Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols
Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. Advantageously, this catalytic protocol works under additive-free conditions and is compatible with the presence of arom...
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| Veröffentlicht in: | Catalysis science & technology 2019, Vol.9 (24), p.6965-6976 |
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| container_issue | 24 |
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| container_title | Catalysis science & technology |
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| creator | Sorribes, Iván Lemos, Samantha C S Martín, Santiago Mayoral, Alvaro Lima, Renata C Andrés, Juan |
| description | Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. Advantageously, this catalytic protocol works under additive-free conditions and is compatible with the presence of aromatic rings, which are fully retained in the final products. This hydrogenative C–N bond cleavage methodology is catalyzed by a Pd-doped In2O3 catalyst prepared by a microwave hydrothermal-assisted method followed by calcination. This catalyst displays highly dispersed Pd2+ ionic species in the oxide matrix of In2O3 that have appeared to be essential for its high catalytic performance. |
| doi_str_mv | 10.1039/c9cy02128k |
| format | Article |
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This catalyst displays highly dispersed Pd2+ ionic species in the oxide matrix of In2O3 that have appeared to be essential for its high catalytic performance.</description><subject>Alcohol</subject><subject>Alcohols</subject><subject>Amides</subject><subject>Amines</subject><subject>Aromatic compounds</subject><subject>Catalysts</subject><subject>Hydrogenation</subject><subject>Indium oxides</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Palladium</subject><issn>2044-4753</issn><issn>2044-4761</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNo9jU1LAzEQhoMoWGov_oKA59Uks7tJjlL8KBTqQc9lmmS3W9OkblKl_95dKs5lHnjfeYaQW87uOQP9YLQ5McGF-rwgE8HKsihlzS__uYJrMktpx4YpNWdKTEj_ht6j7Y57auOhCy2NDV0EsQKa4w_2NlGkrQuuR08xWJqcdyZ3344azOhPuTN0e7J9HEqYuxhGAe4769JgGCkMNF6iN3EbfbohVw365GZ_e0o-np_e56_FcvWymD8uixaEyIXFZgN1Ka0CBWAQmZYSlBOVrK1o-BgqqSorlXYb52rQQ42jtAakrhuYkruz99DHr6NLeb2Lxz4ML9cCBDCoQFTwC6RgXRg</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Sorribes, Iván</creator><creator>Lemos, Samantha C S</creator><creator>Martín, Santiago</creator><creator>Mayoral, Alvaro</creator><creator>Lima, Renata C</creator><creator>Andrés, Juan</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>2019</creationdate><title>Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols</title><author>Sorribes, Iván ; Lemos, Samantha C S ; Martín, Santiago ; Mayoral, Alvaro ; Lima, Renata C ; Andrés, Juan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g322t-dafb3647d83833caa097738e2576d2f1b3648785d789ebee63933c1a7dc3796f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alcohol</topic><topic>Alcohols</topic><topic>Amides</topic><topic>Amines</topic><topic>Aromatic compounds</topic><topic>Catalysts</topic><topic>Hydrogenation</topic><topic>Indium oxides</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Palladium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sorribes, Iván</creatorcontrib><creatorcontrib>Lemos, Samantha C S</creatorcontrib><creatorcontrib>Martín, Santiago</creatorcontrib><creatorcontrib>Mayoral, Alvaro</creatorcontrib><creatorcontrib>Lima, Renata C</creatorcontrib><creatorcontrib>Andrés, Juan</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Catalysis science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sorribes, Iván</au><au>Lemos, Samantha C S</au><au>Martín, Santiago</au><au>Mayoral, Alvaro</au><au>Lima, Renata C</au><au>Andrés, Juan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols</atitle><jtitle>Catalysis science & technology</jtitle><date>2019</date><risdate>2019</risdate><volume>9</volume><issue>24</issue><spage>6965</spage><epage>6976</epage><pages>6965-6976</pages><issn>2044-4753</issn><eissn>2044-4761</eissn><abstract>Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. 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| ispartof | Catalysis science & technology, 2019, Vol.9 (24), p.6965-6976 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Alcohol Alcohols Amides Amines Aromatic compounds Catalysts Hydrogenation Indium oxides NMR Nuclear magnetic resonance Palladium |
| title | Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols |
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