Natural attenuation of antimony and arsenic in soils at the abandoned Sb-deposit Poproč, Slovakia
This contribution investigates the natural attenuation of arsenic (As) and antimony (Sb) in highly contaminated soils at the abandoned Sb-deposit Poproč in eastern Slovakia. The studied soils were identified as technosols with pH values of 3.5–7.0 and high metal and metalloid load: antimony, arsenic...
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| Veröffentlicht in: | Environmental earth sciences 2019-12, Vol.78 (24), p.1-13, Article 672 |
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| creator | Jurkovič, Ľubomír Majzlan, Juraj Hiller, Edgar Klimko, Tomáš Voleková-Lalinská, Bronislava Méres, Štefan Göttlicher, Jörg Steininger, Ralph |
| description | This contribution investigates the natural attenuation of arsenic (As) and antimony (Sb) in highly contaminated soils at the abandoned Sb-deposit Poproč in eastern Slovakia. The studied soils were identified as technosols with pH values of 3.5–7.0 and high metal and metalloid load: antimony, arsenic, lead, and zinc up to 5757, 2484, 683, and 407 mg/kg, respectively. These toxic elements occur in the soils mainly as constituents of secondary minerals, which are products of sulphide oxidation. Bulk correlation between Fe and As is weak (
p
> 0.05), but inspection of micro-X-ray fluorescence maps shows that the secondary iron oxides are always associated with elevated As. Electron microprobe (EMP) and micro-X-ray diffraction analyses showed significant chemical and mineralogical heterogeneity of the secondary minerals, with wide variations of their Fe/Sb ratio and occasionally elevated Ca and Pb (> 5 wt%). The most common secondary minerals are goethite (α-FeOOH) with concentrations of Sb up to 3.14 wt% and As (1.29 wt%) and tripuhyite (FeSbO
4
) with increased content of As (1.14 wt%). Sb-rich secondary phases were identified as valentinite/senarmontite (Sb
2
O
3
), cervantite (Sb
2
O
4
), and a pyrochlore-group mineral stibiconite. High Sb phases with increased concentrations of Ca (up to 6.48 wt%) or Pb (20.78 wt%) were identified as stibiconite (EMP). This study shows that the secondary mineralogy in naturally attenuated contaminated soils and in Sb-containing tailings is identical. Hence, such tailings achieve their final state with respect to the Sb minerals within decades and are unlikely to change further. |
| doi_str_mv | 10.1007/s12665-019-8701-6 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2320922665</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2320922665</sourcerecordid><originalsourceid>FETCH-LOGICAL-a339t-65c8a7f74e83d6991efee75c73fd0c73a0e179999facfd6cd93381134835f2833</originalsourceid><addsrcrecordid>eNp1kM9KAzEQxoMoWLQP4C3g1Wiy6WaToxT_QVGheg7T3URTt0lNUqEP4Vv5YKas6Mk5zAzM930DP4ROGD1nlDYXiVVC1IQyRWRDGRF7aMSkEERUSu3_7pIeonFKS1qKM66oGKHFPeRNhB5DzsZvILvgcbAYfHar4Ldl6TDEZLxrsfM4BdenIsb51WBYlGvwpsPzBenMOiSX8WNYx_D1eYbnffiANwfH6MBCn8z4Zx6h5-urp-ktmT3c3E0vZwQ4V5mIupXQ2GZiJO-EUsxYY5q6bbjtaOlADWtUKQut7UTbKc4lY3wieW0ryfkROh1yy__3jUlZL8Mm-vJSV7yiqtpBKio2qNoYUorG6nV0K4hbzaje0dQDTV1o6h1NLYqnGjypaP2LiX_J_5u-Af3Td_4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2320922665</pqid></control><display><type>article</type><title>Natural attenuation of antimony and arsenic in soils at the abandoned Sb-deposit Poproč, Slovakia</title><source>SpringerLink Journals - AutoHoldings</source><creator>Jurkovič, Ľubomír ; Majzlan, Juraj ; Hiller, Edgar ; Klimko, Tomáš ; Voleková-Lalinská, Bronislava ; Méres, Štefan ; Göttlicher, Jörg ; Steininger, Ralph</creator><creatorcontrib>Jurkovič, Ľubomír ; Majzlan, Juraj ; Hiller, Edgar ; Klimko, Tomáš ; Voleková-Lalinská, Bronislava ; Méres, Štefan ; Göttlicher, Jörg ; Steininger, Ralph</creatorcontrib><description>This contribution investigates the natural attenuation of arsenic (As) and antimony (Sb) in highly contaminated soils at the abandoned Sb-deposit Poproč in eastern Slovakia. The studied soils were identified as technosols with pH values of 3.5–7.0 and high metal and metalloid load: antimony, arsenic, lead, and zinc up to 5757, 2484, 683, and 407 mg/kg, respectively. These toxic elements occur in the soils mainly as constituents of secondary minerals, which are products of sulphide oxidation. Bulk correlation between Fe and As is weak (
p
