcontrib>Chivers, Tristram</creatorcontrib><creatorcontrib>Edelmann, Frank T</creatorcontrib><title>Catenated and spirocyclic polychalcogenides from potassium carbonate and elemental chalcogens</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>The reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph
3
P)
2
N) produces
catena
-[S
12
]
2−
, the longest structurally characterised polysulfide dianion, or
spiro
-[Se
11
]
2−
as ion-separated [PPN]
+
salts.
Reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph
3
P)
2
N) produces
catena
-[S
12
]
2−
, the longest structurally characterised polysulfide dianion, or
spiro
-[Se
11
]
2−
as ion-separated [PPN]
+
salts.</description><subject>Acetone</subject><subject>Anions</subject><subject>Chemical industry</subject><subject>Crystallography</subject><subject>Potash</subject><subject>Potassium</subject><subject>Potassium carbonate</subject><subject>Selenium</subject><subject>Supply & demand</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kc1LxDAQxYMo7rp68a5UvIhQTZpk2xy1-AULXhS8SEmnU-3SNjVpD_vfm_1wBQ8GQoZ5vzcML4QcM3rFKFfXoABowkWc75Ax41MRSpG87S5rqcKYCzkiB87NqT9MJvtkxFkcCxGxMXlPdY-tv0Wg2yJwXWUNLKCuIOhMvYBPXYP5wLYq0AWlNY1v99q5amgC0DY3S-_KijU22Pa6DrYmd0j2Sl07PNq8E_J6f_eSPoaz54en9GYWgohUHxZK4XLXkmGOSc60KKgWlAMVSijNWT6N4oJHWkiBCZexglzlIECjFIJKPiEX67mdNV8Duj5rKgdY17pFM7gs4kxFVCrKPHr-B52bwbZ-O09FnEqaqMhTl2sKrHHOYpl1tmq0XWSMZsvQs1Sl6Sr0Ww-fbkYOeYPFFv1J2QMna8A62Kq_v-b1s__0rCtK_g2K_pIa</recordid><startdate>20191225</startdate><enddate>20191225</enddate><creator>Liebing, Phil</creator><creator>Kühling, Marcel</creator><creator>Swanson, Claudia</creator><creator>Feneberg, Martin</creator><creator>Hilfert, Liane</creator><creator>Goldhahn, Rüdiger</creator><creator>Chivers, Tristram</creator><creator>Edelmann, Frank T</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-5209-0018</orcidid><orcidid>https://orcid.org/0000-0001-8296-2331</orcidid><orcidid>https://orcid.org/0000-0002-0659-1759</orcidid><orcidid>https://orcid.org/0000-0003-4253-0061</orcidid><orcidid>https://orcid.org/0000-0002-4660-1691</orcidid></search><sort><creationdate>20191225</creationdate><title>Catenated and spirocyclic polychalcogenides from potassium carbonate and elemental chalcogens</title><author>Liebing, Phil ; Kühling, Marcel ; Swanson, Claudia ; Feneberg, Martin ; Hilfert, Liane ; Goldhahn, Rüdiger ; Chivers, Tristram ; Edelmann, Frank T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-d99e1359f1ebe8b1a4d0a403c04949a31b627d32a454e83579cb9bc4cae544053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acetone</topic><topic>Anions</topic><topic>Chemical industry</topic><topic>Crystallography</topic><topic>Potash</topic><topic>Potassium</topic><topic>Potassium carbonate</topic><topic>Selenium</topic><topic>Supply & demand</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liebing, Phil</creatorcontrib><creatorcontrib>Kühling, Marcel</creatorcontrib><creatorcontrib>Swanson, Claudia</creatorcontrib><creatorcontrib>Feneberg, Martin</creatorcontrib><creatorcontrib>Hilfert, Liane</creatorcontrib><creatorcontrib>Goldhahn, Rüdiger</creatorcontrib><creatorcontrib>Chivers, Tristram</creatorcontrib><creatorcontrib>Edelmann, Frank T</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liebing, Phil</au><au>Kühling, Marcel</au><au>Swanson, Claudia</au><au>Feneberg, Martin</au><au>Hilfert, Liane</au><au>Goldhahn, Rüdiger</au><au>Chivers, Tristram</au><au>Edelmann, Frank T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catenated and spirocyclic polychalcogenides from potassium carbonate and elemental chalcogens</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2019-12-25</date><risdate>2019</risdate><volume>55</volume><issue>99</issue><spage>14965</spage><epage>14967</epage><pages>14965-14967</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph
3
P)
2
N) produces
catena
-[S
12
]
2−
, the longest structurally characterised polysulfide dianion, or
spiro
-[Se
11
]
2−
as ion-separated [PPN]
+
salts.
Reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph
3
P)
2
N) produces
catena
-[S
12
]
2−
, the longest structurally characterised polysulfide dianion, or
spiro
-[Se
11
]
2−
as ion-separated [PPN]
+
salts.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31774421</pmid><doi>10.1039/c9cc08347b</doi><tpages>3</tpages><orcidid>https://orcid.org/0000-0001-5209-0018</orcidid><orcidid>https://orcid.org/0000-0001-8296-2331</orcidid><orcidid>https://orcid.org/0000-0002-0659-1759</orcidid><orcidid>https://orcid.org/0000-0003-4253-0061</orcidid><orcidid>https://orcid.org/0000-0002-4660-1691</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2019-12, Vol.55 (99), p.14965-14967 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_journals_2323050892 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acetone Anions Chemical industry Crystallography Potash Potassium Potassium carbonate Selenium Supply & demand |
| title | Catenated and spirocyclic polychalcogenides from potassium carbonate and elemental chalcogens |
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