UNAM-1: a robust CuI and CuII containing 3D-hydrogen-bonded framework with permanent porosity and reversible SO2 sorption
The construction of hydrogen-bonded frameworks (HBFs) that express permanent porosity and functionality is challenging due to the delicateness of hydrogen bonds. We present UNAM-1, a robust 3D-HBF fully sustained by charge-assisted H-bonds between [CuIICu12I(HL)12]10− and [Me2NH2]+ units, which disp...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2019-01, Vol.7 (47), p.26812-26817 |
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| container_issue | 47 |
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| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
| container_volume | 7 |
| creator | Domínguez-González, Ricardo Rojas-León, Irán Martínez-Ahumada, Eva Martínez-Otero, Diego Lara-García, Hugo A Balmaseda-Era, Jorge Ibarra, Ilich A Percástegui, Edmundo G Jancik, Vojtech |
| description | The construction of hydrogen-bonded frameworks (HBFs) that express permanent porosity and functionality is challenging due to the delicateness of hydrogen bonds. We present UNAM-1, a robust 3D-HBF fully sustained by charge-assisted H-bonds between [CuIICu12I(HL)12]10− and [Me2NH2]+ units, which displays a surface area of 522 m2 g−1 and reversibly adsorbs SO2 (3.5 mmol g−1). |
| doi_str_mv | 10.1039/c9ta07834g |
| format | Article |
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We present UNAM-1, a robust 3D-HBF fully sustained by charge-assisted H-bonds between [CuIICu12I(HL)12]10− and [Me2NH2]+ units, which displays a surface area of 522 m2 g−1 and reversibly adsorbs SO2 (3.5 mmol g−1).</description><subject>Crystallography</subject><subject>Hydrogen</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Porosity</subject><subject>Sulfur dioxide</subject><subject>Sulfur dioxide sorption</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNo9jctOAyEYRonRxKZ24xOQuEYZGBhw19Rbk2oX1nXDlJ_p1BZGYGz69tZL_DbnW52D0GVBrwvK9c1KZ0MrxcvmBA0YFZRUpZan_1-pczRKaUOPU5RKrQfo8PYyfibFLTY4hrpPGU_6KTbefnOKV8Fn0_rWN5jfkfXBxtCAJ3XwFix20exgH-I73rd5jTuIO-PBZ9yFGFKbDz-iCJ8QU1tvAb_OGU4hdrkN_gKdObNNMPrjEC0e7heTJzKbP04n4xlppGBESqOsY64sqaVWKK0MY1xVogConOBMV1BJEFVpaqmts6VbFSBkoTm1dW35EF39arsYPnpIebkJffTH4pJxRpVSWjD-BSG8Xq0</recordid><startdate>20190101</startdate><enddate>20190101</enddate><creator>Domínguez-González, Ricardo</creator><creator>Rojas-León, Irán</creator><creator>Martínez-Ahumada, Eva</creator><creator>Martínez-Otero, Diego</creator><creator>Lara-García, Hugo A</creator><creator>Balmaseda-Era, Jorge</creator><creator>Ibarra, Ilich A</creator><creator>Percástegui, Edmundo G</creator><creator>Jancik, Vojtech</creator><general>Royal Society of Chemistry</general><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope></search><sort><creationdate>20190101</creationdate><title>UNAM-1: a robust CuI and CuII containing 3D-hydrogen-bonded framework with permanent porosity and reversible SO2 sorption</title><author>Domínguez-González, Ricardo ; Rojas-León, Irán ; Martínez-Ahumada, Eva ; Martínez-Otero, Diego ; Lara-García, Hugo A ; Balmaseda-Era, Jorge ; Ibarra, Ilich A ; Percástegui, Edmundo G ; Jancik, Vojtech</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g652-66a8df2f440d0d5898a2238751ee7f53297e76e574ab69dfd4fc1e561930dbbd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Crystallography</topic><topic>Hydrogen</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Porosity</topic><topic>Sulfur dioxide</topic><topic>Sulfur dioxide sorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Domínguez-González, Ricardo</creatorcontrib><creatorcontrib>Rojas-León, Irán</creatorcontrib><creatorcontrib>Martínez-Ahumada, Eva</creatorcontrib><creatorcontrib>Martínez-Otero, Diego</creatorcontrib><creatorcontrib>Lara-García, Hugo A</creatorcontrib><creatorcontrib>Balmaseda-Era, Jorge</creatorcontrib><creatorcontrib>Ibarra, Ilich A</creatorcontrib><creatorcontrib>Percástegui, Edmundo G</creatorcontrib><creatorcontrib>Jancik, Vojtech</creatorcontrib><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of materials chemistry. 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| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2019-01, Vol.7 (47), p.26812-26817 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Crystallography Hydrogen Hydrogen bonding Hydrogen bonds Porosity Sulfur dioxide Sulfur dioxide sorption |
| title | UNAM-1: a robust CuI and CuII containing 3D-hydrogen-bonded framework with permanent porosity and reversible SO2 sorption |
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