> 0.05), but inspection of micro-X-ray fluorescence maps shows that the secondary iron oxides are always associated with elevated As. Electron microprobe (EMP) and micro-X-ray diffraction analyses showed significant chemical and mineralogical heterogeneity of the secondary minerals, with wide variations of their Fe/Sb ratio and occasionally elevated Ca and Pb (> 5 wt%). The most common secondary minerals are goethite (α-FeOOH) with concentrations of Sb up to 3.14 wt% and As (1.29 wt%) and tripuhyite (FeSbO
4
) with increased content of As (1.14 wt%). Sb-rich secondary phases were identified as valentinite/senarmontite (Sb
2
O
3
), cervantite (Sb
2
O
4
), and a pyrochlore-group mineral stibiconite. High Sb phases with increased concentrations of Ca (up to 6.48 wt%) or Pb (20.78 wt%) were identified as stibiconite (EMP). This study shows that the secondary mineralogy in naturally attenuated contaminated soils and in Sb-containing tailings is identical. Hence, such tailings achieve their final state with respect to the Sb minerals within decades and are unlikely to change further.</description><identifier>ISSN: 1866-6280</identifier><identifier>EISSN: 1866-6299</identifier><identifier>DOI: 10.1007/s12665-019-8701-6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Antimony ; Antimony oxides ; Arsenic ; Attenuation ; Biogeosciences ; Earth and Environmental Science ; Earth Sciences ; Electron microprobe ; Electron probes ; Environmental Science and Engineering ; Fluorescence ; Geochemistry ; Geology ; Goethite ; Heavy metals ; Heterogeneity ; Hydrology/Water Resources ; Identification ; Inspection ; Iron ; Iron constituents ; Iron oxides ; Lead ; Mine tailings ; Mineralogy ; Minerals ; Natural attenuation ; Organic chemistry ; Original Article ; Oxidation ; Oxides ; Soil ; Soil contamination ; Soil investigations ; Soil pollution ; Soils ; Sulfides ; Sulphides ; Terrestrial Pollution ; X rays ; X-ray diffraction ; X-ray fluorescence ; Zinc</subject><ispartof>Environmental earth sciences, 2019-12, Vol.78 (24), p.1-13, Article 672</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Environmental Earth Sciences is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a339t-65c8a7f74e83d6991efee75c73fd0c73a0e179999facfd6cd93381134835f2833</citedby><cites>FETCH-LOGICAL-a339t-65c8a7f74e83d6991efee75c73fd0c73a0e179999facfd6cd93381134835f2833</cites><orcidid>0000-0003-4329-0717</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12665-019-8701-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12665-019-8701-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Jurkovič, Ľubomír</creatorcontrib><creatorcontrib>Majzlan, Juraj</creatorcontrib><creatorcontrib>Hiller, Edgar</creatorcontrib><creatorcontrib>Klimko, Tomáš</creatorcontrib><creatorcontrib>Voleková-Lalinská, Bronislava</creatorcontrib><creatorcontrib>Méres, Štefan</creatorcontrib><creatorcontrib>Göttlicher, Jörg</creatorcontrib><creatorcontrib>Steininger, Ralph</creatorcontrib><title>Natural attenuation of antimony and arsenic in soils at the abandoned Sb-deposit Poproč, Slovakia</title><title>Environmental earth sciences</title><addtitle>Environ Earth Sci</addtitle><description>This contribution investigates the natural attenuation of arsenic (As) and antimony (Sb) in highly contaminated soils at the abandoned Sb-deposit Poproč in eastern Slovakia. The studied soils were identified as technosols with pH values of 3.5–7.0 and high metal and metalloid load: antimony, arsenic, lead, and zinc up to 5757, 2484, 683, and 407 mg/kg, respectively. These toxic elements occur in the soils mainly as constituents of secondary minerals, which are products of sulphide oxidation. Bulk correlation between Fe and As is weak (
p
> 0.05), but inspection of micro-X-ray fluorescence maps shows that the secondary iron oxides are always associated with elevated As. Electron microprobe (EMP) and micro-X-ray diffraction analyses showed significant chemical and mineralogical heterogeneity of the secondary minerals, with wide variations of their Fe/Sb ratio and occasionally elevated Ca and Pb (> 5 wt%). The most common secondary minerals are goethite (α-FeOOH) with concentrations of Sb up to 3.14 wt% and As (1.29 wt%) and tripuhyite (FeSbO
4
) with increased content of As (1.14 wt%). Sb-rich secondary phases were identified as valentinite/senarmontite (Sb
