Anion ligand promoted selective C-F bond reductive elimination enables C(sp)-H fluorination

A detailed mechanism study on the anion ligand promoted selective C-H bond fluorination is reported. The role of the anion ligand has been clarified by experimental evidence and DFT calculations. Moreover, the nitrate promoted C-F bond reductive elimination enabled a selective C-H bond fluorination...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2019-11, Vol.55 (96), p.14458-14461
Hauptverfasser:	Mao, Yang-Jie, Luo, Gen, Hao, Hong-Yan, Xu, Zhen-Yuan, Lou, Shao-Jie, Xu, Dan-Qian
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Crystallography Fluorination Hydrogen bonds Ligands
Online-Zugang:	Volltext
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