The enhanced photoluminescence and temperature sensing performance in rare earth doped SrMoO4 phosphors by aliovalent doping: from material design to device applications

Simultaneous enhancement of upconversion luminescence and temperature sensitivity is achieved by aliovalent doping in Er3+/Yb3+ codoped SrMoO4 phosphors and a highly accurate ratiometric temperature sensing platform has been constructed in an all-fiber structure. The influence of aliovalent doping o...

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Veröffentlicht in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2019, Vol.7 (47), p.15007-15013
Hauptverfasser: Zhang, Hui, Zhao, Shilong, Wang, Xiuli, Ren, Xiaotong, Ye, Jiatao, Huang, Lihui, Xu, Shiqing
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container_issue 47
container_start_page 15007
container_title Journal of materials chemistry. C, Materials for optical and electronic devices
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creator Zhang, Hui
Zhao, Shilong
Wang, Xiuli
Ren, Xiaotong
Ye, Jiatao
Huang, Lihui
Xu, Shiqing
description Simultaneous enhancement of upconversion luminescence and temperature sensitivity is achieved by aliovalent doping in Er3+/Yb3+ codoped SrMoO4 phosphors and a highly accurate ratiometric temperature sensing platform has been constructed in an all-fiber structure. The influence of aliovalent doping of Li+ and Ga3+ in SrMoO4 phosphors on the crystal structure and growth was investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). A detailed structural analysis was carried out using Eu3+ ions as a spectroscopic probe to disclose the change of the local site symmetry due to aliovalent doping. The upconversion emission intensity of Er3+ in SrMoO4 phosphors is enhanced by 82 times and 255 times due to Li+ doping and Li+/Ga3+ codoping, respectively. The intense upconversion luminescence and high temperature sensitivity lead to a small temperature uncertainty (0.091 K) and an absolute error (−0.5–0.3 K) as well as good repeatability (
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The influence of aliovalent doping of Li+ and Ga3+ in SrMoO4 phosphors on the crystal structure and growth was investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). A detailed structural analysis was carried out using Eu3+ ions as a spectroscopic probe to disclose the change of the local site symmetry due to aliovalent doping. The upconversion emission intensity of Er3+ in SrMoO4 phosphors is enhanced by 82 times and 255 times due to Li+ doping and Li+/Ga3+ codoping, respectively. The intense upconversion luminescence and high temperature sensitivity lead to a small temperature uncertainty (0.091 K) and an absolute error (−0.5–0.3 K) as well as good repeatability (&lt;1%). 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source Royal Society Of Chemistry Journals 2008-
subjects Crystal growth
Crystal structure
Doping
Erbium
High temperature
Luminescence
Phosphors
Photoluminescence
Sensitivity
Structural analysis
Temperature
Temperature sensors
Upconversion
Ytterbium
title The enhanced photoluminescence and temperature sensing performance in rare earth doped SrMoO4 phosphors by aliovalent doping: from material design to device applications
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