2
O
3
), cervantite (Sb
2
O
4
), and a pyrochlore-group mineral stibiconite. High Sb phases with increased concentrations of Ca (up to 6.48 wt%) or Pb (20.78 wt%) were identified as stibiconite (EMP). This study shows that the secondary mineralogy in naturally attenuated contaminated soils and in Sb-containing tailings is identical. Hence, such tailings achieve their final state with respect to the Sb minerals within decades and are unlikely to change further.</description><subject>Antimony</subject><subject>Antimony oxides</subject><subject>Arsenic</subject><subject>Attenuation</subject><subject>Biogeosciences</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Electron microprobe</subject><subject>Electron probes</subject><subject>Environmental Science and Engineering</subject><subject>Fluorescence</subject><subject>Geochemistry</subject><subject>Geology</subject><subject>Goethite</subject><subject>Heavy metals</subject><subject>Heterogeneity</subject><subject>Hydrology/Water Resources</subject><subject>Identification</subject><subject>Inspection</subject><subject>Iron</subject><subject>Iron constituents</subject><subject>Iron oxides</subject><subject>Lead</subject><subject>Mine tailings</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Natural attenuation</subject><subject>Organic chemistry</subject><subject>Original Article</subject><subject>Oxidation</subject><subject>Oxides</subject><subject>Soil</subject><subject>Soil contamination</subject><subject>Soil investigations</subject><subject>Soil pollution</subject><subject>Soils</subject><subject>Sulfides</subject><subject>Sulphides</subject><subject>Terrestrial Pollution</subject><subject>X rays</subject><subject>X-ray diffraction</subject><subject>X-ray fluorescence</subject><subject>Zinc</subject><issn>1866-6280</issn><issn>1866-6299</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kM9KAzEQxoMoWLQP4C3g1Wiy6WaToxT_QVGheg7T3URTt0lNUqEP4Vv5YKas6Mk5zAzM930DP4ROGD1nlDYXiVVC1IQyRWRDGRF7aMSkEERUSu3_7pIeonFKS1qKM66oGKHFPeRNhB5DzsZvILvgcbAYfHar4Ldl6TDEZLxrsfM4BdenIsb51WBYlGvwpsPzBenMOiSX8WNYx_D1eYbnffiANwfH6MBCn8z4Zx6h5-urp-ktmT3c3E0vZwQ4V5mIupXQ2GZiJO-EUsxYY5q6bbjtaOlADWtUKQut7UTbKc4lY3wieW0ryfkROh1yy__3jUlZL8Mm-vJSV7yiqtpBKio2qNoYUorG6nV0K4hbzaje0dQDTV1o6h1NLYqnGjypaP2LiX_J_5u-Af3Td_4</recordid><startdate>20191201</startdate><enddate>20191201</enddate><creator>Jurkovič, Ľubomír</creator><creator>Majzlan, Juraj</creator><creator>Hiller, Edgar</creator><creator>Klimko, Tomáš</creator><creator>Voleková-Lalinská, Bronislava</creator><creator>Méres, Štefan</creator><creator>Göttlicher, Jörg</creator><creator>Steininger, Ralph</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7TG</scope><scope>7UA</scope><scope>7XB</scope><scope>88I</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H96</scope><scope>HCIFZ</scope><scope>KL.</scope><scope>L.G</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-4329-0717</orcidid></search><sort><creationdate>20191201</creationdate><title>Natural attenuation of antimony and arsenic in soils at the abandoned Sb-deposit Poproč, Slovakia</title><author>Jurkovič, Ľubomír ; Majzlan, Juraj ; Hiller, Edgar ; Klimko, Tomáš ; Voleková-Lalinská, Bronislava ; Méres, Štefan ; Göttlicher, Jörg ; Steininger, Ralph</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a339t-65c8a7f74e83d6991efee75c73fd0c73a0e179999facfd6cd93381134835f2833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Antimony</topic><topic>Antimony oxides</topic><topic>Arsenic</topic><topic>Attenuation</topic><topic>Biogeosciences</topic><topic>Earth and Environmental Science</topic><topic>Earth Sciences</topic><topic>Electron microprobe</topic><topic>Electron probes</topic><topic>Environmental Science and Engineering</topic><topic>Fluorescence</topic><topic>Geochemistry</topic><topic>Geology</topic><topic>Goethite</topic><topic>Heavy metals</topic><topic>Heterogeneity</topic><topic>Hydrology/Water Resources</topic><topic>Identification</topic><topic>Inspection</topic><topic>Iron</topic><topic>Iron constituents</topic><topic>Iron oxides</topic><topic>Lead</topic><topic>Mine tailings</topic><topic>Mineralogy</topic><topic>Minerals</topic><topic>Natural attenuation</topic><topic>Organic chemistry</topic><topic>Original Article</topic><topic>Oxidation</topic><topic>Oxides</topic><topic>Soil</topic><topic>Soil contamination</topic><topic>Soil investigations</topic><topic>Soil pollution</topic><topic>Soils</topic><topic>Sulfides</topic><topic>Sulphides</topic><topic>Terrestrial Pollution</topic><topic>X rays</topic><topic>X-ray diffraction</topic><topic>X-ray fluorescence</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jurkovič, Ľubomír</creatorcontrib><creatorcontrib>Majzlan, Juraj</creatorcontrib><creatorcontrib>Hiller, Edgar</creatorcontrib><creatorcontrib>Klimko, Tomáš</creatorcontrib><creatorcontrib>Voleková-Lalinská, Bronislava</creatorcontrib><creatorcontrib>Méres, Štefan</creatorcontrib><creatorcontrib>Göttlicher, 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Central Basic</collection><collection>Environment Abstracts</collection><jtitle>Environmental earth sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jurkovič, Ľubomír</au><au>Majzlan, Juraj</au><au>Hiller, Edgar</au><au>Klimko, Tomáš</au><au>Voleková-Lalinská, Bronislava</au><au>Méres, Štefan</au><au>Göttlicher, Jörg</au><au>Steininger, Ralph</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Natural attenuation of antimony and arsenic in soils at the abandoned Sb-deposit Poproč, Slovakia</atitle><jtitle>Environmental earth sciences</jtitle><stitle>Environ Earth Sci</stitle><date>2019-12-01</date><risdate>2019</risdate><volume>78</volume><issue>24</issue><spage>1</spage><epage>13</epage><pages>1-13</pages><artnum>672</artnum><issn>1866-6280</issn><eissn>1866-6299</eissn><abstract>This contribution investigates the natural attenuation of arsenic (As) and antimony (Sb) in highly contaminated soils at the abandoned Sb-deposit Poproč in eastern Slovakia. The studied soils were identified as technosols with pH values of 3.5–7.0 and high metal and metalloid load: antimony, arsenic, lead, and zinc up to 5757, 2484, 683, and 407 mg/kg, respectively. These toxic elements occur in the soils mainly as constituents of secondary minerals, which are products of sulphide oxidation. Bulk correlation between Fe and As is weak (
p
> 0.05), but inspection of micro-X-ray fluorescence maps shows that the secondary iron oxides are always associated with elevated As. Electron microprobe (EMP) and micro-X-ray diffraction analyses showed significant chemical and mineralogical heterogeneity of the secondary minerals, with wide variations of their Fe/Sb ratio and occasionally elevated Ca and Pb (> 5 wt%). The most common secondary minerals are goethite (α-FeOOH) with concentrations of Sb up to 3.14 wt% and As (1.29 wt%) and tripuhyite (FeSbO
4
) with increased content of As (1.14 wt%). Sb-rich secondary phases were identified as valentinite/senarmontite (Sb
2
O
3
), cervantite (Sb
2
O
4
), and a pyrochlore-group mineral stibiconite. High Sb phases with increased concentrations of Ca (up to 6.48 wt%) or Pb (20.78 wt%) were identified as stibiconite (EMP). This study shows that the secondary mineralogy in naturally attenuated contaminated soils and in Sb-containing tailings is identical. Hence, such tailings achieve their final state with respect to the Sb minerals within decades and are unlikely to change further.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s12665-019-8701-6</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-4329-0717</orcidid></addata></record> |
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| ispartof | Environmental earth sciences, 2019-12, Vol.78 (24), p.1-13, Article 672 |
| issn | 1866-6280 1866-6299 |
| language | eng |
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| subjects | Antimony Antimony oxides Arsenic Attenuation Biogeosciences Earth and Environmental Science Earth Sciences Electron microprobe Electron probes Environmental Science and Engineering Fluorescence Geochemistry Geology Goethite Heavy metals Heterogeneity Hydrology/Water Resources Identification Inspection Iron Iron constituents Iron oxides Lead Mine tailings Mineralogy Minerals Natural attenuation Organic chemistry Original Article Oxidation Oxides Soil Soil contamination Soil investigations Soil pollution Soils Sulfides Sulphides Terrestrial Pollution X rays X-ray diffraction X-ray fluorescence Zinc |
| title | Natural attenuation of antimony and arsenic in soils at the abandoned Sb-deposit Poproč, Slovakia |
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